Water-containing multiphase cleaning composition based on nonionic surfactant

• US 6,689,223 B1
• Filed: 08/04/2000
• Issued: 02/10/2004
• Est. Priority Date: 08/06/1999
• Status: Expired due to Fees

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Schaper, Ulf-Armin, Ditze, Alexander, Katowicz, Ryzard, Meine, Georg
• Primary Examiner(s): Douyon, Lorna M.
• Application Number:
  US09/632,562
• Time in Patent Office: 1,285 Days
• Field of Search: 510/417, 510/421, 510/424, 510/434, 510/480, 134/2, 134/40, 134/42
• US Class Current: 134/2
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/721 End blocked ethers
• CPC Class Codes: C11D 1/8305 containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
• CPC Class Codes: C11D 17/0017 Multi-phase liquid compositions
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/2068 Ethers
• CPC Class Codes: C11D 3/2086 Hydroxy carboxylic acids-salts thereof
• CPC Class Codes: C11D 3/50 Perfumes

Abstract

A method of cleaning hard surfaces by contact with an aqueous, liquid, multiphase, surfactant-containing cleaning composition having at least two continuous phases, one lower aqueous phase I and an upper aqueous phase II immiscible with the lower phase I, which can be temporarily converted into an emulsion by shaking and which cleaning composition contains no more than 50% by weight of nonionic surfactants, based on the total quantity of surfactants present.

Claims

1. A method of cleaning a hard surface, comprising contacting a hard surface in need of cleaning with an aqueous, liquid, multiphase, cleaning composition containing surfactants and having at least two continuous phases, comprising at least a lower aqueous phase I and an upper aqueous phase II immiscible with the lower phase I, which composition can be temporarily converted into an emulsion by shaking, said surfactants comprising more than 50% by weight of nonionic surfactants based on the quantity of surfactants contained in the composition, in an amount and for a time effective to clean the surface.

2. The method of claim 1, wherein a clearly defined phase boundary separates the phases I and II.

3. The method of claim 1, wherein one or both of the continuous phases I and II comprise a part of the other phase as a dispersant.

4. The method of claim 3, wherein one or both of the continuous phases I and II comprise 0.1% to 25% by volume of the other phase as a dispersant.

5. The method of claim 4, wherein one or both of the continuous phases I and II comprise 0.2% to 15% by volume of the other phase as a dispersant.

6. The method of claim 1, wherein phase I is emulsified into phase II in an amount of 0.1% to 25% by volume based on the volume of phase II.

7. The method of claim 6, wherein phase I is emulsified into phase II in an amount of 0.2% to 15% by volume based on the volume of phase II.

8. The method of claim 1, wherein the upper and lower phases I and II form an emulsion between the two phases I and II that is separated from phases I and II by a clearly defined upper phase boundary and a clearly defined lower phase boundary.

9. The method of claim 1, wherein phases I and II have a volume ratio of 90:

10 to 10;

90.

10. The method of claim 9, wherein phases I and II have a volume ratio of 75:

25 to 25;

75.

11. The method of claim 10, wherein phases I and II have a volume ratio of 65:

35 to 35;

65.

12. The method of claim 1, wherein the nonionic surfactants comprise C_6-22 alkyl alcohol polyglycol ethers, alkyl polyglycosides, or mixtures thereof.

13. The method of claim 1, wherein the composition further comprises one or more anionic surfactants.

14. The method of claim 13, wherein the one or more anionic surfactants are selected from the group consisting of C_6-22 altkyl sulfates, C_6-22 alkyl ether sulfates, C_6-22 alkyl benzenesulfonates, and mixtures thereof.

15. The method of claim 14, wherein at least one anionic surfactant is in the form of its potassium salt.

16. The method of claim 1, wherein the composition comprises one or more nonionic surfactants selected from the group consisting of C_6-22 alkyl alcohol polyglycol ethers and alkylpolyglycosides and one or more anionic surfactants selected from the group consisting of C_6-22 alkyl benzenesulfonates, C_6-22 alkyl sulfates, and C_6-22 alkyl ether sulfates.

17. The method of claim 16, wherein the nonionic surfactants comprise one or more C_6-22 alkyl alcohol polyglycol ethers, and the anionic surfactants comprise one or more C_6-22 alkyl benzenesulfonares.

18. The method of claim 1, wherein the composition further comprises one or more hydrophobic components selected from the group consisting of symmetric or asymmetric C_4-14 dialkyl ethers, etheritied or esteritfed monomeric or polymeric C_2-4 alkylene glycols, hydrocarbons having a boiling range of 100 to 300°

C., essential oils, and mixtures thereof.

19. The method of claim 1, wherein the composition further comprises one or more phase separation auxiliaries.

20. The method of claim 19, wherein the composition comprises one or more phase separation auxiliaries selected from the group consisting of alkaline metal and alkaline earth metal chlorides and sulfates, and mixtures thereof.

21. The method of claim 1, wherein the composition further comprises one or more builders.

22. The method of claim 21, wherein the composition comprises one or more builders selected from the group consisting of alkali metal citrates, gluconates, nitrilocriacetates, carbonates and bicarbonates, alkali metal and alkaline earth metal hydroxides, ammonia, amines, and mixtures thereof.

23. The method of claim 1, wherein the composition further comprises one or more builders selected from the group consisting of alkali metal, alkaline earth metal, ammonium, and mono-, di- and trialkanolammonium citrates, and mixtures thereof.

24. The method of claim 23, wherein the composition comprises sodium citrate, potassium citrate, or a mixture thereof.

25. The method of claim 1, wherein the composition further comprises one or more perfume oils.

26. The method of claim 1, wherein the composition further comprises one or more enzymes.