Polymeric compositions and processes for providing weatherable film and sheet

• US 6,673,868 B2
• Filed: 04/27/2001
• Issued: 01/06/2004
• Est. Priority Date: 05/03/2000
• Status: Expired due to Term

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Choulet, Olivier Jacques
• Primary Examiner(s): MULLIS, JEFFREY C
• Application Number:
  US09/844,534
• Publication Number:
  US 20010049416A1
• Time in Patent Office: 984 Days
• Field of Search: 525/70, 525/71, 525/80
• US Class Current: 525/70
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence
• CPC Class Codes: C08L 51/04 grafted on to rubbers

Abstract

The present invention discloses polymeric compositions containing a vinylaromatic lubricating copolymer which can be melt processed to provide plastic films or layers having excellent optical, printing, weathering, and tensile impact resistance characteristics. The present invention also discloses a processes for preparing plastic films of the compositions of the present invention. The present invention also discloses composite articles having the plastic films of the present invention and an underlying substrate.

Claims

1. A polymeric composition, comprising:

(A) 100 parts by weight of an acrylic core-shell graft-co-polymer, comprising

(i) from 20% to 70% by weight of an acrylic rubbery core polymer, based on the total weight of the acrylic core-shell graft-co-polymer and

(ii) from 30% to 80% by weight of an acrylic hard shell polymer, based on the total weight of the acrylic core-shell graft-co-polymer wherein the acrylic hard shell polymer contains 80 to 99 parts by weight of units derived from at least one C1-C8 alkyl methacrylate monomer, based on 100 parts by weight of the acrylic hard shell polymer;

(B) based on 100 parts by weight of the acrylic core-shell polymer, from 1 to 40 parts by weight of a processing aid polymer, wherein the weight average molecular weight of the processing aid polymer is greater than 1 million g/mol and

(C) based on 100 parts by weight of the acrylic core-shell polymer, from 0.1 to 10 parts by weight of a VA lubricating copolymer, comprising

(i) from 20% to 70% by weight of polymerizable units derived from one or more vinyl aromatic monomers, based on the total weight of the VA lubricating copolymer and

(ii) from 30% to 80% by weight of polymerizable units derived from one or more ethylenically unsaturated monomers based on the total weight of the VA lubricating copolymer, wherein the weight average molecular weight of the VA lubricating polymer is in the range of from 20,000 g/mol to 1 million g/mol.

2. The composition of claim 1,

wherein the amount of the (B) processing aid polymer is in the range of from 1 to 25 parts by weight, based on 100 parts by weight of the acrylic core-shell polymer; and

the amount of the (C) VA lubricating copolymer is in the range of from 0.5 to 2.0 parts by weight, based on 100 parts by weight of the acrylic core-shell polymer.

3. The composition of claim 1, wherein

the percentage of the (i) core polymer of the (A) graft-co-polymer is in the range of from 30% to 60%, and

the percentage of the (ii) shell polymer of the (A) graft-co-polymer is in the range of from 40% to 70%.

4. The composition of claim 1, wherein the weight average molecular weight of the (B) processing aid polymer is in the range of from 1.5 million to 6 million g/mol.

5. The composition of claim 1, wherein the (C) VA lubricating copolymer is prepared by a multistage process.

6. The composition of claim 1, further comprising, based on 100 parts by weight of the acrylic core-shell polymer, up to 50 parts by weight of a second core-shell graft-co-polymer, which is compositionally different from the acrylic core-shell graft-co-polymer in component (A).

8. A plastic film prepared from the polymeric composition according to any one of claims 1 to 7.

9. A process for preparing a plastic film, comprising the steps of

(I) feeding the polymeric composition according to any one of claims 1 to 7 into a pre-melting device;

(II) heating the polymeric composition to a temperature of at least 1500C in the pre-melting device to form a gel;

(III) heating the gel to a temperature of at least 1700C to form a melt;

(IV) forming the melt into a molten film having a thickness in the range of from 30 to 2,000 microns; and

(V) cooling the molten film.

10. A composite article comprising the plastic film prepared according to the process of claim 9, the plastic film affixedly disposed onto at least one surface of a substrate layer, the substrate layer comprising one or more materials selected from the group consisting of thermoplastic resins, thermosets, adhesives, coatings, glasses, metals, ceramics, cellulosic materials and mixtures thereof.

7. A polymeric composition, comprising:

(A) 100 parts by weight of an acrylic core-shell graft-co-polymer, comprising

(i) from 35% to 45% by weight of an acrylic rubbery core polymer based on the total weight of the acrylic core-shell graft-co-polymer; and

(ii) from 55% to 65% by weight of an acrylic hard shell polymer based on the total weight of the acrylic core-shell graft-co-polymer;

wherein the acrylic hard shell polymer contains 80 to 99 parts by weight of units derived from at least one C1-C8 alkyl methacrylate monomer, based on 100 parts by weight of the acrylic hard shell polymer;

(B) based on 100 parts by weight of the acrylic core-shell polymer, from 2 to 25 parts by weight of a processing aid polymer, wherein the weight average molecular weight of the processing aid polymer is in the range of 1.5 to 6 million g/mol

(C) based on 100 parts by weight of the acrylic core-shell polymer, from 0.5 to 2 parts by weight of a VA lubricating copolymer, comprising

(i) from 20% to 70% by weight of polymerizable units derived from styrene, based on the total weight of the VA lubricating copolymer, and

(ii) from 30% to 80% by weight of polymerizable units selected from the group consisting of acrylonitrile, C1 to C8 alkyl acrylates, C1 to C4 alkyl methacrylates, and mixtures thereof, based on the total weight of the VA lubricating copolymer;

wherein the weight average molecular weight of the (C) VA lubricating polymer is in the range of from 50,000 to 800,000 g/mol; and

(D) based on 100 parts by weight of the acrylic core-shell polymer, from 5 to 50 parts by weight of a second core-shell graft-co-polymer, which is compositionally different from the acrylic core-shell graft-co-polymer in component (A).

11. A polymeric composition, consisting of:

(A) 100 parts by weight of an acrylic core-shell graft-co-polymer, comprising

(i) from 20% to 70% by weight of an acrylic rubbery core polymer based on the total weight of the acrylic core-shell graft-co-polymer and

(ii) from 30% to 80% by weight of an acrylic hard shell polymer based on the total weight of the acrylic core-shell graft-co-polymer wherein the acrylic hard shell polymer contains 80 to 99 parts by weight of units derived from at least one C1-C8 alkyl methacrylate monomer, based on 100 parts by weight of the acrylic hard shell polymer;

(B) based on 100 parts by weight of the acrylic core-shell polymer, from 1 to 40 parts by weight of a processing aid polymer, wherein the weight average molecular weight of the processing aid polymer is greater than 1 million g/mol;

(C) based on 100 parts by weight of the acrylic core-shell polymer, from 0.1 to 10 parts by weight of a VA lubricating copolymer, comprising

(i) from 20% to 70% by weight of polymerizable units derived from one or more vinyl aromatic monomers, based on the total weight of the VA lubricating copolymer; and

(ii) from 30% to 80% by weight of polymerizable units derived from one or more ethylenically unsaturated monomers based on the total weight of the VA lubricating copolymer,

wherein the weight average molecular weight of the VA lubricating polymer is in the range of from 20,000 g/mol to 1 million g/mol;

(D) an optional UV light stabilizer component; and

(E) an optional pigment component.

12. A polymeric composition, consisting of:

(A) 100 parts by weight of an acrylic core-shell graft-co-polymer, comprising

(i) from 20% to 70% by weight of an acrylic rubbery core polymer based on the total weight of the acrylic core-shell graft-co-polymer and

(ii) from 30% to 80% by weight of an acrylic hard shell polymer based on the total weight of the acrylic core-shell graft-co-polymer wherein the acrylic hard shell polymer contains 80 to 99 parts by weight of units derived from at least one C1-C8 alkyl methacrylate monomer, based on 100 parts by weight of the acrylic hard shell polymer;

(B) based on 100 parts by weight of the acrylic core-shell polymer, from 1 to 40 parts by weight of a processing aid polymer, wherein the weight average molecular weight of the processing aid polymer is greater than 1 million g/mol;

(C) based on 100 parts by weight of the acrylic core-shell polymer, from 0.1to 10 parts by weight of a VA lubricating copolymer, comprising

(i) from 20% to 70% by weight of polymerizable units derived from one or more vinyl aromatic monomers, based on the total weight of the VA lubricating copolymer and

(ii) from 30% to 80% by weight of polymerizable units derived from one or more ethylenically unsaturated monomers based on the total wei&

ht of the VA lubricating copolymer,

wherein the weight average molecular weight of the VA lubricating polymer is in the range of from 20,000 g/mol to 1 million g/mol;

(D) based on 100 parts by weight of the acrylic core-shell polymer, from 0 to 100 parts by weight of a second core-shell graft;

co polymer, which is compositionally different from the acrylic core-shell graft-co-polymer in component (A);

(E) an optional UV light stabilizer component; and

(F) an optional pigment component.