Golf ball with sulfur cured inner core component

• US 6,695,718 B2
• Filed: 06/29/2001
• Issued: 02/24/2004
• Est. Priority Date: 06/01/1993
• Status: Expired due to Fees

• Current Assignee: Callaway Golf Company
• Original Assignee: Top-Flite Golf Company (Callaway Golf Company)
• Inventors: Nesbitt, R. Dennis
• Primary Examiner(s): Graham, Mark S.
• Assistant Examiner(s): Gorden, Raeann
• Application Number:
  US09/894,960
• Publication Number:
  US 20020010037A1
• Time in Patent Office: 970 Days
• Field of Search: 473/373, 473/374, 473/376, 473/367, 473/368, 473/377
• US Class Current: 473/374
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/00621 Centre hardness
• CPC Class Codes: A63B 37/00622 Surface hardness
• CPC Class Codes: A63B 37/0064 Diameter
• CPC Class Codes: A63B 37/0066 Density; Specific gravity
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/02 Special cores balls with finger holes A63B37/0001, golf ball cores A63B37/005
• CPC Class Codes: A63B 37/04 Rigid cores
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

A golf ball is disclosed that includes a core assembly comprising a center core component and at least one core layer and a cover comprising at least one layer. The center core component preferably is formed from a sulfur-cured polybutadiene. The core layer component preferably is formed from a peroxide-cured polybutadiene and a metal salt of an unsaturated fatty acid such as zinc diacrylate or zinc dimethacrylate. The resulting golf ball of the present invention provides enhanced playability characteristics (i.e., spin and feel) without sacrificing distance or durability properties. The sulfur-cured center core component exhibits a remarkable combination of properties—a high resiliency coupled with being very soft.

Claims

1. A golf ball comprising:

a center core component formed from a first composition comprising a cis-1,4 polybutadiene and a sulfur curing agent, wherein said sulfur curing agent comprises at least one of N-oxydiethylene 2-benzothiazole sulfenamide, N,N-di-orthotolyguanidine, bismuth dimethyldithiocarbamate, N-cyclohexl 2-benzothiazole sulfenamide, N,N-diphenylguanidine or combinations thereof;

at least one core layer disposed about said center core component thereby forming an intermediate ball, said core layer formed from a second composition comprising a cis-1,4 polybutadiene and a peroxide curing agent; and

at least one cover layer disposed about said core layer thereby forming said golf ball.

2. The golf ball of claim 1 wherein said center core component has a diameter of from about 0.35 inches to about 1.20 inches.

3. The golf ball of claim 2 wherein said center core component is free of zinc diacrylate.

4. The golf ball of claim 1 wherein said core layer has a diameter of from about 1.450 inches to about 1.650 inches.

5. The golf ball of claim 1 wherein said golf ball has a Shore D cover hardness of from about 35 to about 90.

6. The golf ball of claim 1 wherein said polybutadiene utilized in at least one of said first composition and said second composition has a cis-1,4 content greater than 90 percent.

7. The golf ball of claim 1 wherein said center core component has a specific gravity of from about 1.0 to about 1.8.

8. The golf ball of claim 1 wherein said center core component exhibits a specific gravity of less than 1.0.

9. The golf ball of claim 1 wherein said center core component comprises microballoons, cellular foam materials, or combinations thereof.

10. The golf bail of claim 1 wherein said first composition also comprises an accelerator.

12. The golf ball of claim 1 wherein said peroxide curing agent comprises at least one of dicumyl peroxide;

2,5-dimethyl-2,5-di(t-butylperoxy) hexane;

2,5-dimethyl-2,5-di(t-butylperoxy) hexyne;

2,5-dimethyl-2,5-di(benzoylperoxy) hexane;

2,2′

-bis(t-butylperoxy)-di-iso-propylbenzene;

1,1-bis(t-butylperoxy)-3,3,5-trimethyl cyclohexane;

n-butyl 4,4-bis(t-butyl-peroxy) valerate;

t-butyl perbeuzoate;

benzoyl peroxide;

t-butyl peroxy-3,5,5 trimethylhexanoate or combinations thereof.

11. A golf ball comprising:

a center core component formed from a first composition comprising a cis-1,4 polybutadiene and a sulfur curing agent;

at least one core layer disposed about said center core component thereby forming an intermediate ball, said core layer formed from a second composition comprising a cis-1,4 polybutadiene and a peroxide curing agent; and

at least one cover layer disposed about said core layer thereby forming said golf ball;

wherein said first composition also comprises an accelerator; and

wherein said accelerator comprises at least one of mercaptobenzothiazoles, sulfenamides, dithiocarbamates, thiuram sulfides, guanidines, thioureas, xanthates, dithiophosphates, aldehyde-amines, dibenzothiadyl disulfide, N,N′

-diccyclohexyl-2-benzothiadylsulfenamide, hexamethylenetetramine, mercaptbenzothiazole, tetramethylthiuram disulfide, tetraethylthiuram disulfide, tetrabutylthiuram disulfide or combinations thereof.

13. A golf ball comprising:

a generally spherical inner core component formed from a first composition including (i) a cis-1, 4 polybutadiene having a cis-1, 4 content greater than 90 percent, (ii) a sulfur curing agent comprising at least one of N-oxydiethylene 2-benzothiazole sulfenamide, N,N-di-orthotolyguanidine, bismuth dimethyldithiocarbamate, N-cyclohexyl 2-benzothiazole sulfenamide, N,N-diphenylguanidine or combinations thereof, and (iii) an accelerator comprising at least one of mercaptobenzothiazoles, sulfenamides, dithiocarbamates, thiruam sulfides, guanidines, thioureas, xanthates, dithiophosphates, aldehyde-amines, dibenzothiadyl disulfide, N,N′

-diccyclohexyl-2-benzothiadylsulfenamide, hexamethylenetetramine, mercaptbenzothiazole, tetramethylthiuram disulfide, tetraethylthiuram disulfide, tetrabutylthiuram disulfide or combinations thereof;

at least one core layer disposed on said inner core component, said core layer formed from a second composition including (i) a cis-1,4 polybutadiene having a cis-1,4 content greater than 90 percent, and (ii) a peroxide curing agent comprising at least one of dicumyl peroxide;

2,5-dimethyl-2,5-di(t-butylperoxy) hexane;

2,5-dimethyl-2,5-di(t-butylperoxy) hexyne;

2,5-dimethyl-2,5-di(benzoylperoxy) hexane;

2,2′

-bis(t-butylperoxy)-di-iso-propylbenzene;

1,1-bis(t-butylperoxy)-3,3,5-trimethyl cyclohexane;

n-butyl 4,4-bis(t-butyl-peroxy) valerate;

t-butyl perbenzoate;

benzoyl peroxide;

n-butyl 4,4′

-bis(butylperoxy) valerate;

di-t-butyl peroxide;

2,5-di-(t-butylperoxy) -2,5 dimethyl hexane;

or combinations thereof; and

at least one cover layer disposed on said core Layer.

14. The golf ball of claim 13 wherein said cis-1,4 polybutadiene of one of said first composition and said second composition has a cis-1,4 content greater than 96 percent.

15. The golf ball of claim 13 wherein at least one of said, inner core component, said core layer, and said cover layer comprises a heavy weight filler comprising at least one of graphite, precipitated hydrated silica, clay, talc, asbestos, glass aramid fibers, mica, calcium metasilicate, barium sulfate, zinc sulfide silicates, diatomaceous earth, calcium carbonate, magnesium carbonate, titanium, tungsten, aluminum, bismuth, nickel, molybdenum, iron, copper, brass, boron, bronze, cobalt, beryllium, zinc, tin, zinc oxide, iron oxide, aluminum oxide, titanium oxide, magnesium oxide, zirconium oxide, zinc stearate, calcium stearate, barium stearate, lithium stearate, magnesium stearate, carbon black, natural bitumen, cotton flock, cellulose flock, leather fiber, or combinations thereof.