Breathable composite sheet structure and absorbent articles utilizing same

• US 6,677,258 B2
• Filed: 11/25/1998
• Issued: 01/13/2004
• Est. Priority Date: 05/29/1996
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.), The Procter & Gamble Company
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.), The Procter & Gamble Company
• Inventors: Lavon, Gary Dean, Lim, Hyun Sung, Curro, John Joseph, Ostapchenko, George Joseph, Vaidya, Shailaja R., Sparks, Richard L., Carroll, Nora Liu, Mc Kenna, J. Michael
• Primary Examiner(s): Juska, Cheryl A.
• Assistant Examiner(s): Pratt, Christopher C.
• Application Number:
  US09/194,378
• Publication Number:
  US 20020019187A1
• Time in Patent Office: 1,875 Days
• Field of Search: 442/394, 442/395, 442/398, 442/399
• US Class Current: 442/394
• CPC Class Codes: A61F 13/51462 being defined by a value or parameter
• CPC Class Codes: A61F 13/5148 having an impervious inner layer and a cloth-like outer layer
• CPC Class Codes: B32B 2262/0253 Polyolefin fibres vinyl or acrylic copolymers B32B2262/0223 or B32B2262/0246
• CPC Class Codes: B32B 2307/724 Permeability to gases, adsorption
• CPC Class Codes: B32B 2535/00 Medical equipment, e.g. bandage, prostheses, catheter medical patches B32B2556/00
• CPC Class Codes: B32B 2555/00 Personal care
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: D04H 1/4291 Olefin series
• CPC Class Codes: D04H 1/4374 using different kinds of webs, e.g. by layering webs
• CPC Class Codes: Y10T 442/674 Nonwoven fabric with a preformed polymeric film or sheet
• CPC Class Codes: Y10T 442/675 Ester condensation polymer sheet or film [e.g., polyethylene terephthalate, etc.]
• CPC Class Codes: Y10T 442/678 Olefin polymer or copolymer sheet or film [e.g., polypropylene, polyethylene, ethylene-butylene copolymer, etc.]
• CPC Class Codes: Y10T 442/679 Natural or synthetic rubber sheet or film

Abstract

A breathable composite sheet material, a method for making such a sheet material, and an absorbent article utilizing the sheet material are provided. The composite sheet material is comprised of a thermoplastic film adhered directly to a fibrous substrate. The thermoplastic film comprises at least 50% by weight of a polymer material from the group of block copolyether esters, block copolyether amides and polyurethanes. The substrate comprises a fibrous web of at least 50% by weight of polyolefin polymersynthetic fibers. The composite sheet exhibits a peel strength of at least 0.1 N/cm, a dynamic fluid transmission of less than about 0.75 g/m² when subjected to an impact energy of about 2400 joules/m², and a moisture vapor transmission rate, according to the dessiccant method, of at least 1500 g/m²/2 hr. The absorbent article comprises: (a) a topsheet; (b) a backsheet; and (c) an absorbent core located between the topsheet and the backsheet; wherein the backsheet comprises the non-porous, substantially fluid impermeable moisture vapor permeable composite sheet material described above. The composite sheet material is oriented such that the film layer of the composite sheet material faces toward the absorbent core. The absorbent article may comprise a disposable diaper.

Claims

1. A breathable composite sheet material comprising a substrate and a thermoplastic film adhered directly to the substrate,

said thermoplastic film comprising

at least 50% by weight of a Fraction A consisting essentially of polymer from the group of block copolyether esters, block copolyether amides and polyurethanes,

at least 5% by weight of a Fraction B consisting essentially of polymer that is incompatible with Fraction A, and

at least 0.1% by weight of a Fraction C consisting essentially of a compatibilizer for Fractions A and B;

and

said substrate comprising at least 50% by weight of a polymer that is incompatible with film Fraction A.

2. The composite sheet material of claim 1 wherein film Fraction B is comprised of at least 50% by weight of at least one of a homopolymer of an alpha-olefin, a copolymer or terpolymer containing an alpha-olefin and one or more other monomers, and a block copolymer of a vinylarene and a conjugated diene.

3. The composite sheet material of claim 2 wherein film Fraction C consists essentially of homopolymers, copolymers and terpolymers with backbones that are compatible with Fraction B, said backbones being grafted with a monomer having a functional group that is compatible with Fraction A.

4. The composite sheet material of claim 3 wherein film Fraction C is a polymer with a backbone identical to Fraction B, said backbone being grafted with monomer selected from the group of alpha- and beta-ethylenically unsaturated carbonic acids and anhydrides, and derivatives thereof.

5. The composite sheet material of claim 1 wherein the substrate is a fibrous nonwoven sheet comprised of at least 50% by weight of a polyolefin polymer.

6. The composite sheet material of claim 5 wherein the substrate is a nonwoven sheet made from a fibrous web comprised of at least 50% by weight polypropylene.

7. The composite sheet material of claim 5 wherein the substrate is a nonwoven sheet made from a fibrous web comprised of at least 50% by weight polyethylene.

8. The composite sheet material of claim 1 wherein film Fraction is a block copolyether ester, film Fraction B is polypropylene, film Fraction C is a grafted polymer having a backbone of polypropylene that is grafted with maleic anhydride, and the substrate is a nonwoven spunbonded sheet made from a fibrous web comprised of at least 50% by weight polypropylene.

9. The composite sheet material of claim 8 wherein the thermoplastic film comprises, by weight, 50% to 95% film Fraction A, 5% to 50% film Fraction B, and 0.1% to 15% film Fraction C.

10. The composite sheet material of claim 9 wherein the thickness of the thermoplastic film is in the range of 5 to 50 microns, and the sheet material has a moisture vapor transmission rate of at least 200 g/m²/24 hrs (by method ASTM E96-B), and a peel strength per unit thickness of the thermoplastic film of the sheet material is at least 0.003 N/cm-micron.