Electrophotographic image forming method and apparatus

• US 6,670,089 B2
• Filed: 01/11/2002
• Issued: 12/30/2003
• Est. Priority Date: 01/11/2001
• Status: Expired due to Fees

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Aoike, Tatsuyuki, Ehara, Toshiyuki, Miura, Masaharu, Hashizume, Junichiro
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US10/042,370
• Publication Number:
  US 20020150831A1
• Time in Patent Office: 718 Days
• Field of Search: 430/126, 430/110.3, 430/66, 430/122, 399/159
• US Class Current: 430/123.41
• CPC Class Codes: G03G 5/08214 Silicon-based
• CPC Class Codes: G03G 5/08285 Carbon-based in ad mixture with Si G03G5/08214
• CPC Class Codes: G03G 5/14704 comprising inorganic material
• CPC Class Codes: G03G 9/0827 characterised by their shape, e.g. degree of sphericity
• CPC Class Codes: G03G 9/0835 Magnetic parameters of the magnetic components
• CPC Class Codes: G03G 9/0837 Structural characteristics of the magnetic components, e.g. shape, crystallographic structure

Abstract

An electrophotographic image forming method having cyclic steps including a charging step of charging a rotating image-bearing member to charge a surface thereof, a latent image forming steps of forming an electrostatic latent image on the charged surface of the image-bearing member, a developing step of developing the electrostatic latent image with a magnetic toner to form a toner image thereon, and a transfer step of transferring the toner image onto a recording material. In the method, the image-bearing member includes an electroconductive support, and a photoconductor layer and a surface layer formed on the support.

Claims

1. An electrophotographic image forming method, comprising cyclic steps including:

a charging step of charging a rotating image-bearing member to charge a surface thereof;

a latent image forming steps of forming an electrostatic latent image on the charged surface of the image-bearing member;

a developing step of developing the electrostatic latent image with a negatively chargeable magnetic toner to form a toner image thereon; and

a transfer step of transferring the toner image onto a recording material,

wherein the image-bearing member comprises an electroconductive support, and a photoconductor layer and a surface layer formed on the support, said photoconductor layer comprising a silicon-based non-single crystal material containing at least one of hydrogen and halogen, said surface layer comprising a carbon-based non-single crystal material containing at least one of hydrogen and halogen and also containing silicon in a proportion of 0.2 to 20 atm. % as calculated by Si/(Si+C),

said magnetic toner comprises toner particles comprising at least a binder resin and a magnetic material, and inorganic fine powder, has an average circularity of at least 0.950 and has a saturation magnetization of 10 to 50 Am²/kg as measured at 79.6 kA/m,

in the charging step, the image-bearing member is charged to a negative polarity by a contact charging means including charging particles comprising principally electroconductive particles having particle sizes of 0.1-10 μ

m, and a charging particle carrying member having an electroconductive and elastic surface and carrying the charging particles on the surface so as to contact the image-bearing member via the charging particles,

in the latent image forming step, an image forming part of the surface of the image-bearing member is exposed to light to provide an attenuated potential thereat, thereby forming the electrostatic latent image, and

no cleaning step is included between the transfer step and the charging step.

2. The method according to claim 1, wherein the image-bearing member further includes a buffer layer comprising a silicon-based non-single crystal material containing at least one of hydrogen and halogen and also at least one of carbon, oxygen and nitrogen between the photoconductive layer and the surface layer.

3. The method according to claim 1, wherein the surface layer is formed by a plasma chemical vapor deposition using a high frequency of 50-450 MHz wherein at least a hydrocarbon gas is decomposed by plasma to cause film deposition.

4. The method according to claim 1, wherein in the charging step, the image-bearing member is charged by bringing the charging particle-carrying member carrying the charging particles into contact with the image-bearing member via the charging particles in such a state that the surface of the charging particle-carrying member is moved while providing a relative speed difference with the surface of the image-bearing member.

5. The method according to claim 4, wherein the surface of the charging particle-carrying member and the surface of the image-bearing member are moved in mutually opposite directions to charge the image-bearing member in the charging step.

6. The method according to claim 1, wherein the charging particle-carrying member comprises an elastic member having a porous surface.

7. The method according to claim 1, wherein the charging particle-carrying member comprises a roller member having an Asker C hardness of at most 50 deg.

8. The method according to claim 1, wherein the charging particle-carrying member comprises a roller member having an Asker C hardness of 25-50 deg.

9. The method according to claim 1, wherein the charging particle-carrying member comprises a roller member having a volume-resistivity of 1×

10³-1×

10⁸ ohm.cm.

10. The method according to claim 1, wherein the electroconductive particles have a volume-resistivity of at most 1×

10⁹ ohm.cm.

11. The method according to claim 1, wherein the electroconductive particles have a volume-resistivity of 1×

10¹-1×

10⁹ ohm.cm.

12. The method according to claim 1, wherein the toner has the electroconductive particles at its surface.

13. The method according to claim 1, wherein the inorganic fine powder has been subjected to hydrophobicity-imparting treatment.

14. The method according to claim 13, wherein the inorganic fine powder has been treated with a silicone oil.

15. The method according to claim 1, wherein the electroconductive particles are attached onto the surface of the image-bearing member in the developing step and remain thereon even after the transfer step to be conveyed to reach the charging particle-carrying member.

16. An electrophotographic image forming apparatus, comprising:

a rotating image-bearing member;

a charging means for charging the rotating image-bearing member to charge a surface thereof;

a latent image forming means for forming an electrostatic latent image on the charged surface of the image-bearing member;

a developing means for developing the electrostatic latent image with a negatively chargeable magnetic toner to form a toner image thereon; and

a transfer means for transferring the toner image onto a recording material,

wherein the image-bearing member comprises an electroconductive support, and a photoconductor layer and a surface layer formed on the support;

said photoconductor layer comprising a silicon-based non-single crystal material containing at least one of hydrogen and halogen, said surface layer comprising a carbon-based non-single crystal material containing at least one of hydrogen and halogen and also containing silicon in a proportion of 0.2 to 20 atm. % as calculated by Si/(Si+C),

said magnetic toner comprises toner particles comprising at least a binder resin and a magnetic material, and inorganic fine powder, has an average circularity of at least 0.950 and has a saturation magnetization of 10 to 50 Am²/kg as measured at 79.6 kA/m,

the charging means includes charging particles comprising principally electroconductive particles having particle sizes of 0.1-10 μ

m, and a charging particle-carrying member carrying the charging particles so as to contact the image-bearing member via the charging particles, thereby charging the image-bearing member to a negative polarity,

the latent image-forming means includes an exposure means for exposing an image forming part of the image-bearing member to provide an attenuated potential thereat, and

no cleaning means is present between the transfer means and the charging means along the surface of the image-bearing member.

17. The apparatus according to claim 16, wherein the image-bearing member further includes a buffer layer comprising a silicon-based non-single crystal material containing at least one of hydrogen and halogen and also at least one of carbon, oxygen and nitrogen between the photoconductive layer and the surface layer.

18. The apparatus according to claim 16, wherein the surface layer is formed by a plasma chemical vapor deposition using a high frequency of 50-450 MHz wherein at least a hydrocarbon gas is decomposed by plasma to cause film deposition.

19. The apparatus according to claim 16, wherein the image-bearing member is charged by bringing the charging particle-carrying member carrying the charging particles into contact with the image-bearing member via the charging particles in such a state that the surface of the charging particle-carrying member is moved while providing a relative speed difference with the surface of the image-bearing member.

20. The apparatus according to claim 19, wherein the surface of the charging particle-carrying member and the surface of the image-bearing member are moved in mutually opposite directions to charge the image-bearing member.

21. The apparatus according to claim 16, wherein the charging particle-carrying member comprises an elastic member having a porous surface.

22. The apparatus according to claim 16, wherein the charging particle-carrying member comprises a roller member having an Asker C hardness of at most 50 deg.

23. The apparatus according to claim 16, wherein the charging particle-carrying member comprises a roller member having an Asker C hardness of 25-50 deg.

24. The apparatus according to claim 16, wherein the charging particle-carrying member comprises a roller member having a volume-resistivity of 1×

10³-1×

10⁸ ohm.cm.

25. The apparatus according to claim 16, wherein the electroconductive particles have a volume-resistivity of at most 1×

10⁹ ohm.cm.

26. The apparatus according to claim 16, wherein the electroconductive particles have a volume-resistivity of 1×

10¹-1×

10⁹ ohm.cm.

27. The apparatus according to claim 16, wherein the toner has the electroconductive particles at its surface.

28. The apparatus according to claim 16, wherein the inorganic fine powder has been subjected to hydrophobicity-imparting treatment.

29. The apparatus according to claim 28, wherein the inorganic fine powder has been treated with a silicone oil.

30. The apparatus according to claim 16, wherein the electroconductive particles are attached onto the surface of the image-bearing member in the developing step and remain thereon even after the transfer step to be conveyed to reach the charging particle-carrying member.