Autonomous cleaning apparatus and method

• US 6,689,276 B2
• Filed: 05/13/2002
• Issued: 02/10/2004
• Est. Priority Date: 11/10/1999
• Status: Expired due to Fees

• Current Assignee: Eco-Bat Technologies Limited (Quexco, Inc.)
• Original Assignee: Eco-Bat Technologies Limited (Quexco, Inc.)
• Inventors: Caruthers, Eddie Lee Jr.
• Primary Examiner(s): WEBB, GREGORY E
• Application Number:
  US10/144,331
• Publication Number:
  US 20020132752A1
• Time in Patent Office: 638 Days
• Field of Search: 210/687, 210/670, 813/7, 510/352, 510/446, 510/459, 252/179
• US Class Current: 210/687
• CPC Class Codes: B01F 2101/24 Mixing of ingredients for cleaning compositions
• CPC Class Codes: B01F 2101/4505 Mixing ingredients comprising detergents, soaps, for washing, e.g. washing machines
• CPC Class Codes: B01F 25/316 with containers for additional components fixed to the conduit
• CPC Class Codes: C11D 11/0094 Process for making liquid detergent compositions, e.g. slurries, pastes or gels
• CPC Class Codes: C11D 2111/12 Soft surfaces, e.g. textile
• CPC Class Codes: C11D 3/0052 Gas evolving or heat producing compositions
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/08 Silicates
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/128 Aluminium silicates, e.g. zeolites C11D3/1253 takes precedence

Abstract

An apparatus, method, and composition provide a long-term, solid cartridge made of cleaning agents mixed at an equilibrium concentration with a solubility limiting agent for controlling an equilibrium concentration of the composition in a solvent, such as water, for example. In use, the cleaning agents are dissolved only to a predetermined concentration needed for a single dose of a cleaning appliance, such as a clothes washing machine, for example. The apparatus may be configured to cyclically expose the solid cartridge to the solvent. A dosing amount of the solvent dissolves a pre-determined concentration of cleaning agents, controlled by the solubility limiting agent. The apparatus discharges the dose of cleaning agent to a cleaning appliance, and readies itself again by dissolving a dose of cleaning agent from a surface of the solid cartridge into the solvent. An equilibrium concentration of sodium bicarbonate with amorphous silica provides the cleaning agent and solubility control, with additional sodium sesquicarbonate for alkalinity control and zeolite for scavenging hard water ions. The putty-like mixture may be cast, cured, and cooled to form a solid, monolithic charge in a desirable shape for controlling surface area.

Claims

1. A method for delivering solvated cleaning agents to a cleaning appliance, the method comprising the steps of:

providing a dispensing apparatus;

providing a cleaning agent configured in a solid block having an outer surface, wherein the cleaning agent comprises a gas-releasing component configured to create mechanically explosive cleaning action at the interface between a soiling agent and a corresponding surface to be cleaned;

placing the cleaning agent into the dispensing apparatus;

providing a water supply;

routing a first portion of the water supply over the outer surface;

dissolving a selected portion of the solid block in the first portion of the water supply as a solvate; and

exposing the soiling agent and the surface to be cleaned to the solvate.

2. The method according to claim 1, wherein the cleaning agent further comprises an alkalinity agent as a pH regulator and a solubility control component to limit the amount of gas releasing component in solution.

3. The method according to claim 2, wherein the solubility control component is substantially insoluble in water.

4. The method according to claim 3, wherein the solubility control component is amorphous silica.

5. The method according to claim 2, wherein the gas releasing component is selected from carbonates and bicarbonates.

6. The method according to claim 5, wherein the gas releasing component is present in the cleaning agent in an amount from 20% to 60% by weight.

7. A method for delivering solvated cleaning agents to a cleaning appliance, the method comprising the steps of:

providing a dispensing apparatus;

providing a cleaning agent configured in a solid block having an outer surface, wherein the cleaning agent comprises;

a gas-releasing component as a cleaning agent selected from the group consisting of carbonates and bicarbonates, wherein the gas-releasing component is present in an amount from 20% to 60% by weight;

a solubility control component to limit the solubility of the cleaning composition, wherein the solubility control component is present in an amount from 5% to 35% by weight; and

an alkalinity agent as a pH regulator, wherein the alkalinity agent is present in an amount from 1% to 10% by weight;

placing the cleaning agent into the dispensing apparatus;

providing a water supply;

routing a first portion of the water supply over the outer surface;

dissolving a selected portion of the solid block in the first portion of the water supply as a solvate; and

exposing a surface to be cleaned to the solvate.

8. The method for delivering solvated cleaning agents to a cleaning appliance according to claim 7, wherein the solubility control component is an amorphous silica.

9. The method for delivering solvated cleaning agents to a cleaning appliance according to claim 7, wherein the alkalinity agent is selected from the group consisting of sodium sesquicarbonate, alkali hydroxide, alkali hydride, alkali oxide, alkali phosphate and alkali borate.

10. The method for delivering solvated cleaning agents to a cleaning appliance according to claim 7, wherein the cleaning agent further comprises a water softener which is a natural zeolite to solvate metal ions in a solution of water.

11. A method for delivering cleaning solution to a cleaning appliance, the method comprising:

flooding a dispensing apparatus;

dissolving a selected portion from an outer surface of a substantially monolithic solid charge of cleaning agent;

equilibrating a solution of the cleaning agent;

flushing the dispensing apparatus;

delivering the solution to a cleaning appliance; and

cleaning a surface of a material to be cleaned by a combination of reacting a base therewith and releasing a gas.

12. The method according to claim 11, wherein the dissolved cleaning agent consists essentially of:

a gas-releasing component as a cleaning agent selected from the group consisting of carbonates and bicarbonates;

a solubility control component which is an amorphous silica to limit the solubility of the cleaning composition;

an alkalinity agent as a pH regulator selected from the group consisting of sodium sesquicarbonate, alkali hydroxide, alkali hydride, alkali oxide, alkali phosphate and alkali borate; and

optionally a water softener which is a natural zeolite to solvate metal ions in a solution of water.

13. The method of claim 11, wherein the gas-releasing component is present in an amount from 20% to 60% by weight.

14. The method of claim 11, wherein the solubility control component is present in an amount from 5% to 35% by weight.

15. The method of claim 11, wherein the water softener is present in an amount from 1% to 20% by weight.

16. The method of claim 11, wherein the alkalinity agent is present in an amount from 1% to 10% by weight.

17. The method of claim 11, wherein the alkalinity agent is present in an amount sufficient to give a solution of the composition a pH greater than 7.

18. The method of claim 11, wherein the alkalinity agent is present in an amount sufficient to give a solution of the composition a pH from about 7.8 to about 8.8.