Cavity enhanced fiber optic and waveguide chemical sensor

• US 6,694,067 B1
• Filed: 01/05/2001
• Issued: 02/17/2004
• Est. Priority Date: 01/05/2001
• Status: Expired due to Term

• Current Assignee: Los Gatos Research Inc (ABB Limited)
• Original Assignee: Los Gatos Research Inc (ABB Limited)
• Inventors: OʼKeefe, Anthony, Scherer, James J.
• Primary Examiner(s): Bovernick, Rodney
• Assistant Examiner(s): HAHM, SARAH UH YOUNG
• Application Number:
  US09/755,925
• Time in Patent Office: 1,138 Days
• Field of Search: 385/12, 385/37, 385/15, 385/27, 385/31, 385/123, 385/129, 385/132, 385/141, 385/144, 385/145
• US Class Current: 385/12
• CPC Class Codes: G01N 2021/7716 in cladding
• CPC Class Codes: G01N 2021/7783 Transmission, loss
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B
• CPC Class Codes: G02B 6/02033 Core or cladding made from organic material, e.g. polymeric material G02B1/04 takes precedence
• CPC Class Codes: G02B 6/02057 comprising gratings

Abstract

Chemically specific fiber and waveguide sensors are formed in a fiber optic or optical waveguide material in which injected light is trapped within a Bragg grating optical cavity. The Bragg cavity effectively traps the light for long times, corresponding to effective path lengths equal to hundreds or thousands of meters in the fiber or waveguide medium. The Bragg grating optical cavity is surrounded by a cladding of chemically sensitive material whose optical properties change when exposed to specific chemicals or classes of chemicals. The change in the optical properties of the cladding results in a change in the light trapping characteristics of the fiber or waveguide. Changes in optical transmission of the fiber optic or waveguide sensor can then be related to the concentration of specific chemicals or classes of chemicals in the environment surrounding the sensor.

Claims

1. A chemical sensor, comprising:

a diode laser source producing laser light;

means for wavelength modulating the laser light output from the diode laser, the wavelength modulation amplitude being at least 0.1 nm and the modulation rate being at least 100 Hz;

an optical fiber waveguide having an input optically coupled to receive the modulated laser light and having an output, the optical fiber waveguide including a chemically sensitive cladding layer responsive to the presence of a specific class of chemicals in the environment around the cladding layer so as to produce a change in the cladding refractive index that alters the light propagation characteristics of the fiber waveguide, the optical fiber waveguide further including a fiber core with a pair of grating reflectors formed therein, the grating reflectors defining an optical cavity therebetween; and

a photodetector optically coupled to said output of said optical fiber waveguide to receive laser light transmitted through said fiber.

2. The sensor of claim 1 wherein said cladding layer is composed of a chemically sensitive polymer material.

3. The sensor of claim 2 wherein said polymer material is selected from the group consisting of polyoxyethylene (4) lauryl ether (POELE), poly(ethyleneglycol)methyl ether (POEME), and (45-55%) glycidoxypropylmethyl dimethyl siloxane copolymer.

4. The sensor of claim 1 wherein the response of said cladding layer to the presence of chemicals is reversible.

5. The sensor of claim 1 wherein said grating reflectors have reflectivities of at least 99%.

6. The sensor of claim 1 wherein said grating reflectors are spaced apart by at least 1 cm.

7. The sensor of claim 1 wherein said modulating means comprises a modulated drive current power supply.

8. The sensor of claim 1 wherein said wavelength-modulated diode laser source has a central output wavelength at or near a minimum absorption loss wavelength of said optical fiber waveguide.

9. A sensor, comprising:

a laser light source producing laser light and which is wavelength modulated over a plurality of optical cavity modes at a modulation rate of at least 100 Hz;

a waveguide having an input and optically coupled to receive said laser light and having an output and, the waveguide having an environmentally sensitive cladding layer responsive to the presence of a measurand of interest in the environment around said cladding layer in a manner that alters the light propagation properties of said waveguide, the waveguide having a pair of grating reflectors formed therein and defining an optical cavity therebetween; and

a photodetector optically coupled to said output of said waveguide to receive laser light transmitted through said waveguide.