Electrode material for electric double layer capacitor and electric double layer capacitor using the same

• US 6,654,229 B2
• Filed: 03/18/2002
• Issued: 11/25/2003
• Est. Priority Date: 03/21/2001
• Status: Expired due to Term

• Current Assignee: GSI Creos Corporation, Morinobu Endo
• Original Assignee: GSI Creos Corporation, Morinobu Endo
• Inventors: Yanagisawa, Takashi, Endo, Morinobu
• Primary Examiner(s): Reichard, Dean A.
• Assistant Examiner(s): HA, NGUYEN T
• Application Number:
  US10/098,379
• Publication Number:
  US 20020141140A1
• Time in Patent Office: 617 Days
• Field of Search: 361/503, 361/502, 361/504, 361/508, 361/509, 361/510, 361/512, 361/518, 361/516, 361/535, 361/525, 429/40, 429/44, 429/231.8, 429/235
• US Class Current: 361/502
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 32/15 Nano-sized carbon materials
• CPC Class Codes: D01F 9/127 by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
• CPC Class Codes: H01G 11/36 Nanostructures, e.g. nanofibres, nanotubes or fullerenes
• CPC Class Codes: H01G 11/40 Fibres
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries

Abstract

An electrode material for an electric double layer capacitor having a carbon fiber as an essential material. The carbon fiber has a coaxial stacking morphology of truncated conical tubular graphene layers, and each of the truncated conical tubular graphene layers includes a hexagonal carbon layer. Edges of the hexagonal carbon layer are exposed. The exposed edges of the hexagonal carbon layers have a high degree of activity and can be modified with functional groups such as —COOH, —CHO, or —OH. This enables use of the carbon fiber as the electrode material. The specific surface area of the surfaces on which the edges are exposed is extremely large, whereby a large-capacitance electric double layer capacitor can be formed.

Claims

1. An electrode material for an electric double layer capacitor comprising a carbon fiber as an essential material,

wherein the carbon fiber has a coaxial stacking morphology of truncated conical tubular graphene layers;

wherein each of the truncated conical tubular graphene layers includes a hexagonal carbon layer and has a large ring end at one end and a small ring end at the other end in an axial direction; and

wherein at least part of edges of the hexagonal carbon layers is exposed at the large ring ends.

2. The electrode material for an electric double layer capacitor as defined in claim 1,

wherein at least part of edges of the hexagonal carbon layers is exposed at the small ring ends.

3. The electrode material for an electric double layer capacitor as defined in claim 2,

wherein the coaxial stacking morphology of the truncated conical tubular graphene layers is vapor grown;

and

wherein at least part of a deposited film formed during the vapor growth is removed from the large and small ring ends.

4. The electrode material for an electric double layer capacitor as defined in claim 1,

wherein the coaxial stacking morphology of the truncated conical tubular graphene layers has a shape of a hollow core with no bridge.

5. The electrode material for an electric double layer capacitor as defined in claim 1,

wherein an outer surface of the carbon fiber is formed of the large ring ends stacked in the axial direction;

and

wherein the exposed part of the edges of the hexagonal carbon layers has an area equal to or more than 2 percentages of an area of the outer surface.

6. The electrode material for an electric double layer capacitor as defined in claim 5,

wherein positions of the large ring ends forming the outer surface are irregular, and the outer surface has minute irregularity at the level of atoms.

7. The electrode material for an electric double layer capacitor as defined in claim 1,

wherein an inner surface of the carbon fiber is formed of the small ring ends stacked in the axial direction;

and

wherein positions of the small ring ends forming the inner surface are irregular, and the inner surface has minute irregularity at the level of atoms.

8. The electrode material for an electric double layer capacitor as defined in claim 1,

wherein the coaxial stacking morphology of the truncated conical tubular graphene layers is vapor grown;

and

wherein at least part of gaps between the hexagonal carbon layers is larger than the gaps between the hexagonal carbon layers at the time of the vapor growth.

9. The electrode material for an electric double layer capacitor as defined in claim 8, having a bulk density of 0.010 g/cm³ or less.

10. The electrode material for an electric double layer capacitor as defined in claim 8,

wherein at least part of the gaps between the hexagonal carbon layers is 100 to 1000 times larger than the gaps between the hexagonal carbon layers at the time of the vapor growth.

11. The electrode material for an electric double layer capacitor as defined in claim 8,

wherein one to several tens of thousands of the hexagonal carbon layers are stacked.

12. An electric double layer capacitor in which the electrode material as defined in claim 1 is used for an electrode.

13. An electrode material for an electric double layer capacitor comprising a carbon fiber as an essential material,

wherein the carbon fiber has a coaxial stacking morphology of truncated conical tubular graphene layers;

wherein the coaxial stacking morphology of the truncated conical tubular graphene layers includes one to several hundreds of stacked hexagonal carbon layers;

wherein each of the truncated conical tubular graphene layers includes a hexagonal carbon layer and has a large ring end at one end and a small ring end at the other end in an axial direction; and

wherein at least part of edges of the hexagonal carbon layers is exposed at the large ring ends.

14. The electrode material for an electric double layer capacitor as defined in claim 13,

wherein at least part of edges of the hexagonal carbon layers is exposed at the small ring ends.

15. The electrode material for an electric double layer capacitor as defined in claim 14,

wherein the coaxial stacking morphology of the truncated conical tubular graphene layers is vapor grown;

and

wherein at least part of a deposited film formed during the vapor growth is removed from the large and small ring ends.

16. The electrode material for an electric double layer capacitor as defined in claim 13,

wherein the coaxial stacking morphology of the truncated conical tubular graphene layers has a shape of a hollow core with no bridge.

17. The electrode material for an electric double layer capacitor as defined in claim 13,

wherein an outer surface of the carbon fiber is formed of the large ring ends stacked in the axial direction;

and

wherein the exposed part of the edges of the hexagonal carbon layers has an area equal to or more than 2 percentages of an area of the outer surface.

18. The electrode material for an electric double layer capacitor as defined in claim 17,

wherein positions of the large ring ends forming the outer surface are irregular, and the outer surface has minute irregularity at the level of atoms.

19. The electrode material for an electric double layer capacitor as defined in claim 13,

wherein an inner surface of the carbon fiber is formed of the small ring ends stacked in the axial direction;

and

wherein positions of the small ring ends forming the inner surface are irregular, and the inner surface has minute irregularity at the level of atoms.

20. An electric double layer capacitor in which the electrode material as defined in claim 13 is used for an electrode.