Method and apparatus for casting near-net shape articles

• US 6,676,381 B2
• Filed: 04/03/2002
• Issued: 01/13/2004
• Est. Priority Date: 04/03/2002
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Subramanian, Pazhayannur Ramanathan, Bewlay, Bernard Patrick, Jackson, Melvin Robert, Dupree, Paul Leonard, Evenden, Theodore McCall
• Primary Examiner(s): Look, Edward K.
• Assistant Examiner(s): McCoy, Kimya N
• Application Number:
  US10/063,249
• Publication Number:
  US 20030190235A1
• Time in Patent Office: 650 Days
• Field of Search: 164/519, 164/518, 164/517, 164/516, 164/361, 416/241.B, 416/241.R, 415/200
• US Class Current: 416/241.00B
• CPC Class Codes: B22D 27/04 Influencing the temperature of the metal, e.g. by heating or cooling the mould
• CPC Class Codes: F01D 5/28 Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
• CPC Class Codes: F05D 2230/21 by casting
• CPC Class Codes: F05D 2300/13 Refractory metals, i.e. Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W
• CPC Class Codes: Y02T 50/60 Efficient propulsion technologies, e.g. for aircraft

Abstract

A method and apparatus for casting a near-net-shape article from a high temperature material, such as a refractory metal intermetallic composite material. The apparatus includes: a means for forming a molten material comprising at least one of a metal and an alloy; a means for pouring the molten material; a mold assembly comprising a solid shell having a face coat interposed between the solid shell and molten material; and a heater assembly for maintaining the solid shell at a temperature. The molten material solidifies within the solid shell to form a near-net shape of the article. The near-net shape article may be a turbine assembly component, such as, but not limited to, a vane or airfoil.

Claims

1. An apparatus for casting an article, said apparatus comprising:

(a) a means for forming a molten material, said molten material comprising at least one of a metal and an alloy;

(b) a means for pouring said molten material from said means for forming said molten material, wherein said means for pouring said molten material includes a cup for receiving said molten material in a superheated state;

(c) a mold assembly for receiving said molten material from said cup, said mold assembly comprising a solid shell for containing said molten material, the shell having a face coat, wherein said face coat is disposed on an inner surface that contacts said molten material such that said face coat is interposed between said solid shell and said molten material, said face coat comprising at least one of an oxide, a silicide, a silicate, an oxysulfide, and a sulfide and containing at least one of a rare earth metal, a refractory metal, and combinations thereof, and a heater assembly for maintaining said solid shell at a predetermined temperature, wherein said molten material solidifies within said solid shell to form a near-net shape of said article.

2. The apparatus according to claim 1, wherein said refractory metal is one of hafnium and zirconium, and wherein said rare earth metal is one of yttrium, erbium, and cerium.

3. The apparatus according to claim 2, wherein said face coat has a melting temperature of at least about 1900°

C.

4. The apparatus according to claim 2, wherein said face coat comprises at least one of hafnia, erbia, zircon, yttria, ceria, zirconia and at least one stabilized zirconia.

5. The apparatus according to claim 2, wherein said face coat has a thickness from about 5 microns to about 100 microns.

6. The apparatus according to claim 5, wherein said face coat has a thickness from about 5 microns to about 50 microns.

7. The apparatus according to claim 2, wherein said face coat comprises at least one layer.

8. The apparatus according to claim 1, wherein said means for forming said molten material comprises one of an arc melter, an electron beam melter, and an induction skull melter.

9. The apparatus according to claim 8, wherein said arc melter is one of a plasma arc melter, a vacuum arc melter, and a vacuum arc remelter.

10. The apparatus according to claim 1, further including an enclosure for containing said means for forming said molten material, said means for pouring said molten material, and said mold assembly under one of a vacuum and an inert gas atmosphere.

11. The apparatus according to claim 1, wherein said means for forming said molten material comprises a means for forming a molten material having a melting temperature of at least 1500°

C.

12. The apparatus according to claim 11, wherein said molten material comprises silicon and at least one of niobium, titanium, molybdenum, and chromium.

13. The apparatus according to claim 1, wherein said means for forming said molten material includes a ceramic-free path for said molten material.

14. The apparatus according to claim 1, wherein said means for pouring includes one of a tilt-pour tundish and a bottom-pour tundish.

15. The apparatus according to claim 14, wherein said tilt-pour tundish further includes a lip for pouring said molten material into said cup.

16. The apparatus according to claim 14, wherein said bottom-pour tundish further includes an orifice therethrough for pouring said molten material into said cup.

17. The apparatus according to claim 1, wherein said cup comprises at least one of alumina, hafnia, yttria stabilized zirconia, zirconia, and yttrium aluminum garnet.

18. The apparatus according to claim 1, wherein said means for pouring further includes a heater for maintaining said molten material within said cup in said superheated state.

19. The apparatus according to claim 1, wherein said solid shell comprises at least one of alumina, hafnia, yttria stabilized zirconia, zirconia, and yttrium aluminum garnet.

20. The apparatus according to claim 1, wherein said heater assembly comprises at least one heating element, at least one temperature sensor for sensing a temperature of said mold, and a power supply electrically coupled to said at least one heating element and said at least one temperature sensor, wherein said power supply provides electrical power to said at least one heating element and controls said temperature.

21. The apparatus according to claim 20, wherein said at least one heating element comprises at least one of silicon carbide, molybdenum, and tungsten.

22. The apparatus according to claim 20, wherein said at least one heating element is a resistively heated heating element comprising at least one of a bar, a rod, a tube, a wire, and combinations thereof.

23. The apparatus according to claim 20, wherein said at least one heating element is an inductively heated heating element.

24. The apparatus according to claim 20, wherein said mold comprises:

a) an outer solid shell having a hollow therein;

wherein said at least one face coat is disposed on an inner surface of said outer solid shell such that said face coat is interposed between said outer solid shell and said molten material; and

b) an inner core disposed in said hollow, said inner core comprising a inner solid shell, wherein said face coat is disposed on an outer surface of said inner solid shell such that said face coat is interposed between said inner solid shell and said molten material.

25. A mold assembly for casting an article from a molten material, said mold assembly comprising:

a) a mold comprising a ceramic shell defining a cavity therein for receiving said molten material within said cavity, and at least one face coat of a refractory material disposed on an inner surface of said ceramic shell in said cavity such that said face coat is interposed between said solid shell and said molten material, wherein said refractory material comprises at least one of hafnia, erbia, zircon, yttria, ceria, zirconia and at least one stabilized zirconia; and

b) a heater assembly for heating said mold to a predetermined temperature and controlling a temperature of said mold, said heater assembly being proximate to an outer surface of said mold.

26. The mold assembly according to claim 25, wherein said molten material is at a first temperature when received within said cavity, and wherein said ceramic shell has a melting point greater than said first temperature.

27. The mold assembly according to claim 25, wherein said ceramic shell comprises at least one of alumina, hafnia, yttria stabilized zirconia, zirconia, and yttrium aluminum garnet.

28. The mold assembly according to claim 26, wherein said ceramic shell comprises at least one discrete layer of a ceramic material.

29. The mold assembly according to claim 25, further including an outer cooling jacket for cooling said mold.

30. The mold assembly according to claim 29, wherein said cooling jacket comprises a water-cooled copper shell.

31. The mold assembly according to claim 25, further including at least one heat shield for insulating said mold.

32. The mold assembly according to claim 31, wherein said at least one heat shield includes at least one of a baffle and an insulating material.

33. The mold assembly according to claim 25, wherein said heater assembly comprises at least one heating element, at least one temperature sensor for sensing a temperature of said mold, and a power supply electrically coupled to said at least one heating element and said at least one temperature sensor, wherein said power supply provides electrical power to said at least one heating element and controls said temperature.

34. The mold assembly according to claim 33, wherein said at least one heating element comprises at least one of silicon carbide, molybdenum, and tungsten.

35. The mold assembly according to claim 33, wherein said at least one heating element is a resistively heated heating element comprising at least one of a bar, a rod, a tube, a wire, and combinations thereof.

36. The mold assembly according to claim 33, wherein said at least one heating element is an inductively heated heating element.

37. The mold assembly according to claim 25, wherein said at least one face coat has a melting temperature of at least 1900°

C.

38. The mold assembly according to claim 25, wherein said at least one face coat has a thickness from about 5 microns to about 100 microns.

39. The mold assembly according to claim 38, wherein said at least one face coat has a thickness from about 5 microns to about 50 microns.

40. The mold assembly according to claim 25, wherein said mold comprises:

a) an outer ceramic shell having a hollow therein;

wherein said at least one face coat is disposed on an inner surface of said outer ceramic shell such that said face coat is interposed between said outer ceramic shell and said molten material; and

b) an inner core disposed in said hollow, said inner core comprising a inner ceramic shell, wherein said face coat is disposed on an outer surface of said inner ceramic shell such that said face coat is interposed between said inner ceramic shell and said molten material.

41. An apparatus for casting an article, said apparatus comprising:

(a) a means for forming a molten material, said molten material comprising at least one of a metal and an alloy;

(b) a means for pouring said molten material from said means for forming said molten material, wherein said means for pouring said molten material includes a cup for receiving said molten material in a superheated state;

(c) a mold assembly for receiving said molten material from said cup, said mold assembly comprising a ceramic shell for containing said molten material, said ceramic shell defining a cavity therein for accepting said molten material, and at least one face coat of a refractory material disposed on an inner surface of said ceramic shell in said cavity such that said face coat is interposed between said solid shell and said molten material, said refractory material comprising at least one of hafnia, erbia, zircon, yttria, ceria, zirconia, and a stabilized zirconia, wherein said face coat contacts said molten material, and wherein said molten material solidifies within said ceramic shell to form a near-net shape of said article; and

(d) a heater assembly for heating said mold to a predetermined temperature and controlling a temperature of said mold, said heater assembly being proximate to an outer surface of said mold.

42. The apparatus according to claim 41, wherein said molten material is at a first temperature when received within said cavity, and wherein said ceramic shell has a melting point greater than said first temperature.

43. The apparatus according to claim 41, wherein said ceramic shell comprises at least one of alumina, hafnia, yttria stabilized zirconia, zirconia, and yttrium aluminum garnet.

44. The apparatus according to claim 41, wherein said ceramic shell comprises at least one discrete layer of a ceramic material.

45. The apparatus according to claim 41, further including an outer cooling jacket for cooling said mold.

46. The apparatus according to claim 45, wherein said outer cooling jacket comprises a water-cooled copper shell.

47. The apparatus according to claim 41, further including at least one heat shield for insulating said mold.

48. The apparatus according to claim 47, wherein said at least one heat shield includes at least one of a baffle and an insulating material.

49. The apparatus according to claim 41, wherein said heater assembly comprises at least one heating element, at least one temperature sensor for sensing a temperature of said mold, and a power supply electrically coupled to said at least one heating element and said at least one temperature sensor, wherein said power supply provides electrical power to said at least one heating element and controls said temperature.

50. The apparatus according to claim 49, wherein said at least one heating element comprises at least one of silicon carbide, molybdenum, and tungsten.

51. The apparatus according to claim 49, wherein said at least one heating element is a resistively heated heating element comprising at least one of a bar, a rod, a tube, a wire, and combinations thereof.

52. The apparatus according to claim 49, wherein said at least one heating element is an inductively heated heating element.

53. The apparatus according to claim 41, wherein said at least one face coat has a melting temperature of at least 1900°

C.

54. The apparatus according to claim 41, wherein said at least one face coat has a thickness from about 5 microns to about 100 microns.

55. The apparatus according to claim 54, wherein said at least one face coat has a thickness from about 5 microns to about 50 microns.

56. The apparatus according to claim 41, wherein said mold comprises:

a) an outer ceramic shell having a hollow therein;

wherein said at least one face coat is disposed on an inner surface of said outer ceramic shell such that said face coat is interposed between said outer ceramic shell and said molten material; and

b) an inner core disposed in said hollow, said inner core comprising a inner ceramic shell, wherein said face coat is disposed on an outer surface of said inner ceramic shell such that said face coat is interposed between said inner ceramic shell and said molten material.

57. The apparatus according to claim 41, wherein said means for forming said molten material comprises one of an arc melter, an electron beam melter, and an induction skull melter.

58. The apparatus according to claim 57, wherein said arc melter is one of a plasma arc melter, a vacuum arc melter, and a vacuum arc remelter.

59. The apparatus according to claim 41, further including an enclosure for containing said means for forming said molten material, said means for pouring said molten material, and said mold assembly under one of a vacuum and an inert gas atmosphere.

60. The apparatus according to claim 41, wherein said means for forming said molten material comprises a means for forming a molten material having a melting temperature of at least 1500°

C.

61. The apparatus according to claim 41, wherein said molten material comprises silicon and at least one of niobium, titanium, molybdenum, and chromium.

62. The apparatus according to claim 41, wherein said means for forming said molten material includes a ceramic-free path for said molten material.

63. The apparatus according to claim 41, wherein said means for pouring includes one of a tilt-pour tundish and a bottom-pour tundish.

64. The apparatus according to claim 63, wherein said tilt-pour tundish further includes a lip for pouring said molten material into said cup.

65. The apparatus according to claim 63, wherein said bottom-pour tundish further includes an orifice therethrough for pouring said molten material into said cup.

66. The apparatus according to claim 41, wherein said cup comprises at least one of alumina, hafnia, yttria stabilized zirconia, zirconia, and yttrium aluminum garnet.

67. The apparatus according to claim 41, wherein said means for pouring further includes a heater for maintaining said molten material within said cup in said superheated state.

68. The apparatus according to claim 41, wherein said article is a turbine component.

69. The apparatus according to claim 68, wherein said turbine component is an airfoil.

70. A method of casting a near-net shape article, the method comprising the steps of:

(a) forming a molten material comprising at least one of a metal and an alloy;

(b) pouring the molten material into a cup;

(c) maintaining the molten material in a superheated state within the cup;

(d) receiving the molten material from the cup in a mold assembly, wherein the mold assembly comprises a solid shell for containing the molten material, the solid shell having a face coat disposed on an inner surface of the solid shell that contacts the molten material, the face coat comprising at least one of an oxide, a silicide, a silicate, an oxysulfide, and a sulfide and containing at least one of a rare earth metal, a refractory metal, and combinations thereof, and a heater assembly for maintaining the solid shell at a predetermined temperature; and

(e) solidifying the molten material in the mold assembly to form the near-net shape article.

71. The method according to claim 70, wherein the step of forming a molten material comprising at least one of a metal and an alloy comprises:

(a) providing an alloy comprising silicon and at least one of niobium, molybdenum, titanium, and chromium; and

(b) forming a molten material comprising the alloy.

72. The method according to claim 70, wherein the step of forming a molten material comprising at least one of a metal and an alloy comprises arc melting at least one of a metal and an alloy to form a molten material.

73. The method according to claim 70, wherein the step of forming a molten material comprising at least one of a metal and an alloy comprises electron beam melting at least one of a metal and an alloy to form a molten material.

74. The method according to claim 70, wherein the step of forming a molten material comprising at least one of a metal and an alloy comprises plasma melting at least one of a metal and an alloy to form a molten material.

75. The method according to claim 70, wherein the step of forming a molten material comprising at least one of a metal and an alloy comprises induction skull melting at least one of a metal and an alloy to form a molten material.

76. The method according to claim 70, wherein the step of receiving the molten material from the cup in a mold assembly further comprises maintaining the molten material in a fluid state within the mold assembly.

77. The method according to claim 76, wherein the step of maintaining the molten material in a fluid state within the mold assembly comprises heating the mold assembly to a temperature at which the molten material is in a fluid state.

78. The method according to claim 77, wherein the step of heating the mold assembly to a temperature at which the molten material is in a fluid state comprises heating the mold assembly to a temperature of at least about 1300°

C.

79. The method according to claim 70, wherein the step of receiving the molten material from the cup in a mold assembly comprises receiving the molten material from the cup in a mold assembly comprising a ceramic shell and at least one face coat of a refractory material disposed on an inner surface of the ceramic shell, wherein the refractory material comprises at least one of hafnia, erbia, zircon, yttria, zirconia, and stabilized zirconia.

80. The method according to claim 70, wherein the near-net shape article is a hollow article and wherein the step of receiving the molten material from the cup in a mold assembly comprises receiving the molten material from the cup in a mold assembly comprising an outer ceramic shell having a hollow therein and an inner core disposed in the hollow;

wherein at least one face coat is disposed on an inner surface of the outer ceramic shell and an outer surface of the inner ceramic shell such that the face coat is interposed between the molten material and each of the outer ceramic shell and the inner ceramic shell.

81. The method according to claim 70, wherein the near-net shape article is a turbine airfoil.

82. A method of casting a near-net shape article from at least one alloy comprising silicon and at least one of niobium, molybdenum, titanium, and chromium, the method comprising the steps of:

(a) providing the at least one alloy comprising silicon and at least one of niobium, molybdenum, titanium, and chromium;

(b) forming a molten material comprising the alloy;

(c) pouring the molten material into a cup;

(d) maintaining the molten material in a superheated state within the cup;

(e) receiving the molten material from the cup in a mold assembly, wherein the mold assembly comprises a ceramic shell having a cavity for receiving the molten material, at least one face coat of a refractory material disposed on an inner surface of the ceramic shell in the cavity, wherein the refractory material comprises at least one of hafnia, erbia, zircon, yttria, zirconia, and stabilized zirconia, and a heater assembly for maintaining the solid shell at a predetermined temperature; and

(f) solidifying the molten material in the mold assembly to form the near-net shape article.

83. The method according to claim 82, wherein the step of forming a molten material comprising the alloy comprises arc melting the at least one alloy to form a molten material.

84. The method according to claim 83, wherein the step of arc melting the at least one alloy to form a molten material comprises one of plasma arc melting the at least one alloy, vacuum art melting the at least one alloy, and vacuum arc remelting the at least one alloy to form a molten material.

85. The method according to claim 83, wherein the step of forming a molten material comprising the alloy comprises one of plasma melting the at least one alloy and induction skull melting the at least one alloy to form a molten material.

86. The method according to claim 83, wherein the step of receiving the molten material from the cup in a mold assembly further comprises maintaining the molten material in a fluid state within the mold assembly.

87. The method according to claim 86, wherein the step of maintaining the molten material in a fluid state within the mold assembly comprises heating the mold assembly to a temperature at which the molten material is in a fluid state.

88. The method according to claim 87, wherein the step of heating the mold assembly to a temperature at which the molten material is in a fluid state comprises heating the mold assembly to a temperature of at least about 1300°

C.

89. The method according to claim 82, wherein the near-net shape article is a hollow article and wherein the step of receiving the molten material from the cup in a mold assembly comprises receiving the molten material from the cup in a mold assembly comprising an outer ceramic shell having a hollow therein and an inner core disposed in the hollow;

wherein at least one face coat is disposed on an inner surface of the outer ceramic shell and an outer surface of the inner ceramic shell such that the face coat is interposed between the molten material and each of the outer ceramic shell and the inner shell.

90. The method according to claim 82, wherein the near-net shape article is a turbine airfoil.

91. A near-net shape article comprising at least one alloy, the at least one alloy comprising silicon and at least one of niobium, molybdenum, titanium, and chromium, wherein the near-net shape article is cast by:

(a) forming a molten material comprising the at least one alloy;

(b) pouring the molten material into a cup;

(c) maintaining the molten material in a superheated state within the cup;

(d) receiving the molten material from the cup in a mold assembly, wherein the mold assembly comprises a ceramic shell, at least one face coat of a refractory material disposed on an inner surface of the ceramic shell in the cavity, wherein the refractory material comprises at least one of hafnia, erbia, zircon, yttria, zirconia, and stabilized zirconia, and a heater assembly for maintaining the solid shell at a predetermined temperature;

(e) heating the mold assembly to a temperature at which the molten material is in a fluid state; and

(f) solidifying the molten material in the mold assembly to form the near-net shape article.

92. The near-net shape article of claim 91, wherein the near-net shape article is a turbine airfoil.

93. The near-net shape article of claim 91, wherein the near-net shape article is a hollow article and wherein the step of receiving the molten material from the cup in a mold assembly comprises receiving the molten material from the cup in a mold assembly comprising an outer ceramic shell having a hollow therein and an inner core disposed in the hollow;

wherein at least one face coat is disposed on an inner surface of the outer ceramic shell and an outer surface of the inner ceramic shell such that the face coat is interposed between the molten material and each of the outer ceramic shell and the inner shell.