Method for production of (meth) acrylic acid and/or (meth)acrylic esters

• US 6,695,928 B1
• Filed: 03/01/2000
• Issued: 02/24/2004
• Est. Priority Date: 03/02/1999
• Status: Expired due to Term

• Current Assignee: Nippon Shokubai Company Limited
• Original Assignee: Nippon Shokubai Company Limited
• Inventors: Nishimura, Takeshi, Nakahara, Sei, Ueoka, Masatoshi
• Primary Examiner(s): Gulakowski, Randy
• Assistant Examiner(s): KORNAKOV, MIKHAIL
• Application Number:
  US09/516,680
• Time in Patent Office: 1,455 Days
• Field of Search: 134/2, 134/26, 134/29, 134/22.1, 134/22.12, 134/22.13, 134/22.17, 134/35, 134/36, 134/40, 134/42, 203/DIG.21, 203/8, 203/37
• US Class Current: 134/26
• CPC Class Codes: C07C 51/44 by distillation
• CPC Class Codes: C07C 51/46 by azeotropic distillation
• CPC Class Codes: C07C 57/04 Acrylic acid; Methacrylic acid
• CPC Class Codes: C07C 67/54 by distillation
• CPC Class Codes: C07C 69/54 Acrylic acid esters; Methacrylic acid esters
• CPC Class Codes: Y10S 203/22 Accessories

Abstract

A method for the production of (meth)acrylic acid and/or a (meth)acrylic ester is provided. This method for the production of (meth)acrylic acid and/or a (meth)acrylic ester includes washing the device constructed for the production thereof with a basic solution and subsequently rinsing them with a solvent for the purpose of removing solid substances such as polymer and precipitate which occur during the production of (meth)acrylic acid and/or a (meth)acrylic ester.

Claims

1. A method for removing solid substances adhered during production of (meth)acrylic acid, which comprises:

washing a device constructed for the production thereof with a basic solution; and

rinsing it with a solvent until the pH value of the waste water is not more than 9 at 50°

C.

for the purpose of removing solid substances such as polymer and precipitate formed during the course of the production, the solid substances being adhered to the surface of a flow way of the (meth)acrylic acid in the device;

wherein removing of adhered solid substance is performed without overhauling of the device.

2. A method according to claim 1 further containing a pre-washing with a solvent prior to the washing with the basic solution.

8. A method according to claim 1, wherein the solvent is water.

10. A method according to claim 1, wherein the rinsing with water subsequent to the washing with the basic solution is continued until the total content of an alkali metal and alkaline earth metal in the waste water is not more than 50 mg/liter.

11. A method according to claim 10, wherein the rinsing is continued until the total content of the alkali metal and alkaline earth metal therein is not more than 10 mg/liter.

3. A method for removing solid'"'"'substances adhered during production of a (meth)acrylic ester, which comprises:

pre-washing a device constructed for the production thereof with a solvent,

washing it with a basic solution; and

rinsing it with a solvent until the pH value of the waste water is not more than 9 at 50°

C.

for the purpose of removing solid substances such as polymer and precipitate formed during the course of the production, the solid substances being adhered to the surface of a flow way of the (meth)acrylic ester in the device;

wherein removing of adhered solid substances is performed without overhauling of the device.

4. A method for removing solid substances adhered during production of (meth)acrylic acid and/or a (meth)acrylic ester, which comprises:

pre-washing a device constructed for the production thereof with a solvent

washing it with a basic solution being a solution of at least one member selected from the group consisting of an oxide, hydroxide, carbonate, and hydrogen carbonate of an alkali metal and an oxide and hydroxide of an alkaline earth metal; and

rinsing it with a solvent until the pH value of the waste water is not more than 9 at 50°

C.

for the purpose of removing solid substances such as polymer and precipitate formed during the course of the production, the solid substances being adhered to the surface of a flow way of the (meth)acrylic acid and/or the (meth)acrylic ester in the device;

wherein removing of adhered solid substances is performed without overhauling of the device.

5. A method according to claim 4, wherein the basic solution is a solution of at least one member selected from the group consisting of an oxide, hydroxide, carbonate, and hydrogen carbonate of an alkali metal.

6. A method according to claim 5, wherein the basic solution is a solution of a hydroxide of an alkali metal.

7. A method according to claim 6, wherein the alkali metal is sodium or potassium.

9. A method according to claim 4, wherein the solvent to be used for the pre-washing and the rinsing is water.

12. A method according to claim 9, wherein the water to be used for the rinsing has an electric conductivity of not more than 10 mS/m.

13. A method according to claim 12, wherein the water to be used for the rinsing has an electric conductivity of not more than 1 mS/m.

14. A method according claim 4, wherein the devices is selected from the group consisting of a distillation column, an absorption column, and a stripping column, and further includes accessories which are annexed thereto and pipes between therewith.

15. A method according to claim 4, wherein the washing with the basic solution and/or the rinsing with the solvent is performed under temperature(s) in the range of 50°

C. to the boiling point thereof used.

16. A method according to claim 15, wherein the washing with the basic solution and/or the rinsing with the solvent is performed under temperature(s) in the range of 80°

C. to the boiling point thereof used.

17. A method for removing solid substances adhered during production of (meth)acrylic acid and/or a (meth)acrylic ester, which comprises:

pre-washing a device constructed for the production thereof with a solvent

washing it under a reduced pressure with a basic solution being a solution of at least one member selected from the group consisting of an oxide, hydroxide, carbonate, and hydrogen carbonate of an alkali metal and an oxide and hydroxide of an alkaline earth metal; and

rinsing it with a solvent under a reduced pressure until the pH value of the waste water is not more than 9 at 50°

C.

for the purpose of removing solid substances such as polymer and precipitate formed during the course of the production, the solid substances being adhered to the surface of a flow way of the (meth)acrylic acid and/or the (meth)acrylic ester in the device.

18. A method according to claim 17, wherein the reduced pressure is in the range of 100 to 900 hPa.

19. A method according to claim 17, wherein the reduced pressure is in the range of 150 to 300 hPa.