Efficiency water desalination/purification

• US 6,673,249 B2
• Filed: 11/15/2001
• Issued: 01/06/2004
• Est. Priority Date: 11/22/2000
• Status: Expired due to Fees

• Current Assignee: Marine Desalination Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael D.
• Primary Examiner(s): Hoey, Betsey Morrison
• Application Number:
  US09/987,725
• Publication Number:
  US 20020060192A1
• Time in Patent Office: 782 Days
• Field of Search: 210/747, 210/750, 210/170, 210/188, 210/198.1, 625/32, 626/18, 626/32, 626/35, 203/10, 585/15
• US Class Current: 210/747.5
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: E21B 41/0099 specially adapted for drilling for or production of natural hydrate or clathrate gas reservoirs; Drilling through or monitoring of formations containing gas hydrates or clathrates
• CPC Class Codes: Y02A 20/124 Water desalination

Abstract

Various methods and apparatus for maximizing the efficiency of hydrate-based desalination or other water purification in open-water or partially open-water installations are disclosed. In one embodiment, water is accessed from depth where the ambient temperature is as cold as possible, which depth is other than the maximum depth of the hydrate fractionation column used in the process. The accessed water preferably is brought to reduced pressures so that gases other than hydrate-forming gases that are dissolved in the water to be treated are exsolved. Using pre-pressurized sources of hydrate-forming substances, including deep-sea natural gas deposits or supplies of liquified natural gas being transported by sea, are also disclosed. A multiple column, detachable column fractionation installation is disclosed, as is a hybrid installation having an underwater hydrate formation portion and a land-based dissociation and heat-exchange section.

Claims

1. A method of desalinating or otherwise purifying water to be treated in a hydrate-based, desalination or purification installation located in a naturally occurring body of water, said installation extending downward and having a lower, hydrate formation region disposed at a hydrate formation region depth, said method comprising:

drawing water to be treated from a depth other than the hydrate formation region depth, the temperature of ambient water at the depth from which the water to be treated is drawn being lower than the temperature of ambient water at the hydrate formation region depth;

conveying and delivering the water to be treated to a hydrate formation region of said installation and introducing a gas hydrate-forming substance into said water to be treated in said hydrate formation region, the temperature of said water to be treated and the pressure within said hydrate formation region being conducive to formation of hydrate of said gas hydrate-forming substance, said gas hydrate-forming substance being introduced in a manner such that said hydrate is, at least in toto, positively buoyant;

allowing said hydrate to rise into an upper region of the installation and dissociate into said gas hydrate-forming substance and fresh or purified water; and

collecting said fresh or purified water.

2. The method of claim 1, wherein the depth from which said water to be treated is drawn is less than said hydrate formation region depth.

3. The method of claim 1, wherein said water to be treated is degassed before being delivered to the hydrate formation region of said installation by being conveyed upward to a depth that is less than the depth from which it was drawn, whereby gas dissolved in said water to be treated is exsolved from said water to be treated.

4. The method of claim 3, wherein said water to be treated is degassed by being conveyed upward toward the surface of the body of water and then is conveyed downward before being delivered to said hydrate formation region.

5. The method of claim 4, further comprising pre-treating said water to be treated before it is delivered to the hydrate formation region of said installation by introducing an initial amount of pre-treatment gas hydrate-forming substance into said water to be treated.

6. The method of claim 3, further comprising pre-treating said water to be treated before it is delivered to the hydrate formation region of said installation by introducing an initial amount of pre-treatment gas hydrate-forming substance into said water to be treated.

7. The method of claim 1, further comprising pre-treating said water to be treated before it is delivered to the hydrate formation region of said installation by introducing an initial amount of pre-treatment gas hydrate-forming substance into said water to be treated.

8. The method of claim 1, further comprising varying the depth from which said water to be treated is drawn as the temperature of ambient water at the depth from which said water to be treated is drawn varies.

9. The method of claim 1, further comprising capturing and recycling said gas hydrate-forming substance in a further cycle of hydrate-based desalination or water purification.

10. The method of claim 1, further comprising cooling said water to be treated before delivering said water to be treated to the hydrate formation region of the installation.

11. A method of desalinating or otherwise purifying water to be treated in a hydrate-based, desalination or purification installation, said installation being located in a naturally occurring body of water, said method comprising:

drawing water to be treated and degassing said water to be treated by conveying said water to be treated upward to a depth that is less than the depth from which said water to be treated was drawn such that gas dissolved in said water to be treated is exsolved from said water to be treated;

conveying and delivering said water to be treated to a hydrate formation region of said installation and introducing a gas hydrate-forming substance into said water to be treated in said hydrate formation region under pressure and temperature conditions conducive to formation of hydrate of said gas hydrate-forming substance, said gas hydrate-forming substance being introduced in a manner such that said hydrate is, at least in toto, positively buoyant;

allowing said hydrate to rise into an upper region of said installation and dissociate into said gas hydrate-forming substance and fresh or purified water; and

collecting said fresh or purified water.

12. The method of claim 11, wherein said water to be treated is degassed by being conveyed upward toward the surface of the body of water and then is conveyed downward and delivered to said hydrate formation region.

13. The method of claim 12, further comprising pre-treating said water to be treated before it is delivered to the hydrate formation region of said installation by introducing an initial amount of pre-treatment gas hydrate-forming substance into said water to be treated.

14. The method of claim 12, further comprising cooling said water to be treated before delivering said water to be treated to the hydrate formation region of said installation.

15. Apparatus for desalinating or otherwise purifying water to be treated using a gas hydrate-forming substance, said apparatus comprising:

a fractionation column located within a naturally occurring body of water, said fractionation column having

1) a lower, hydrate formation region disposed at a hydrate formation region depth, where pressure is conducive to formation of hydrate of the gas hydrate-forming substance, and

2) an upper, hydrate dissociation region;

a water intake system extending to and configured to draw water to be treated from a depth other than said hydrate formation region depth, the temperature of ambient water at the depth from which the water to be treated is drawn being lower than the temperature of ambient water at the hydrate formation region depth, said water intake system being configured to convey and introduce the water to be treated into the hydrate formation region of said fractionation column; and

a gas hydrate-forming substance introduction system configured and disposed to introduce the gas hydrate-forming substance into the water to be treated in said hydrate formation region.

16. The apparatus of claim 15, wherein said water intake system draws the water to be treated from a depth that is less than said hydrate formation region depth.

17. The apparatus of claim 15, wherein said water intake system extends upward, from the depth at which the water to be treated is drawn toward the surface of the body water, then downward to said hydrate formation region.

18. The apparatus of claim 15, further comprising a pre-treatment system configured to introduce an initial amount of pre-treatment gas hydrate-forming substance into the water to be treated before the water to be treated is introduced into said hydrate formation region.

19. The apparatus of claim 15, wherein said water intake system is configured such that the depth from which said water intake system draws the water to be treated can be varied.

20. The apparatus of claim 19, wherein said water intake system comprises a duct having multiple, selectively openable orifices disposed at different water depths along the length of said duct.

21. Apparatus for desalinating or otherwise purifying water to be treated using a gas hydrate-forming substance, said apparatus comprising:

a fractionation column located within a naturally occurring body of water, said fractionation column having

1) a lower, hydrate formation region disposed at a hydrate formation region depth, where pressure is conducive to formation of hydrate of the gas hydrate-forming substance, and

2) an upper, hydrate dissociation region;

a water intake system configured to draw in water to be treated, convey the water to be treated upward, and subsequently introduce the water to be treated into the hydrate formation region of said fractionation column, said water intake system having a gas release by means of which gas is exsolved from the water to be treated is released from said water intake system; and

a gas hydrate-forming substance introduction system configured and disposed to introduce the gas hydrate-forming substance into the water to be treated in said hydrate formation region.

22. The apparatus of claim 21, wherein said water intake system extends upward, from the depth at which the water to be treated is drawn toward the surface of the body water, then downward to said hydrate formation region.

23. The apparatus of claim 21, further comprising a pre-treatment system configured to introduce an initial amount of pre-treatment gas hydrate-forming substance into the water to be treated before the water to be treated is introduced into said hydrate formation region.

24. A method of desalinating or otherwise purifying water to be treated in a hydrate-based, desalination or purification installation using a gas hydrate-forming substance, said method comprising:

introducing water to be treated into a hydrate formation region of said installation, water pressure and temperature in said hydrate formation region being conducive to formation of hydrate of said gas hydrate-forming substance;

obtaining said gas hydrate-forming substance from a pre-pressurized source and introducing said gas hydrate-forming substance into said water to be treated in said hydrate formation region in a manner which causes hydrate of said gas hydrate-forming substance to form which is, at least in toto, positively buoyant;

allowing said hydrate to rise into an upper region of the installation and dissociate into said gas hydrate-forming substance and fresh or purified water;

collecting said fresh or purified water released upon dissociation of said hydrate; and

passing said gas hydrate-forming substance to a downstream application without reusing said gas hydrate-forming substance in another cycle of desalination or purification.

25. The method of claim 24, wherein said gas hydrate-forming substance is methane and said obtaining comprises obtaining said methane from an underwater deposit of methane.

26. The method of claim 24, wherein said gas hydrate-forming substance is natural gas;

said natural gas is obtained and introduced into said hydrate formation region in liquified form;

said hydrate dissociates into pure water and gaseous natural gas; and

said natural gas is passed to said downstream application in gaseous form.

27. The method of claim 26, wherein said installation is located in a naturally occurring body of water and said liquified natural gas is delivered to said installation by boat.

28. The method of claim 27, wherein said gaseous natural gas is passed ashore.

29. A method of vaporizing natural gas originally in liquified form, said method comprising:

injecting said liquified natural gas into a body of water under temperature and pressure conditions conducive to formation of natural gas hydrate;

allowing said natural gas hydrate to rise and dissociate into water and gaseous natural gas; and

passing said gaseous natural gas to a downstream application without reusing said natural gas in another cycle of hydrate formation and dissociation.

30. The method of claim 29, wherein said body of water is a body of saltwater or otherwise polluted water;

said hydrate dissociates into said gaseous natural gas and fresh or purified water; and

said fresh or purified water is collected for downstream use.

31. Apparatus for desalinating or otherwise purifying water to be treated using a gas hydrate-forming substance, said apparatus comprising:

a plurality of fractionation columns each having

1) a lower, hydrate formation region disposed at a depth where pressure is conducive to formation of hydrate of the gas hydrate-forming substance, and

2) an upper, hydrate dissociation region;

a gas hydrate-forming substance introduction system configured and disposed to introduce the gas hydrate-forming substance into water to be treated disposed within the hydrate formation regions of said fractionation columns; and

a common water collection section from which each of said plurality of fractionation columns depends, said water collection section communicating with the upper, hydrate dissociation regions of said plurality of fractionation columns;

whereby gas hydrate formed in the hydrate formation regions said fractionation columns rises into said upper, hydrate dissociation regions of said columns and releases fresh or purified water and the gas hydrate-forming substance, and whereby the released fresh or purified water from each of said plurality of fractionation columns is collected in said common water collection section.

32. The apparatus of claim 31,

wherein said apparatus is disposed in a naturally occurring body of water; and

wherein said fractionation columns are open to said body of water such that water flows naturally into the hydrate formation regions thereof.

33. The apparatus of claim 32, wherein said fractionation columns and said common water collection section are cooperatively configured such that at least some of said plurality of fractionation columns can be removed from said common water collection section and said apparatus can be operated to desalinate or purify water with said at least some of said plurality of fractionation columns removed.

34. A hybrid installation for desalinating or otherwise purifying water to be treated using a gas hydrate-forming substance, said apparatus comprising:

a hydrate formation installation disposed within a naturally occurring body of water, generally near an above-water landmass, said hydrate formation installation having a hydrate formation region configured to receive water from said naturally occurring body of water and disposed at a depth where pressure and temperature conditions are conducive to formation of hydrate of the gas hydrate-forming substance;

a hydrate dissociation and water collection installation disposed above water on said above-water landmass; and

a connector assembly establishing communication between said hydrate formation installation and said hydrate dissociation and water collection installation;

whereby gas hydrate is formed in said hydrate formation installation upon introducing the gas hydrate-forming substance into said hydrate formation region;

said gas hydrate rises through said connector assembly into said hydrate dissociation and water collection installation; and

said gas hydrate dissociates into fresh or purified water and the gas hydrate-forming substance in said hydrate dissociation and water collection installation.

35. The installation of claim 34, wherein said hydrate formation installation includes a salinity and thermal equilibration section in which heated residual water is replaced by ambient water from the naturally occurring body of water.

36. The installation of claim 34, wherein said connector assembly has at least one flow constrictor by means of which flow through said connector assembly can be interrupted.

37. The installation of claim 36, wherein said connector assembly has two flow constrictors such that a slug of hydrate-rich slurry can be formed therebetween for batch-mode introduction into said hydrate dissociation and water collection installation.

38. The installation of claim 34, wherein said hydrate dissociation and water collection installation comprises at least one pressurized vessel in which the gas hydrate dissociates under pressure-controlled conditions.