Method and materials for preventing warping in optical films

• US 6,673,425 B1
• Filed: 10/27/2000
• Issued: 01/06/2004
• Est. Priority Date: 10/27/2000
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Hebrink, Timothy J., Ouderkirk, Andrew J.
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US09/698,717
• Time in Patent Office: 1,166 Days
• Field of Search: 428/480, 428/483, 428/212, 428/216, 428/910, 428/141, 428/156, 428/172, 156/244.11, 156/297, 156/244.24, 156/299, 264/173.11, 264/173.12, 264/173.15, 264/173.16, 264/171.13, 264/171.23, 264/509, 359/586, 359/577, 359/580
• US Class Current: 428/212
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 156/1089 of discrete laminae to single face of additional lamina
• CPC Class Codes: Y10T 156/1092 All laminae planar and face to face
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/24612 Composite web or sheet
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A multilayer optical body having improved dimensional stability is disclosed. The optical body includes an optical film, such as an oriented multilayer optical film, and a dimensionally stable layer, such as a transparent polycarbonate layer. In addition, in specific implementations, the invention includes an intermediate layer between the optical film and the dimensionally stable layer. Methods of making the optical body are also disclosed.

Claims

1. A multilayer optical body comprising:

an optical film;

an extrudable thermoplastic polymeric layer secured to the optical film; and

a flexible, dimensionally stable layer secured to the polymeric layer, wherein the dimensionally stable layer comprises polystyrene or a polystyrene copolymer and the dimensionally stable layer is configured and arranged to permit cycling the optical body through temperatures of −

30°

C. and 85°

C. every 1.5 hours for 400 hours without warping.

2. The mutlilayer optical body of claim 1, wherein the optical film comprises an oriented optical film.

3. The multilayer optical body of claim 2, wherein the optical film is oriented independently of the polymeric layer and dimensionally stable layer.

4. The multilayer optical body of claim 2, wherein the optical film is oriented simultaneously with the polymeric layer and dimensionally stable layer.

5. The multilayer optical body of claim 1, wherein the optical film comprises multiple layers.

6. The multilayer optical body of claim 5, wherein at least one layer of the optical film comprises polyester.

7. The multilayer optical body of claim 6, wherein the polyester is selected from the group consisting of CoPEN and CoPET.

8. The multilayer optical body of claim 1, wherein the polymeric layer is thermally stable in the melt phase at a temperature above 250°

C.

9. The multilayer optical body of claim 1, wherein the polymeric layer comprises polyester.

10. The multilayer optical body of claim 9, wherein the polymeric layer comprises CoPEN, CoPET, or combinations thereof.

11. The multilayer optical body of claim 1, wherein the polymeric layer is transparent.

12. The multilayer optical body of claim 1, wherein the polymeric layer has a refractive index from 1.55 to 1.62.

13. The multilayer optical body of claim 1, wherein the polymeric layer has a refractive index within 0.06 of the refractive index of the dimensionally stable layer.

14. The multilayer optical body of claim 1, wherein the polymeric layer has a refractive index between the refractive index of the optical film and the dimensionally stable layer.

15. The multilayer optical body of claim 1, wherein the polystyrene copolymer is selected from the group styrene acrylonitrile, styrene methyl methacrylate, acrylonitrile butadiene styrene, and combinations thereof.

16. The mutlilayer optical body of claim 1, wherein the dimensionally stable layer is formed by extrusion.

17. The multilayer optical body of claim 16, wherein the dimensionally stable layer and polymeric layer are formed by coextrusion onto the optical film.

18. The multilayer optical body of claim 1, wherein the dimensionally stable layer has a thickness in the range of 0.5 to 10 mils.

19. The multilayer optical body of claim 1, wherein the dimensionally stable layer comprises the copolymer of polystyrene and the copolymer of polystyrene comprises butadiene monomer units.

20. The multilayer optical body of claim 1, wherein the dimensionally stable layer is configured and arranged to diffuse light passing through the dimensionally stable layer.

21. The multilayer optical body of claim 1, wherein dimensionally stable layer a comprises a surface configured and arranged in a diffuse pattern.

22. The multilayer optical body of claim 1, wherein the surface of the dimensionally stable layer is embossed to form a diffuse pattern.

28. The multilayer optical body of claim 20, further comprising:

a polymeric layer secured to the optical film, the polymeric layer having a glass transition temperature greater than 80°

C.

29. The multilayer optical body of claim 28, wherein the polymeric layer comprises polyester.

30. The multilayer optical body of claim 28, wherein the polymeric layer comprises CoPEN containing naphthalene dicarboxylic acid, and dimethyl terepthalate.

31. The multilayer optical body of claim 28, wherein the polymeric layer has a refractive index of 1.56 to 1.62.

32. The multilayer optical body of claim 28, wherein the polymeric layer has a refractive index within 0.06 of the refractive index of the dimensionally stable layer.

33. The multilayer optical body of claim 28, wherein the polymeric layer has a refractive index between the refractive index of the optical film and the dimensionally stable layer.

23. A multilayer optical body comprising:

an oriented optical film; and

a dimensionally stable layer comprising an acrylonitrile butadiene styrene copolymer.

24. The multilayer optical body of claim 23, wherein the optical film comprises multiple layers.

25. The multilayer optical body of claim 24, wherein at least one layer of the optical film comprises polyester.

26. The multilayer optical body of claim 25, wherein the polyester is selected from the group consisting of PEN, CoPEN, PET, CoPET, and combinations thereof.

27. The multilayer optical body of claim 23, wherein the optical film comprises multiple alternating layers comprising PEN and CoPEN.

34. The multilayer optical body of claim 23, wherein the dimensionally stable layer has a thickness in the range of 0.5 to 10 mils.

35. The multilayer optical body of claim 23, wherein the dimensionally stable layer is configured and arranged to diffuse light passing through the dimensionally stable layer.

36. The multilayer optical body of claim 23, wherein dimensionally stable layer comprises a surface configured and arranged in a diffuse pattern.

37. The multilayer optical body of claim 23, wherein the surface of the dimensionally stable layer is embossed to form a diffuse pattern.

38. A method of forming a warp-resistant optical body, the method comprising:

providing a first film comprising an optical film;

forming a second film comprising a thermoplastic polymeric material having a glass transition temperature greater than 85°

C.;

forming a third film, wherein the third film comprises a dimensionally stable layer that comprises an acrylonitrile butadiene styrene copolymer; and

adhering the first film to the second film, and the second film to the third film, to form a dimensionally stable optical body.

39. The method of claim 38, wherein the optical film is an oriented optical film.

40. The method of claim 38, further comprising orienting the optical film prior to forming the second film and third film.

41. The method of claim 38, further comprising orienting the optical film after forming the second film and third film.

42. The method of claim 38, wherein the second film and third film are extruded.

43. The method of claim 42, wherein the second film and third film are coextruded.

44. The method of claim 38, wherein the optical film comprises multiple layers.

45. The method of claim 44, wherein at least one layer of the optical film comprises polyester.

46. The method of claim 38, wherein the second film comprises polyester.

47. The method of claim 38, wherein the second film comprises a polymeric material selected from the group consisting of CoPEN, CoPET, and combinations thereof.

48. The method of claimn 38, further comprising forming a diffuse pattern on at least a portion of a surface of the dimensionally stable layer of the third film.

49. The method of claim 48, wherein forming a diffuse pattern comprises embossing the portion of the surface of the dimensionally stable layer of the third film to form the diffuse pattern.

50. A method of forming a warp-resistant optical body, the method comprising:

providing an optical film; and

coating the optical film by coextruding a thermoplastic polymeric layer and a dimensionally stable layer onto the optical film, wherein the dimensionally stable layer comprises polystyrene or a polystyrene copolymer and the dimensionally stable layer is configured and arranged to permit cycling of the optical body through temperatures of −

30°

C. and 85°

C. every 1.5 hours for 400 hours without warping.

51. The method of claim 50, further comprising orienting the optical film.

52. The method of claim 51, wherein the optical film is oriented prior to coating the film with the thermoplastic polymeric layer and the dimensionally stable layer.

53. The method of claim 50, wherein the thermoplastic polymeric layer comprises a polymeric material selected from CoPEN, CoPET, and combinations thereof.

54. The method of claim 50, further comprising forming a diffuse pattern on at least a portion of a surface of the dimensionally stable layer.

55. The method of claim 54, wherein forming a diffuse pattern comprises embossing the portion of the surface of the dimensionally stable layerto form the diffuse pattern.

56. The method of claim 50, wherein the dimensionally stable layer further comprises a polyester material selected from CoPEN, CoPET, and combinations thereof.

57. The method of clain 56, wherein the dimensionally stable layer comprises 1 to 30 wt. % of the polyester material.

58. A method of forming a warp-resistant optical body, the method comprising:

providing an optical film; and

securing a dimensionally stable layer to the optical film, wherein the dimensionally stable layer comprises polystyrene or a polystyrene copolymer and the dimensionally stable layer is configured and arranged to permit cycling of the optical body through temperatures of −

30°

C. and 85°

C. every 1.5 hours for 400 hours without warping.

59. The method of claim 58, wherein securing the dimensionally stable layer to the optical film comprises coextruding the dimensionally stable layer with the optical film.

60. The method of claim 58, wherein securing the dimensionally stable layer to the optical film comprises securing an extrudable thermoplastic polymeric layer to the optical film and securing the dimensionally stable layer to the extrudable thermoplastic polymeric layer.

61. The method of claim 60, wherein securing the extrudable thermoplastic polymeric layer to the optical film and securing the dimensionally stable layer to the extrudable thermoplastic polymeric layer comprise coextruding the extrudable thermoplastic polymer layer and dimensionally stable layer onto the optical film.

62. The method of claim 58, further comprising forming a diffuse pattern on at least a portion of a surface of the dimensionally stable layer.

63. The method of claim 62, wherein forming a diffuse pattern comprises embossing the portion of the surface of the dimensionally stable layer that to form the diffuse layer.

64. A multilayer optical body comprising:

an optical film; and

a flexible, dimensionally stable layer disposed on the optical film, wherein the dimensionally stable layer comprises a dimensionally stable material selected from polystyrene and polystyrene copolymers blended with a polyester material selected from CoPEN, CoPET, or combinations thereof.

65. The multilayer optical body of claim 64, wherein the dimensionally stable layer comprises 1 to 30 wt. % of the polyester material.

66. The multilayer optical body of claim 65, wherein the dimensionally stable layer comprises 5 to 20 wt. % of the polyester material.