Toner, image-forming apparatus, process cartridge and image forming method

• US 6,670,087 B2
• Filed: 11/05/2001
• Issued: 12/30/2003
• Est. Priority Date: 11/07/2000
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Fujimoto, Masami, Fujikawa, Hiroyuki, Taya, Masaaki, Kobori, Takakuni
• Primary Examiner(s): Chapman, Mark A.
• Application Number:
  US09/985,517
• Publication Number:
  US 20020098431A1
• Time in Patent Office: 785 Days
• Field of Search: 430/109.2, 430/109.3, 430/111.41, 430/111.4
• US Class Current: 430/109.2
• CPC Class Codes: G03G 9/0821 characterised by physical parameters magnetic parameters G03G9/083
• CPC Class Codes: G03G 9/0823 Electric parameters
• CPC Class Codes: G03G 9/08708 Copolymers of styrene
• CPC Class Codes: G03G 9/08726 Polymers of unsaturated acids or derivatives thereof
• CPC Class Codes: G03G 9/08728 Polymers of esters
• CPC Class Codes: G03G 9/08795 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants

Abstract

In a toner comprising a binder resin and a colorant, the toner contains as the binder resin at least a vinyl resin selected from the group consisting of i) a vinyl resin having a carboxyl group and a vinyl resin having an epoxy group, ii) a vinyl resin having a carboxyl group and an epoxy group and iii) a vinyl resin produced by the reaction of a carboxyl group with an epoxy group, and the toner has, in its dielectric dissipation factor (tan δ), at least a maximum value and a minimum value in the temperature range of from 20° C. to 150° C., and, where the maximum value is represented by Max and the minimum value by Min, has a value of log₁₀(Max/Min)≦2. Also disclosed are an image-forming apparatus, a process cartridge and an image-forming method which make use of the toner.

Claims

1. A toner comprising a binder resin and a colorant, wherein;

said toner contains as the binder resin at least a vinyl resin selected from the group consisting of;

a vinyl resin having a carboxyl group and a vinyl resin having an epoxy group;

a vinyl resin having a carboxyl group and an epoxy group; and

a vinyl resin produced by the reaction of a carboxyl group with an epoxy group; and

said toner has, in its dielectric dissipation factor (tan δ

), at least a maximum value and a minimum value in the temperature range of from 20°

C. to 150°

C., and, where the maximum value is represented by Max and the minimum value by Min, has a value of log₁₀(Max/Min)≦

2.

2. The toner according to claim 1, which has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, a number-average molecular weight of from 1,000 to 40,000 and a weight-average molecular weight of from 10,000 to 10,000,000.

3. The toner according to claim 1, which has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, at least one main peak in the region of molecular weight of from 4,000 to 30,000.

4. The toner according to claim 3, wherein, in said molecular weight distribution, the peak area in the region of molecular weight of 30,000 or lower is in a proportion of from 60% to 100% with respect to the total peak area.

5. The toner according to claim 1, wherein said binder resin contains a tetrahydrofuran-insoluble matter in an amount of from 0.1% by weight to 60% by weight.

6. The toner according to claim 1, which has a THF-soluble matter having an acid value of from 0.1 mg·

KOH/g to 50 mg·

KOH/g.

7. The toner according to claim 1, wherein said colorant is a magnetic material.

8. The toner according to claim 7, wherein said magnetic material is a magnetic iron oxide containing at least one element A belonging to the third and following periods of the long form of the periodic table and having an electronegativity of from 1.0 to 2.5;

said element A being contained in said magnetic material in a content of from 0.1% by weight to 4.0% by weight on the basis of Fe in said magnetic material; and

said magnetic material standing liberated into the toner in a number of from 70 particles to 500 particles per 10,000 toner particles.

9. The toner according to claim 8, wherein said element A is an element selected from the group consisting of Al, Si, P, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Zr, Sn and Pb.

10. The toner according to claim 8, wherein said element A is an element selected from the group consisting of Al, Si, Ti, Mn and Zn.

11. The toner according to claim 7, wherein said magnetic material is contained in an amount of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of the binder resin.

12. An image-forming apparatus comprising a developing means for moving a toner to an electrostatic latent image formed on a photosensitive member, to render the electrostatic latent image visible to form a toner image, and a transfer means for transferring the toner image to a transfer medium to form an image;

in a developer-carrying member of said developing means, at least an alternating-current bias being applied to make the toner adhere to the electrostatic latent image to form a visible image; and

said toner comprising a binder resin and a colorant;

wherein;

said toner contains as the binder resin at least a vinyl resin selected from the group consisting of;

a vinyl resin having a carboxyl group and a vinyl resin having an epoxy group;

a vinyl resin having a carboxyl group and an epoxy group; and

a vinyl resin produced by the reaction of a carboxyl group with an epoxy group; and

said toner has, in its dielectric dissipation factor (tan δ

), at least a maximum value and a minimum value in the temperature range of from 20°

C. to 150°

C., and, where the maximum value is represented by Max and the minimum value by Min, having a value of log₁₀(Max/Min)≦

2.

13. The image-forming apparatus according to claim 12, wherein said toner has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, a number-average molecular weight of from 1,000 to 40,000 and a weight-average molecular weight of from 10,000 to 10,000,000.

14. The image-forming apparatus according to claim 12, wherein said toner has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, at least one main peak in the region of molecular weight of from 4,000 to 30,000.

15. The image-forming apparatus according to claim 14, wherein, in said molecular weight distribution, the peak area in the region of molecular weight of 30,000 or lower is in a proportion of from 60% to 100% with respect to the total peak area.

16. The image-forming apparatus according to claim 12, wherein said binder resin of said toner contains a tetrahydrofuran-insoluble matter in an amount of from 0.1% by weight to 60% by weight.

17. The image-forming apparatus according to claim 12, wherein said toner has a THF-soluble matter having an acid value of from 0.1 mg·

KOH/g to 50 mg·

KOH/g.

18. The image-forming apparatus according to claim 12, wherein said colorant is a magnetic material.

19. The image-forming apparatus according to claim 18, wherein said magnetic material is a magnetic iron oxide containing at least one element A belonging to the third and following periods of the long form of the periodic table and having an electronegativity of from 1.0 to 2.5;

said element A being contained in said magnetic material in a content of from 0.1% by weight to 4.0% by weight on the basis of Fe in said magnetic material; and

said magnetic material standing liberated into the toner in a number of from 70 particles to 500 particles per 10,000 toner particles.

20. The image-forming apparatus according to claim 19, wherein said element A is an element selected from the group consisting of Al, Si, P, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Zr, Sn and Pb.

21. The image-forming apparatus according to claim 19, wherein said element A is an element selected from the group consisting of Al, Si, Ti, Mn and Zn.

22. The image-forming apparatus according to claim 18, wherein said magnetic material is contained in an amount of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of the binder resin.

23. A process cartridge comprising:

an electrostatic image-bearing member, and developing means for developing an electrostatic image formed on the electrostatic image-bearing member with a toner contained therein;

the electrostatic image-bearing member and the developing means being integrally assembled to form a process cartridge, which is detachably mountable to a main assembly of the image forming apparatus; and

said toner comprising a binder resin and a colorant;

wherein;

said toner contains as the binder resin at least a vinyl resin selected from the group consisting of;

a vinyl resin having a carboxyl group and a vinyl resin having an epoxy group;

a vinyl resin having a carboxyl group and an epoxy group; and

a vinyl resin produced by the reaction of a carboxyl group with an epoxy group; and

said toner has, in its dielectric dissipation factor (tan δ

), at least a maximum value and a minimum value in the temperature range of from 20°

C. to 150°

C., and, where the maximum value is represented by Max and the minimum value by Min, having a value of log₁₀(Max/Min)≦

2.

24. The process cartridge according to claim 23, wherein said toner has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, a number-average molecular weight of from 1,000 to 40,000 and a weight-average molecular weight of from 10,000 to 10,000,000.

25. The process cartridge according to claim 23, wherein said toner has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, at least one main peak in the region of molecular weight of from 4,000 to 30,000.

26. The process cartridge according to claim 25, wherein, in said molecular weight distribution, the peak area in the region of molecular weight of 30,000 or lower is in a proportion of from 60% to 100% with respect to the total peak area.

27. The process cartridge according to claim 23, wherein said binder resin of said toner contains a tetrahydrofuran-insoluble matter in an amount of from 0.1% by weight to 60% by weight.

28. The process cartridge according to claim 23, wherein said toner has a THF-soluble matter having an acid value of from 0.1 mg·

KOH/g to 50 mg·

KOH/g.

29. The process cartridge according to claim 23, wherein said colorant is a magnetic material.

30. The process cartridge according to claim 29, wherein said magnetic material is a magnetic iron oxide containing at least one element A belonging to the third and following periods of the long form of the periodic table and having an electronegativity of from 1.0 to 2.5;

said element A being contained in said magnetic material in a content of from 0.1% by weight to 4.0% by weight on the basis of Fe in said magnetic material; and

said magnetic material standing liberated into the toner in a number of from 70 particles to 500 particles per 10,000 toner particles.

31. The process cartridge according to claim 30, wherein said element A is an element selected from the group consisting of Al, Si, P, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Zr, Sn and Pb.

32. The process cartridge according to claim 30, wherein said element A is an element selected from the group consisting of Al, Si, Ti, Mn and Zn.

33. The process cartridge according to claim 29, wherein said magnetic material is contained in an amount of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of the binder resin.

34. An image-forming method comprising subjecting a toner image held on a transfer medium, to heat-and-pressure fixing by a heat-and-pressure fixing means to form a fixed image on the transfer medium, wherein;

(1) a toner which forms the toner image is a toner comprising a binder resin and a colorant;

said toner containing as the binder resin at least a vinyl resin selected from the group consisting of;

a vinyl resin having a carboxyl group and a vinyl resin having an epoxy group;

a vinyl resin having a carboxyl group and an epoxy group; and

a vinyl resin produced by the reaction of a carboxyl group with an epoxy group; and

said toner having, in its dielectric dissipation factor (tan δ

), at least a maximum value and a minimum value in the temperature range of from 20°

C. to 150°

C., and, where the maximum value is represented by Max and the minimum value by Min, having a value of log₁₀(Max/Min)≦

2; and

(2) as said heat-and-pressure fixing means, a heat-and-pressure fixing means is used which has at least;

(i) a magnetic field generation means;

(ii) a rotary heating member having at least a heat generation layer capable of generating heat by electromagnetic induction, and a release layer; and

(iii) a rotary pressure member which forms a nip with the heating member; and

said toner image held on said transfer medium is heat and pressure fixed while said rotary pressing member is pressed against said rotary heating member via said transfer medium.

35. The image-forming method according to claim 34, wherein said toner has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, a number-average molecular weight of from 1,000 to 40,000 and a weight-average molecular weight of from 10,000 to 10,000,000.

36. The image-forming method according to claim 34, wherein said toner has, in molecular weight distribution measured by gel permeation chromatography of tetrahydrofuran-soluble matter in the toner, at least one main peak in the region of molecular weight of from 4,000 to 30,000.

37. The image-forming method according to claim 36, wherein, in said molecular weight distribution, the peak area in the region of molecular weight of 30,000 or lower is in a proportion of from 60% to 100% with respect to the total peak area.

38. The image-forming method according to claim 34, wherein said binder resin of said toner contains a tetrahydrofuran-insoluble matter in an amount of from 0.1% by weight to 60% by weight.

39. The image-forming method according to claim 34, wherein said toner has a THF-soluble matter having an acid value of from 0.1 mg·

KOH/g to 50 mg·

KOH/g.

40. The image-forming method according to claim 34, wherein said colorant is a magnetic material.

41. The image-forming method according to claim 40, wherein said magnetic material is a magnetic iron oxide containing at least one element A belonging to the third and following periods of the long form of the periodic table and having an electronegativity of from 1.0 to 2.5;

said element A being contained in said magnetic material in a content of from 0.1% by weight to 4.0% by weight on the basis of Fe in said magnetic material; and

said magnetic material standing liberated into the toner in a number of from 70 particles to 500 particles per 10,000 toner particles.

42. The image-forming method according to claim 41, wherein said element A is an element selected from the group consisting of Al, Si, P, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Zr, Sn and Pb.

43. The image-forming method according to claim 41, wherein said element A is an element selected from the group consisting of Al, Si, Ti, Mn and Zn.

44. The image-forming method according to claim 40, wherein said magnetic material is contained in an amount of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of the binder resin.