Light-transmitting and/or coated article with removable protective coating and methods of making the same

• US 6,682,773 B2
• Filed: 02/22/2002
• Issued: 01/27/2004
• Est. Priority Date: 07/02/1999
• Status: Expired due to Term

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Medwick, Paul A., Thiel, James P., Finley, James J., Lawton, Ernest L., Marietti, Gary J., Scriven, Roger L., Martin, George M., Goodreau, Erin
• Primary Examiner(s): Beck, Shrive P.
• Assistant Examiner(s): Michener, Jennifer Kolb
• Application Number:
  US10/080,824
• Publication Number:
  US 20020176988A1
• Time in Patent Office: 704 Days
• Field of Search: 427/154, 427/155, 427/156, 427/207.1, 427/208.8, 427/226, 427/227, 427/372.2, 427/407.1, 427/407.2, 427/419.7
• US Class Current: 427/154
• CPC Class Codes: B65B 33/04 Packaging large articles, e.g. complete machines, aircraft
• CPC Class Codes: B65G 49/069 Means for avoiding damage to stacked plate glass, e.g. by interposing paper or powder spacers in the stack maculation per se B65H39/00
• CPC Class Codes: C03C 17/32 with synthetic or natural resins C03C17/30 takes precedence
• CPC Class Codes: C03C 17/38 at least one coating being a coating of an organic material
• CPC Class Codes: C03C 17/42 at least one coating of an organic material and at least one non-metal coating
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/485 Pigments
• CPC Class Codes: C03C 2218/328 Partly or completely removing a coating
• CPC Class Codes: C03C 2218/355 Temporary coating
• CPC Class Codes: C09D 5/008 Temporary coatings C09D5/20 takes precedence
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31649 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31703 Next to cellulosic
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31931 Polyene monomer-containing
• CPC Class Codes: Y10T 428/31935 : Ester, halide or nitrile of addition polymer

Abstract

A method and coating are provided for temporarily protecting a substrate or article during shipping, handling or storage by applying a removable protective coating over at least a portion of the substrate. The substrate may be flat or curved and may have zero, one or more functional coatings. A plurality of substrates with the protective coating of the invention may be arranged in a shipping container so that the protective coating reduces the possibility of damage to the substrate or optional functional coating. In one embodiment, the protective coating is the evaporation or reaction product of an aqueous coating composition containing a polyvinyl alcohol polymer which may be subsequently removed by aqueous washing, thermal decomposition or combustion. In another embodiment, the protective coating is formed by sputtering a substantially carbon coating onto the substrate. The carbon coating is subsequently removed by combustion. The protective coating may have identification materials, such as colorants or fragrance materials, such that different types of substrates and/or functional coatings can be distinguished from each other. Additionally, the temporary protective coating can improve the heating of a functionally coated glass substrate.

Claims

1. A method of protecting a substrate having at least one light transmitting surface and at least one functional coating from mechanical damage, comprising the steps of:

providing a substrate having at least one light transmitting surface and having a surface with a functional coating over at least a portion of the surface;

depositing a liquid coating composition over at least a portion of the functional coating, the coating composition comprising a film-forming polymeric material; and

forming a removable protective coating from the coating composition with film forming material,

wherein the functional coating is selected from the group consisting of single layer and multiple layer coatings, wherein the functional coating comprises a material selected from the group consisting of one or more metals, non-metals, semimetals, semiconductors, or alloys, compounds, composites, combinations, and blends thereof,

wherein the removable protective coating is essentially free of particulate solid spacer material for interleaving when the functional coating is a single layer metal oxide and

wherein the film-forming polymeric material comprises polyvinyl alcohol having a degree of hydrolyzation of greater than about 80 percent.

2. The method according to claim 1, further comprising contacting the removable protective coating with a liquid to remove the protective coating.

3. The method according to claim 2, wherein the liquid comprises water.

4. The method according to claim 1, further comprising heating the substrate to a temperature sufficient to combust or thermally decompose the removable protective coating.

5. The method according to claim 1, wherein the protective coating comprises the evaporation product or reaction product of a liquid coating composition comprising a film-forming polymeric material.

6. The method of claim 1, wherein the liquid coating composition includes a substantially aqueous carrier.

7. The method of claim 1, wherein the substrate has the functional coating over the at least one light transmitting surface.

8. The method of claim 1, wherein the substrate is selected from the group consisting of glass, polymers, polyester polycarbonates, polyethyleneterephthalate, plastic, ceramic, metal, cellulose, and mixtures or combinations thereof.

9. The method of claim 1, wherein the substrate is selected from the group consisting of flat glass, untempered glass, tempered glass, and heat-strengthened glass.

10. The method of claim 5, wherein the polymeric material is selected from the group consisting of polyesters, polycarbonates, polystyrenes, polyacrylates, cellulosics and derivatives, blends, copolymers, composites, combinations or mixtures thereof.

11. The method of claim 1, wherein the substrate is glass and has dimensions larger than about 1.8 m by about 2.1 m.

12. The method of claim 1, wherein the substrate has dimensions smaller than about 1.8 m by about 2.1 m.

13. The method of claim 1, wherein the functional coating is selected from the group consisting of pyrolytically deposited coatings, sputter deposited coatings, wet chemistry deposited coatings, and chemical vapor deposition deposited coatings.

14. The method of claim 1, wherein the, functional coating is selected from the group consisting of low emissivity coatings, solar energy reflective or absorptive coatings, and thermal infrared reflective or absorptive coatings and combinations thereof.

15. The method of claim 5, wherein the polymeric material is selected from the group consisting of water soluble, emulsifiable, and water dispersible materials.

16. The method of claim 5, wherein the polymeric material comprises up to about 50 weight percent of the coating composition.

17. The method of claim 5, wherein the polymeric material comprises about 5 to about 12 weight percent of the coating composition.

18. The method of claim 1, wherein the liquid coating composition further includes at least one additive selected from the group consisting of fillers, biocides, surfactants, defoamers, colorants, flow agents, leveling agents, hydrophilic agents, hydrophobic agents, spacer materials and fragrance materials.

19. The method of claim 1, wherein the removable coating is a substantially continuous coating.

20. The method of claim 1, wherein the removable coating is a substantially non-continuous coating.

21. The method of claim 1, wherein the removable coating has a mass coverage of about 0.1 to about 0.2 gram per square foot.

22. The method of claim 1, wherein the liquid coating composition comprises one or more non-aqueous carriers.

23. The method of claim 22 wherein the non-aqueous carrier comprises at least one of isopropanol, methanol, or ethanol.

24. The method of claim 1 wherein the removable protective coating is removed without scratching the underlying functional coating.

25. The method of claim 1 wherein the substate has at least two major surfaces with at least one of the surfaces coated with the functional coating over which is coated the removable protective coating.