Optical filter for a window

• US 6,650,478 B1
• Filed: 08/20/1999
• Issued: 11/18/2003
• Est. Priority Date: 08/20/1999
• Status: Expired due to Fees

• Current Assignee: CPFilms Inc. (Eastman Chemical Company)
• Original Assignee: CPFilms Inc. (Eastman Chemical Company)
• Inventors: Maschwitz, Peter, DeBusk, Steven
• Primary Examiner(s): CHANG, AUDREY Y
• Application Number:
  US09/377,777
• Time in Patent Office: 1,551 Days
• Field of Search: 359/350, 359/359, 359/360, 359/580, 359/585, 428/432, 428/213, 427/162
• US Class Current: 359/585
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3649 made of metals other than silver
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection

Abstract

An optical filter in the form of a film which can be used in a window to control the amount of absorbed light, reflected light, transmitted light and solar energy rejection. The optical filter contains a unique combination of an interfering Fabry-Perot stack and a massive Fabry-Perot stack.

Claims

1. A multi-layered optical filter for a window which comprises the layer sequence:

first metal or metal compound/first dielectric/second metal or metal compound/second dielectric/third metal or metal compound wherein the layers;

first metal or metal compound/first dielectric/second metal or metal compound constitute a first stack which is an interference Fabry-Perot stack wherein said first dielectric is configured to function as an interfering dielectric within said Fabry-Perot stack, and the layers;

second metal or metal compound/second dielectric/third metal or metal compound constitute a second stack wherein said second dielectric is configured so that said second stack provides a reflection which is perceived as neutral and said second dielectric is a layer which is laminated to said second metal or metal compound of said first stack;

said second metal or metal compound being shared by said interference Fabry-Perot stack and said second stack;

said layer sequence being adhered to a transparent substrate; and

one of said first, second, and third metal or metal compound layers being a solar energy absorbing metal or metal compound layer;

one of said first, second and third metal or metal compound layers being an infrared reflecting metal layer and one of said first, second and third metal or metal compound layers being either a solar energy absorbing metal or metal compound layer or an infrared reflecting metal layer.

2. The optical filter of claim 1 wherein said solar energy absorbing metal or metal compound is replaced with a solar energy absorbing nonmetal selected from the group consisting of silicon and germanium or is replaced with silicon carbide.

3. The optical filter of claim 1 wherein said solar energy absorbing metal compound is a silicide or nitride formed from a metal selected from the group consisting of Ti, Nb, Ta and W.

4. The optical filter of claim 1 wherein one of said first, second and third metal or metal compound layers is a solar energy absorbing metal layer;

one of said first, second and third metal or metal compound layers is an infrared reflecting metal layer; and

one of said first, second and third metal or metal compound layers is either a solar energy absorbing metal layer or an infrared reflecting metal layer.

5. The optical filter of claim 4 wherein said first and second metal or metal compound layers are solar energy absorbing metal layers and said third metal or metal compound layer is an infrared reflecting metal layer so that said optical filter has the layer sequence:

first absorbing metal/first dielectric/second absorbing metal/second dielectric/infrared reflecting metal.

6. The optical filter of claim 5 wherein said first and second absorbing metal layers are metal selected from the group consisting of nickel alloy, titanium, titanium alloy and stainless steel;

and said infrared reflecting metal is selected from the group consisting of silver, gold, aluminum, copper, nickel, silver alloy, gold alloy, aluminum alloy and copper alloy.

7. The optical filter of claim 6 wherein the first dielectric layer is clear to partially absorbing with an extinction coefficient of 0.0 to 0.2 and said first dielectric is an oxide of a metal selected from the group consisting of Mg, Al, Si, Ti, Cr, Zn, Zr, Nb, Mo, In, Sn, Sb, Ta, W, or Bi or is SiN.

8. The optical filter of claim 7 wherein the second dielectric is a polyester resin adhesive or is a dual layered structure having a polyester resin adhesive layer and a layer of polyethylene terephthalate film;

said transparent substrate is a polyethylene terephthalate film having first and second surfaces wherein said first surface is adhered to said first absorbing metal and said optical filter further includes a transparent UV absorbing polyester film adhered to said infrared reflecting metal laxer.

9. The optical filter of claim 8 which further includes a scratch resistant layer adhered to the second surface of said polyethylene terephthalate substrate.

10. The optical filter of claim 9 wherein the first absorbing metal layer is thicker than said second absorbing metal layer with the ratio of the thicker absorbing metal layer to the thinner absorbing metal layer being 1.9-2.3 and said optical filter has an overall visible light transmission of 30% or less.

11. The optical filter of claim 10 wherein the thicker absorbing metal layer has a thickness of 9.6 to 11.1 nm;

the thinner absorbing metal layer has a thickness of 5.6 to 6.5 nm;

the infrared reflecting metal layer has a thickness of 3.15 to 3.6 mm;

said optical filter has a visible light transmission of 15%;

said infrared reflecting metal is aluminum and said absorbing metal consists of;

12. The optical filter of claim 11 which is secured to a glass sheet with an adhesive layer between said filter and said glass sheet.

13. The optical filter of claim 9 which is secured to a glass sheet with an adhesive layer between said filter and said glass sheet.

14. The optical filter of claim 9 wherein said first and second absorbing metal layers are of about equal thickness in a range of 2.3 to 3 nm;

said infrared reflecting metal layer has a thickness of 3.6 to 4 nm;

said optical filter has a visible light transmission of 35%;

said infrared reflecting metal is aluminum and said absorbing metal consists of;

15. The optical filter of claim 14 which is secured to a glass sheet with an adhesive layer between said filter and said glass sheet.

16. The optical filter of claim 8 which is laminated to a layer of polyvinyl butyrate.

17. A multi-layered optical filter for a window which comprises the layer sequence:

first metal or metal compound/first dielectric/second metal or metal compound/second dielectric/third metal or metal compound wherein the layers;

first metal or metal compound/first dielectric/second metal or metal compound constitute a first stack which is an interference Fabry-Perot stack wherein said first dielectric is configured to function as an interfering dielectric within said Fabry-Perot stack, and the layers;

second metal or metal compound/second dielectric/third metal or metal compound constitute a second stack wherein said second dielectric has a thickness greater than 0.7 microns;

said second metal or metal compound being shared by said interference Fabry-Perot stack and said second stack;

said layer sequence being adhered to a transparent substrate; and

one of said first, second, and third metal or metal compound layers being a solar energy absorbing metal or metal compound layer;

one of said first, second and third metal or metal compound layers being an infrared reflecting metal layer and one of said first, second and third metal or metal compound layers being either a solar energy absorbing metal or metal compound layer or an infrared reflecting metal layer.

18. The optical filter of claim 17 wherein said second dielectric has a thickness of 1.3 to 1.8 microns.

19. A multi-layered optical filter for a window which comprises the layer sequence:

first metal or metal compound/first dielectric/second metal or metal compound/second dielectric/third metal or metal compound wherein the layers;

first metal or metal compound/first dielectric/second metal or metal compound constitute a first stack which is an interference Fabry-Perot stack wherein said first dielectric is configured to function as an interfering dielectric within said Fabry-Perot stack, and the layers;

second metal or metal compound/second dielectric/third metal or metal compound constitute a second stack wherein said second dielectric has a quarter wave optical thickness of at least 7;

said second metal or metal compound being shared by said interference Fabry-Perot stack and said second stack;

said layer sequence being adhered to a transparent substrate; and

one of said first, second, and third metal or metal compound layers being a solar energy absorbing metal or metal compound layer;

one of said first, second and third metal or metal compound layers being an infrared reflecting metal layer and one of said first, second and third metal or metal compound layers being either a solar energy absorbing metal or metal compound layer or an infrared reflecting metal layer.

20. The optical filter of claim 19 wherein said second dielectric has a quarter wave optical thickness of at least 9.