UV-sensitive marking composition

• US 6,652,638 B2
• Filed: 06/01/2001
• Issued: 11/25/2003
• Est. Priority Date: 06/01/2001
• Status: Expired due to Term

• Current Assignee: Aervoe Industries Incorporated
• Original Assignee: Aervoe Pacific Company, Inc.
• Inventors: Finke, Christopher P., Fox, Neil S.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): FAISON GEE, VERONICA FAYE
• Application Number:
  US09/873,027
• Publication Number:
  US 20020178970A1
• Time in Patent Office: 907 Days
• Field of Search: 106/31.64, 106/31.75, 106/31.77, 106/31.86, 106/31.69, 106/31.88, 523/160, 523/161, 524/556, 524/577, 524/589, 524/588
• US Class Current: 106/31.64
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks

Abstract

A marking composition for placing a temporarily visible mark on a surface. The composition includes a paint base and a pigmented colorant. The pigmented colorant is dispersed within the paint base, and has characteristics that cause the mark to progressively become substantially invisible upon exposure to UV light. Additives, such as UV absorbers and anti-oxidants may be included to alter the rate at which the mark becomes invisible. The pigmented colorant may be a dispersion of dyed melamine-toluenesulfonamide-formaldehyde polymer in a mixture of alkyl based resins and aliphatic hydrocarbons. The colorant may be about 2 to 30 parts by weight of the composition.

Claims

1. A composition for placing a temporarily visible mark on a surface, comprising:

a) a paint base; and

b) a pigmented colorant, dispersed within the paint base, having characteristics that cause the mark to progressively become substantially invisible upon exposure to UV light, wherein the pigmented colorant is a dispersion of dyed melamine-toluenesulfonamide-formaldehyde polymer in a mixture of alkyl based resins and aliphatic hydrocarbons.

2. The composition of claim 1, wherein the pigmented colorant is about 2 to about 30 parts by weight of the composition.

3. The composition of claim 1, wherein the pigmented colorant has a color selected from the group consisting of red, orange, yellow, pink, blue and green.

4. The composition of claim 1, wherein the paint base composition comprises a binder, a solvent and at least one paint additive.

5. The composition of claim 4, wherein the binder is about 8 to 45 parts, the solvent is about 10 to 60 parts and the at least one additive is about 1 to 15 parts, by weight of the composition.

6. The composition of claim 4, wherein the binder is at least one member selected from the group consisting of alkyds, vinyls, soluble cellulosics, urethanes, epoxies, modified and unmodified phenolics, acrylics, polystyrenes, alkyls, silicones and terpenes.

7. The composition of claim 4, wherein the solvent is at least one member selected from the group consisting of benzene, toluene, xylene, ethylene dichloride, ethyl acetate, acetone, methyl ethyl ketone, methyl isobutyl ketone, propylene oxide, naphtha, isopropyl alcohol, water, hexanes and ethylene glycol monobutyl ether.

8. The composition of claim 1, further comprising from 15 to about 40 parts by weight of the composition a propellant.

9. The composition of claim 1, wherein the mark remains visible for up to forty (40) days.

10. The composition of claim 1, wherein the mark remains visible for at least four (4) days.

11. The composition of claim 1, further comprising at least one additive from the group consisting of preservatives, plasticizers and surfactants.

12. The composition of claim 1, wherein the surface to be marked is a member selected from the group consisting of asphalt, concrete, grass and soil.

23. The composition of claim 1, further comprising at least one additive selected from the group consisting of UV absorbers and anti-oxidants.

24. The composition of claim 23, wherein the UV absorber is at least one member selected from the group consisting of:

hindered amines and benzotriazole based UV-absorbers.

25. The composition of claim 23, wherein the UV absorber is present in a concentration of about 0.1% to 10% by weight of the composition.

26. The composition of claim 23, Therein the anti-oxidant is a hindered phenolic.

27. The composition of claim 23, wherein the anti-oxidant is present in a concentration of about 0.1% to 10% by weight of the composition.

13. A method of temporarily marking a surface, comprising the steps of:

a) applying a marking composition having;

i) a paint base; and

ii) a pigmented colorant, dispersed within the paint base, having UV-sensitive fading characteristics, wherein the pigmented colorant is a dispersion of dyed melamine-toluenesulfonamide-formaldehyde polymer in a mixture of alkyl based resins and aliphatic hydrocarbons; and

b) exposing the marking composition to UV light, such that the mark fades progressively to an extent that it is substantially invisible.

14. The method of claim 13, wherein the pigmented colorant is about 2 to about 30 parts by weight of the marking composition.

15. The method of claim 13, wherein the pigmented colorant has a color selected from the group consisting of red, orange, yellow, pink, blue and green.

16. The method of claim 13, wherein the paint base comprises a binder, a solvent and at least one paint additive.

17. The method of claim 16, wherein the binder is about 8 to 45 parts, the solvent is about 10 to 60 parts and the at least one additive is about 1 to 15 parts, by weight, of the marking composition.

18. The method of claim 16, wherein the binder is at least one member selected from the group consisting of alkyds, vinyls, soluble cellulosics, urethanes, epoxies, modified and unmodified phenolics, acrylics, polystyrenes, alkyls, silicones and terpenes.

19. The method of claim 16, wherein the solvent is at least one member selected from the group consisting of benzene, toluene, xylene, ethylene dichloride, ethyl acetate, acetone, methyl ethyl ketone, methyl isobutyl ketone, propylene oxide, naphtha, isopropyl alcohol, water, hexanes and ethylene glycol monobutyl ether.

20. The method of claim 13, wherein the marking composition further comprises from 24 to about 34 parts by weight of the marking composition a propellant.

21. The method of claim 13, wherein the marking composition further comprises at least one additive selected from the group consisting of:

preservatives, surfactants and plasticizers.

22. The method of claim 13, wherein the surface to be marked is a member selected from the group consisting of asphalt, concrete, grass and soil.

28. The method of claim 13, wherein the marking composition further comprises at least one additive selected from the group consisting of UV absorbers and anti-oxidants.

29. The method of claim 28, wherein the UV absorber is selected from the group consisting of hindered amines and benzotriazole based UV-absorbers.

30. The method of claim 28, wherein the UV absorber is present in a concentration of about 0.1% to 10% by weight of the composition.

31. The method of claim 28, wherein the anti-oxidant is a hindered phenolic.

32. The method of claim 28, wherein the anti-oxidant is present in a concentration of about 0.1% to 10% by weight of the composition.