High machinability iron base sintered alloy for valve seat inserts

• US 6,679,932 B2
• Filed: 04/30/2002
• Issued: 01/20/2004
• Est. Priority Date: 05/08/2001
• Status: Expired due to Term

• Current Assignee: Federal-Mogul World Wide LLC (Apollo Global Management, Inc.)
• Original Assignee: Federal-Mogul Worldwide Incorporated (Apollo Global Management, Inc.)
• Inventors: Nigarura, Salvator, Trasorras, Juan, Birler, Mark
• Primary Examiner(s): MAI, NGOCLAN THI
• Application Number:
  US10/135,817
• Publication Number:
  US 20030010153A1
• Time in Patent Office: 630 Days
• Field of Search: 752/31, 752/46, 752/52, 419/27, 419/25, 419/38
• US Class Current: 75/231
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: C22C 33/0207 Using a mixture of prealloyed powders or a master alloy mixtures of metal powder in general B22F1/09
• CPC Class Codes: C22C 33/0221 comprising S or a sulfur compound
• CPC Class Codes: C22C 33/0242 using the impregnating technique impregnating articles in general B22F3/26
• CPC Class Codes: F01L 3/02 Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials

Abstract

A ferrous sintered valve seat material is made of mixed powders comprising a sinter-hardenable phase and a finely dispersed carbide phase. The powder mixture comprises a sinter-hardening prealloyed powder forming 75 to 90 wt. % of the mixture and a tool steel powder with finely dispersed carbides forming 5 to 25% of the mixture. Machinability additives of MnS, CaF₂ or MoS₂ types are added in an amount of 1 to 5 wt. %. Improved thermal conductivity is obtained by infiltrating the compact with Cu up to 25 wt. %.

Claims

1. A sinter-hardenable powder metal valve seat material for internal combustion engines comprising a mixture of:

a sinter-hardenable ferrous powder forming 75-90 wt. % of the mixture;

a tool steel powder;

a solid lubricant;

Cu added by infiltration during sintering, and

wherein the ferrous powder is prealloyed with 2 to 5 wt. % Cr.

2. The material of claim 1 wherein the tool steel is mixed in proportions of 5 to 25 wt. %.

3. The material of claim 1 wherein the tool steel is selected from the group consisting of M2 and M3/2 tool steel.

4. The material of claim 1 wherein the tool steel consists of M2 tool steel.

5. The material of claim 1 wherein the ferrous powder is further prealloyed with 0 to 3 wt. % Mo and 0 to 2 wt. % Ni.

6. The material of claim 1 having the following composition:

75 to 90% of the ferrous powder prealloyed with 2 to 5 wt. % Cr, 0 to 3 wt. % Mo and 0 to 2 wt. % Ni;

5 to 25 wt. % M2 tool steel powder;

1 to 5 wt. % of the solid lubricant selected from one or more of the group consisting of MnS, CaF₂ and MoS₂; and

the Cu added by infiltration during sintering amounting to 10 to 25 wt. % of the remaining constituents.

7. The mixture of claim 6 wherein the ferrous powder is present in an amount of 89 wt. %.

8. The mixture of claim 6 wherein the M2 tool steel is present in an amount of 8 wt. %.

9. The mixture of claim 6 wherein the solid lubricant is present in an amount of 3 wt. %.

10. The mixture of claim 6 wherein the Cu is present in an amount of 20 wt. % of the remaining constituents of the mixture.

11. The mixture of claim 6 having the following composition:

89 wt. % of the ferrous powder;

8 wt. % of the M2 tool steel;

3 wt. % of the solid lubricant; and

20 wt. % infiltrated Cu relating to the combined weight percentage of the ferrous powder, M2 tool steel and solid lubricant.

12. A sintered valve seat insert material for internal combustion engines with improved machinability, wear resistance and high thermal conductivity, where said material consists of a mixture of a Cr-containing sinter-hardening ferrous alloy powder, a tool steel powder, a solid lubricant and Cu added by infiltration of compacts during sintering.

13. The material according to claim 12, characterized in that the microstructure is fully martensitic after sintering in a conventional furnace without accelerated cooling.

14. The material according to claim 12, characterized in that the tool steel is mixed in proportions of 5 to 25% only in the mixture.

15. The material according to claim 12, characterized by the following mixture composition:

75 to 90% of a sinter-hardening iron powder prealloyed with;

2 to 5 wt. % Cr;

0 to 2 wt. % Ni;

0 to 3 wt. % Mo 5 to 25 wt. % M2 tool steel powder;

1 to 5 wt. % solid lubricant selected from the group consisting of MnS, CaF₂ and MoS₂;

10 to 25 wt. % of Cu added by infiltration of solid blanks during sintering.

16. A sintered valve seat insert for internal combustion engines exhibiting good machinability, wear resistance and high thermal conductivity, comprising:

a matrix of a sinter-hardening prealloyed or admixed Fe powder containing 2 to 5 wt. % Cr mixed and sintered with an amount of tool steel powder, a solid lubricant and an amount of Cu added by infiltration during sintering.

17. The sintered valve seat insert of claim 16 having a micro structure which is fully martensitic after sintering without accelerated cooling.

18. The sintered valve seat of claim 16 wherein the tool steel is mixed in proportions of 5 to 25 wt. %.

19. The sintered valve seat of claim 16 wherein the Fe powder further includes 0 to 3 wt. % Mo and 0 to 2 wt. % Ni.

20. The sintered valve seat of claim 19 wherein the tool steel comprises M2 tool steel present in an amount of 5 to 25 wt. %.

21. The sintered valve seat of claim 20 wherein the tool steel is present in an amount of 8 wt. %.

22. The sintered valve seat of claim 19 wherein the solid lubricant is selected from one or more of the group consisting of MnS, CaF₂ and MoS₂ and is present in an amount of 1 to 5 wt. %.

23. The sintered valve seat of claim 22 wherein the solid lubricant is present in an amount of 3 wt. %.

24. The sintered valve seat of claim 19 wherein the Cu is infiltrated in an amount of 10 to 25 wt. % of the other constituents of the mixture.

25. The sintered valve seat of claim 24 wherein the Cu is infiltrated in an amount of 20 wt. %.

26. A method of making a sintered powder metal valve seat insert for internal combustion engines exhibiting good machinability, wear resistance and high thermal conductivity, comprising:

mixing Cr-containing sinter-hardenable ferrous powder with tool steel powder and a solid lubricant;

compacting and sintering the mixture; and

during sintering, infiltrating the compact with Cu.

27. The method of claim 26, wherein a fully martensite micro structure results by allowing the sintered compact to cool following sintering without quenching.

28. The method of claim 26 wherein the tool steel is added in an amount of 5 to 25 wt. %.

29. The method of claim 26 wherein the mixture is prepared from the following composition:

75 to 90 wt. % of the Cr-containing ferrous powder;

5 to 25 wt. % of M2 tool steel;

1 to 5 wt. % of the solid lubricant; and

wherein the Cu is infiltrated into the compacted mixture in an amount of 10 to 25 wt. % of the compact.

30. The method of claim 29 wherein the Cr-containing ferrous powder comprises elemental admixed or prealloyed Fe powder combined with 2 to 5 wt. % Cr, 0 to 3 wt. % Mo and 0 to 2 wt. % of Ni.

31. The method of claim 30 wherein the Cr-containing ferrous powder is present in an amount of 89 wt. %, the M2 tool steel present in an amount of 8 wt. %, the solid lubricant present in an amount of 3 wt. %, and the Cu infiltrated in an amount of 20 wt. % of the compact during sintering.