Sensor cell for an electrochemical fuel cell stack

• US 6,673,480 B1
• Filed: 02/23/2001
• Issued: 01/06/2004
• Est. Priority Date: 07/02/1998
• Status: Expired due to Fees

• Current Assignee: Ballard Power Systems Corporation (Superior Plus Corporation)
• Original Assignee: Ballard Power Systems Corporation (Superior Plus Corporation)
• Inventors: Wilkinson, David P., Knights, Shanna D., Lauritzen, Michael V.
• Primary Examiner(s): Gulakowski, Randy
• Assistant Examiner(s): Crepeau, Jonathan
• Application Number:
  US09/719,829
• Time in Patent Office: 1,047 Days
• Field of Search: 429/13, 429/22, 429/23, 429/24
• US Class Current: 429/430
• CPC Class Codes: H01M 8/023 Porous and characterised by the material
• CPC Class Codes: H01M 8/0263 having meandering or serpentine paths
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: H01M 8/0269 Separators, collectors or interconnectors including a printed circuit board
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/0432 Temperature; Ambient temperature
• CPC Class Codes: H01M 8/04873 of the individual fuel cell
• CPC Class Codes: H01M 8/04902 of the individual fuel cell
• CPC Class Codes: H01M 8/04951 of the individual fuel cell
• CPC Class Codes: H01M 8/1011 Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: H01M 8/2484 characterised by external manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrochemical fuel cell stack includes a plurality of fuel cells. At least one of the fuel cells is a sensor cell. The sensor cell has at least one structural dissimilarity with respect to the remaining fuel cells of the plurality. The structural dissimilarity may include, for example, a reduced sensor cell electrochemically active area, reduced electrocatalyst loading, modified anode or cathode flow field, different electrocatalyst composition, or a modified coolant flow field configuration. The sensor cell operates under substantially the same conditions as the remaining cells in the stack. However, in response to a change in a particular stack operating condition, an electrical or thermal response, preferably a voltage change, is induced in the sensor cell which is not simultaneously induced in the remaining fuel cells. Thus, the sensor cell can detect undesirable conditions and its response can be used to initiate corrective action. More than one sensor cell, specific to different types of conditions, may be employed in the stack. In the absence of undesirable conditions, the sensor cell can function as a power-producing fuel cell.

Claims

1. In an electrochemical fuel cell stack comprising a plurality of fuel cells, each of said fuel cells comprising an anode comprising an anode electrocatalyst, a cathode comprising a cathode electrocatalyst, and an ion exchange membrane interposed between said anode and said cathode, the improvement comprising:

at least one of said plurality of fuel cells being a sensor cell having at least one structural dissimilarity with respect to the remaining fuel cells of said plurality, wherein during operation of said stack, said structural dissimilarity induces at least one of an electrical and thermal process in said sensor cell which is not simultaneously induced in said remaining fuel cells under substantially the same operating conditions; and

wherein during operation of said stack, said sensor cell and at least one of said remaining cells are connected to a comparator for comparing said electrical or thermal response of said sensor cell with that of said at least one of said remaining cells.

2. The improved fuel cell stack of claim 1, wherein, during operation of said stack, each of said anodes has a fuel stream directed thereto along an anode flow field, each of said cathodes has an oxidant stream directed thereto along a cathode flow field, each of said fuel stream and said oxidant stream have an inlet pressure and a stoichiometry associated therewith, and each of said plurality of fuel cells generate an electric current per cathode unit area, product water at said cathode and heat at a nominal operating temperature, and wherein said structural dissimilarity induces at least one of an electrical and thermal response in said sensor cell which is not simultaneously induced in said remaining fuel cells under substantially the same operating conditions of fuel and oxidant stream inlet pressure and stoichiometry.

3. The improved fuel cell stack of claim 1 wherein, during operation of said stack, said sensor cell and said remaining cells provide electrical power.

4. The improved fuel cell stack of claim 1 wherein during operation of said stack a variable electrical load is applied across said fuel cell stack comprising said sensor cell.

5. The improved fuel cell stack of claim 1 wherein said plurality of fuel cells are manifolded to be supplied with reactants in a parallel supply configuration.

6. The improved fuel cell stack of claim 1 wherein said at least one response is a voltage change in said sensor cell.

7. The improved fuel cell stack of claim 1 wherein said at least one response is a change in electric current per cathode unit area in said sensor cell.

8. The improved fuel cell stack of claim 1 wherein said at least one response is a change in the voltage distribution within a component of said sensor cell.

9. The improved fuel cell stack of claim 1 wherein said at least one response is a change in electrical resistance in said sensor cell.

10. The improved fuel cell stack of claim 1 wherein said at least one response is a temperature change in said sensor cell.

11. The improved fuel cell stack of claim 1 wherein said structural dissimilarity comprises at least one of said anode and said cathode in said sensor cell having an electrochemically active area less than the electrochemically active areas of said remaining fuel cells.

12. The improved fuel cell stack of claim 1 wherein reactant access to at least one of said anode and cathode electrocatalysts in said sensor cell is impeded relative to in said remaining fuel cells.

13. The improved fuel cell stack of claim 1 wherein said structural dissimilarity comprises at least one of said anode and said cathode in said sensor cell having an electrocatalyst loading less than the electrocatalyst loading in said remaining fuel cells.

14. The improved fuel cell stack of claim 1 wherein said structural dissimilarity comprises a sensor cell anode flow field configuration which differs from the anode flow field configuration of said remaining said fuel cells.

15. The improved fuel cell stack of claim 14 wherein said sensor cell anode flow field configuration induces a pressure drop which is greater than the pressure drop induced in the anode flow field configuration of said remaining fuel cells.

16. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders comprises a sensor cell cathode flow field configuration which differs from the cathode flow field configuration of said remaining fuel cells.

17. The improved fuel cell stack of claim 16 wherein said sensor cell cathode flow field configuration induces a pressure drop along said flow field which is greater than the corresponding pressure drop induced in the cathode flow field configuration of said remaining fuel cells.

18. The improved fuel cell stack of claim 1 wherein the anode electrocatalyst in said sensor cell differs in composition from the anode electrocatalyst in said remaining fuel cells.

19. The improved fuel cell stack of claim 1 wherein the cathode electrocatalyst in said sensor cell differs in composition from the cathode electrocatalyst in said remaining fuel cells.

20. The improved fuel cell stack of claim 1 wherein each of said fuel cells has a coolant stream directed along the coolant flow field in thermal communication with said each of said fuel cells and wherein said structural dissimilarity comprises a sensor cell coolant flow field configuration which differs from the coolant flow field configuration of said remaining fuel cells.

21. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to fuel stoichiometry.

22. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to oxidant stoichiometry.

23. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to carbon monoxide poisoning.

24. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to air bleed level in said fuel stream.

25. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to operating temperature.

26. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to methanol poisoning.

27. The improved fuel cell stack of claim 1 wherein said fuel cell stack is a direct methanol fuel cell stack, and wherein said structural dissimilarity renders said sensor cell more sensitive to methanol concentration.

28. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to flooding.

29. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to dehydration.

30. The improved fuel cell stack of claim 1 wherein said structural dissimilarity renders said sensor cell more sensitive to mass transport phenomena.

31. A method of operating an electrochemical fuel cell stack comprising a fuel cell stack comprising a plurality of solid polymer fuel cells, at least one of said plurality of fuel cells being a sensor cell having at least one structural dissimilarity with respect to the remaining fuel cells of said plurality wherein, during operation of said stack, said structural dissimilarity induces at least one of an electrical and thermal response in said sensor cell which is not simultaneously induced in said remaining fuel cells under substantially the same operating conditions, said method comprising:

monitoring at least one of an electrical and thermal operating parameter of said sensor cell and the same parameter of at least one of said remaining cells;

comparing said monitored operating parameter of said sensor cell with that of said at least one remaining cell;

generating an output signal if said compared parameters differ by more than a predetermined threshold amount indicative of an undesirable operating condition.

32. The method of claim 31 wherein said monitored parameter is cell voltage.

33. The method of claim 31 wherein said monitored parameter is temperature.

34. The method of claim 31 wherein said monitored parameter is the rate of change of cell voltage.

35. The method of claim 31 wherein said output signal comprises issues a warning signal to alert the operator of said system.

36. The method of claim 31 wherein said output signal comprises recording said monitored parameters.

37. The method of claim 31 wherein said output signal initiates a corrective action to restore desirable operating conditions in said system.

38. The method of claim 31 wherein said monitoring is done continuously during operation of said stack.

39. The method of claim 31 wherein said monitoring is done periodically during operation of said stack.