Magnetic recording medium

• US 6,686,022 B2
• Filed: 11/21/2001
• Issued: 02/03/2004
• Est. Priority Date: 11/21/2000
• Status: Active Grant

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Takano, Hiroaki, Suzuki, Masaki, Kunikata, Masanosuke
• Primary Examiner(s): Resan, Stevan A.
• Application Number:
  US09/990,610
• Publication Number:
  US 20020122339A1
• Time in Patent Office: 804 Days
• Field of Search: 428/141, 428/216, 428/323, 428/328, 428/329, 428/336, 428/694.BA, 428/694.BH, 428/694.BN, 428/694.BR
• US Class Current: 428/842.8
• CPC Class Codes: G11B 5/70678 Ferrites
• CPC Class Codes: G11B 5/7085 non-magnetic abrasive particles
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/257 Iron oxide or aluminum oxide
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

Provided is a particulate magnetic recording medium with good output at high frequency, yielding a low coefficient of friction, and having good running properties, in particular, a magnetic recording medium affording good electromagnetic characteristics and good repeat durability in recording and reproducing at a high-density. The magnetic recording medium comprises a lower layer comprising a nonmagnetic powder and a binder and an upper magnetic layer comprising a ferromagnetic powder, a binder and at least one abrasives provided on a nonmagnetic support in this order. The number of abrasive particles present on said magnetic layer surface satisfied the relation 0.2≦X≦1.2 (particles/μm²). When the number of pairs of abrasive particles satisfying the relation L≦2K (where K denotes the mean particle diameter of the abrasive and L denotes the distance from the center of gravity of one of the abrasive particles to the center of gravity of the other abrasive particle) is denoted as Y (particles/μm²), Y/X is equal to or less than 2.

Claims

1. A magnetic recording medium comprising:

a lower layer comprising a nonmagnetic powder, and a binder and an upper magnetic layer having a magnetic layer surface and comprising a ferromagnetic powder, a binder and at least one abrasives material provided on a nonmagnetic support in this order,

wherein said abrasive material has a plurality of abrasive particles, the number of abrasive particles X present on said magnetic layer surface, counted using a scanning electron microscope at 20,000 times magnification, satisfies the relation 0.2≦

X≦

1.2 (particles/μ

m²), and

when the number of pairs of abrasive particles satisfying the relation L≦

2K (where K denotes the mean particle diameter of the abrasive, measuring using the scanning electron microscope at 20,000 times magnification, and L denotes the distance from the center of gravity of one of the abrasive particles to the center of gravity of to other abrasive particle, measured using the scanning electron microscope at 20,000 times magnification) is denoted as Y (particles/μ

m²), Y/X is equal to or less than 2.

2. The magnetic recording medium according to claim 1 wherein said abrasive has the mean particle diameter ranging from 0.1 to 0.6 μ

m.

3. The magnetic recording medium according to claim 1 wherein said magnetic layer has a thickness ranging from 0.05 to 0.6 μ

m.

4. The magnetic recording medium according to claim 1 wherein said abrasive has a mean particle diameter falling within the range of 0.3 to 2 times the thickness of the magnetic layer.

5. The magnetic recording medium according to claim 1 wherein said lower layer has a thickness ranging from 0.5 to 2.0 μ

m.

6. The magnetic recording medium according to claim 1 wherein said magnetic layer has coercivity ranging from 159 to 239 KA/m.

7. The magnetic recording medium according to claim 1 wherein said ferromagnetic powder is a ferromagnetic metal powder chiefly of Fe.

8. The magnetic recording medium according to claim 7 wherein said ferromagnetic metal powder has a major axis length of 0.05 to 0.19 μ

m.

9. The magnetic recording medium according to claim 7 wherein said ferromagnetic metal powder has a crystalline size ranging from 100 to 230 Angstroms.

10. The magnetic recording medium according to claim 7 wherein said ferromagnetic metal powder has a coercivity Hc of 79 to 316 KA/m and an σ

s of 1.26 to 2.26×

10<sup>−

4</sup> WB.m/kg.

11. The magnetic recording medium according to claim 7 wherein said ferromagnetic metal powder has a specific surface area ranging from 35 to 60 m²/g and a pH equal to or higher than 7.

12. The magnetic recording medium according to claim 1 wherein said ferromagnetic powder is a hexagonal ferrite ferromagnetic powder.

13. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has a plate diameter of 40 mm or less.

14. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has a coercivity Hc of 79 to 316 KA/m.

15. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has a σ

s ranging from 45 to 75 A.m²/kg.

16. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has a σ

s ranging from 50 to 70 A.m^2/kg.

17. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has a plate diameter/thickness ratio ranging from 2 to 15.

18. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has a plate diameter/thickness ratio ranging from 3 to 8.

19. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has an average particle volume ranging from 2,000 to 12,000 nm³.

20. The magnetic recording medium according to claim 12 wherein said hexagonal ferrite ferromagnetic powder has an average particle volume ranging from 3,000 to 10,000 nm³.