Process for removing environmentally harmful compounds

• US 6,667,017 B2
• Filed: 09/21/2001
• Issued: 12/23/2003
• Est. Priority Date: 10/15/1999
• Status: Expired due to Fees

• Current Assignee: ABB Lummus Global Inc.
• Original Assignee: ABB Lummus Global Inc.
• Inventors: Trubac, Robert E., Overbeek, Rudolf, Lusse, Pieter, Ramachandran, Balachandran, Murrell, Lawrence L.
• Primary Examiner(s): Silverman, Stanley S.
• Assistant Examiner(s): MEDINA SANABRIA, MARIBEL
• Application Number:
  US09/957,925
• Publication Number:
  US 20020141912A1
• Time in Patent Office: 823 Days
• Field of Search: 423/210, 423/239.1, 423/240.R, 423/245.1, 423/244.02
• US Class Current: 423/210
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 2257/702 Hydrocarbons
• CPC Class Codes: B01D 2257/708 Volatile organic compounds V.O.C.'s
• CPC Class Codes: B01D 53/8631 Processes characterised by a specific device
• CPC Class Codes: B01D 53/864 Removing carbon monoxide or hydrocarbons
• CPC Class Codes: B01D 53/8687 Organic components
• CPC Class Codes: B01D 53/885 Devices in general for catalytic purification of waste gases
• CPC Class Codes: B01D 53/9431 Processes characterised by a specific device
• CPC Class Codes: B01J 23/30 Tungsten
• CPC Class Codes: B01J 23/42 Platinum
• CPC Class Codes: B01J 35/56 Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
• CPC Class Codes: B01J 35/58 Fabrics or filaments
• CPC Class Codes: F01N 13/0097 the purifying devices are arranged in a single housing
• CPC Class Codes: F01N 2330/10 Fibrous material, e.g. mineral or metallic wool
• CPC Class Codes: F01N 2330/12 Metallic wire mesh fabric or knitting
• CPC Class Codes: F01N 2330/14 Sintered material
• CPC Class Codes: F01N 2330/38 flow channels with means to enhance flow mixing,(e.g. protrusions or projections)
• CPC Class Codes: F01N 3/281 Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
• CPC Class Codes: F01N 3/2814 all sheets, plates or foils being corrugated
• CPC Class Codes: F01N 3/2821 the support being provided with means to enhance the mixing process inside the converter, e.g. sheets, plates or foils with protrusions or projections to create turbulence
• CPC Class Codes: F01N 3/2828 : Ceramic multi-channel monoliths, e.g. honeycombs
• CPC Class Codes: F01N 3/2835 : fibrous

Abstract

A process for oxidizing environmentally harmful compounds which participate in atmospheric photochemical reactions to produce for example ozone and undesirable smog constituents from a fluid, in particular a gas, volatile organic compounds (VOC) including hydrocarbons, CO and any other constituent that participates in atmospheric photochemical reactions to produce for example ozone or smog constituents and combustible compounds to be removed from a gas stream for reasons of toxicity, photochemical reactivity or physical discomfort such as irritants, particulates, odor sources and so on, and compounds which may cause upper atmosphere ozone depletion or lower atmosphere ozone formation. The uncoated randomly oriented mesh-like structure preferably has a porosity greater than about 85%. The coated randomly oriented mesh-like structure preferably has a porosity greater than about 65%. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst for oxidizing the volatile organic compound(s). In the disclosed embodiments, corrugated mesh-like sheets are arranged in mirror image angular relative orientations relative to the input gas flow direction in a range of angles from about 30° to about 80°. In a further embodiment, the corrugated sheets are in series with a monolith structure with the corrugated sheets initially receiving the fluid with the environmentally harmful compounds to be oxidized and which fluid then flows into the monolith structure to complete the oxidation. In other embodiments, the mesh-like structure may have different configurations.

Claims

1. A process for removing environmentally harmful compounds from a fluid, in particular a gas, comprising:

forming a substrate comprising a randomly oriented mesh-like fibrous porous material having opposing sides, the material for promoting contact between fluids flowing over the surfaces of the material at the opposing sides, the material having pores exhibiting a range of sizes from sub-micron to no greater than about 500 microns, the pores having a plurality of interstices in communication with each other and externally the material, the material being arranged to create turbulence in the fluid flowing adjacent to said sides which turbulence creates a pressure differential across the material for promoting the flow of the flowing fluid from one side to the other side through the pores and interstices essentially over the entire surface of the material; and

oxidizing the environmentally harmful compounds in the fluid in the presence of an oxidizing catalyst supported on the material, the catalyzed mesh-like structure having a porosity of greater than about 65%.

2. The process of claim 1 wherein said catalyzed mesh-like structure has a porosity of greater than 80%.

3. The process of claim 1 wherein said environmentally harmful compounds include volatile organic compounds (VOC) including hydrocarbons, CO and any other constituent that participates in atmospheric photochemical reactions to produce for example ozone or smog constituents, combustible compounds to be removed from a gas stream for reasons of toxicity, photochemical reactivity or physical discomfort such as irritants, particulates, odor sources, compounds which may cause upper atmosphere ozone depletion or lower atmosphere ozone formation and any organic compound which participates in atmospheric photochemical reactions excluding carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate.

4. The process of claim 1 wherein the fibrous material comprises a plurality of fibers, including coating the catalyst on the fibers and also depositing catalytic material at the intersection of the fibers.

5. The process of claim 4 wherein the coating step includes coating the catalyst to a thickness less than 80 microns.

6. The process of claim 1 wherein the environmentally harmful compounds include any compound of carbon excluding carbon dioxide, carbonic acid, metallic carbides or carbonates and ammonium carbonate.

7. The process of claim 1 including forming the substrate of metal fibers.

8. The process of claim 1 including forming the substrate of ceramic fibers.