Organic light emitting materials and devices
First Claim
Patent Images
1. An organic light emitting device, comprising:
- (a) an anode;
(b) a cathode; and
(c) an emissive layer disposed between the anode and the cathode, the emissive layer including a material having a ligand having the structure;
wherein the ligand is attached to a metal having an atomic weight greater than 40, and A is selected from the group consisting of aryl and heteroaryl rings, and B is an aryl ring, and R″
is selected from the group consisting of hydrogen and any substituent.
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Abstract
An organic light emitting device is provided. The device includes an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer includes material having the structure:
M is a metal having an atomic weight greater than 40, m is at least 1, n is at least zero, R″ is H or any substituent, X is an ancillary ligand, and A is selected from the group consisting of aryl and heteroaryl rings, and B is an aryl ring. A material including the photoactive ligand of the above material is also provided.
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Citations
35 Claims
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1. An organic light emitting device, comprising:
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(a) an anode;
(b) a cathode; and
(c) an emissive layer disposed between the anode and the cathode, the emissive layer including a material having a ligand having the structure;
wherein the ligand is attached to a metal having an atomic weight greater than 40, and A is selected from the group consisting of aryl and heteroaryl rings, and B is an aryl ring, and R″
is selected from the group consisting of hydrogen and any substituent.- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18)
wherein M is a metal having an atomic weight greater than 40, in is at least 1, n is at least zero, R″
is hydrogen or any substituent, X is an ancillary ligand, and A is selected from the group consisting of aryl and heteroaryl rings, and B is an aryl ring.
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3. The device of claim 2, wherein at least one of A and B includes a substituent.
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4. The device of claim 2, wherein M is selected from the group consisting of Ir, Pt, Pd, Rh, Re, Ru, Os, Tl, Pb, Bi, In, Sn, Sb, Te, Au, and Ag.
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5. The device of claim 4, wherein m is 2, and wherein n is 1.
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6. The device of claim 2, wherein M is Ir.
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7. The device of claim 2, wherein M is Pt.
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8. The device of claim 2, wherein n is zero.
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9. The device of claim 2, wherein the emissive material is incorporated into a polymer.
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10. The device of claim 2, wherein the emissive material is incorporated into a dendrimer.
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11. The device of claim 2, wherein the emissive layer further comprises a host material.
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12. The device of claim 11, wherein the emissive material is a dopant in the host material.
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13. The device of claim 2, wherein the emissive material consists essentially of a neat film of the emissive material.
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14. The device of claim 2, wherein the emissive layer includes a material having the structure:
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wherein; Y is C; and
R2, R3, R4, R5, R′
2, R′
3, R′
4, and R′
5 are each independently selected from the group consisting of hydrogen and any substituent.
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15. The device of claim 14, wherein R2, R3, R4, R5, R′
- 2, R′
3, R′
4 and R′
5 are each a hydrogen atom, R″
is —
CH3, and X is acac.
- 2, R′
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16. The device of claim 14, wherein at least one of the groups R2, R3, R4, R5, R′
- 2, R′
3, R′
4 and R′
5 is linked to another of the groups R2, R3, R4, R5, R′
2, R′
3, R′
4 and R′
5 to form a ring.
- 2, R′
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17. The device of claim 2, wherein:
the emissive layer includes a material having the structure;
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18. The device of claim 2, wherein the device has a luminous efficiency of at least 22.5 cd/A, at a luminance of 500 cd/m2.
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19. An emissive material having a ligand having the structure:
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wherein the ligand is attached to a metal having an atomic weight greater than 40, and A is selected from the group consisting of aryl and heteroaryl rings, and B is an aryl ring, and R″
is selected from the group consisting of hydrogen and any substituent.- View Dependent Claims (20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35)
wherein M is a metal having an atomic weight greater than 40, m is at least 1, n is at least zero, R″
is hydrogen or any substituent, X is an ancillary ligand, and A is selected from the group consisting of aryl and heteroaryl rings, and B is an aryl ring.
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21. The emissive material of claim 20, wherein at least one of A and B includes a substituent.
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22. The emissive material of claim 20, wherein M is selected from the group consisting of Ir, Pt, Pd, Rh, Re, Ru, Os, Tl, Pb, Bi, In, Sn, Sb, Te, Au, and Ag.
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23. The emissive material of claim 22, wherein m is 2, and wherein n is 1.
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24. The emissive material of claim 20, wherein M is Ir.
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25. The emissive material of claim 20, wherein M is Pt.
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26. The emissive material of claim 20, wherein n is zero.
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27. The emissive material of claim 20, wherein the emissive material is incorporated into a polymer.
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28. The emissive material of claim 20, wherein the emissive material is incorporated into a dendrimer.
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29. The emissive material of claim 20, wherein the emissive layer further comprises a host material.
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30. The emissive material of claim 29, wherein the emissive material is a dopant in the host material.
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31. The emissive material of claim 20, wherein the emissive material consists essentially of a neat film of the emissive material.
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32. The emissive material of claim 20, wherein the emissive layer includes a material having the structure:
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wherein; M is Ir;
Y is C; and
R2, R3, R4, R5, R′
2, R′
3, R′
4, and R′
5 are each independently selected from the group consisting of hydrogen and any substituent.
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33. The emissive material of claim 32, wherein R2, R3, R4, R5, R′
- 2, R′
3, R′
4 and R′
5 are each a hydrogen atom, R″
is —
CH3, and X is acac.
- 2, R′
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34. The emissive material of claim 32, wherein at least one of the groups R2, R3, R4, R5, R′
- 2, R′
3, R′
4 and R′
5 is linked to another of the groups R2, R3, R4, R5, R′
2, R′
3, R′
4 and R′
5 to form a ring.
- 2, R′
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35. The emissive material of claim 20, wherein the emissive material has the structure:
Specification