Process for the fabrication of glass ceramic structures

• US 6,699,341 B2
• Filed: 07/09/2002
• Issued: 03/02/2004
• Est. Priority Date: 06/20/2000
• Status: Expired due to Term

• Current Assignee: SCHOTT Glass
• Original Assignee: SCHOTT Glass
• Inventors: Conzone, Samuel David, Marker, Alexander J. III
• Primary Examiner(s): Mayes, Curtis
• Application Number:
  US10/190,724
• Publication Number:
  US 20020192422A1
• Time in Patent Office: 602 Days
• Field of Search: 156/89.11, 156/325, 156/153, 106/286.1, 106/286.2, 106/286.8
• US Class Current: 156/89.11
• CPC Class Codes: C03C 27/044 of glass, glass-ceramic or ceramic material only
• CPC Class Codes: C03C 27/06 Joining glass to glass by processes other than fusing fusing C03B23/20; units for use as elements for closing wall or like openings and comprising two or more parallel glass panes in spaced relationship, the panes being permanently secured together E06B3/66
• CPC Class Codes: Y10T 428/21 Circular sheet or circular blank
• CPC Class Codes: Y10T 428/24273 including aperture
• CPC Class Codes: Y10T 428/24322 Composite web or sheet

Abstract

A method for fabricating composite light-weighted glass ceramics, suitable for use as, e.g. mirror blanks or microlithography stages, at low temperatures is disclosed. Component pieces are polished then joined at low temperature using a silicate-containing joining liquid. Assembly is then performed in such a way that the joining liquid forms an interface between each component. After a period of low or slightly elevated temperature curing, rigid joints are formed throughout and the composite is dimensionally, vibrationally, and temperature stable and can withstand tensile stresses >4000 psi. The room-temperature cured composite can be heat treated using a slow, systematic temperature increase to dehydrate the joints. A sealing coating may optionally be provided to prevent excess dried joining liquid from flaking off the formed joint.

Claims

1. A low-temperature process for the fabrication of lightweight composite glass ceramic structures, comprising:

providing a plurality of glass ceramic components, said glass ceramic components each being polished to form at least one joining surface on each component,

providing a silicate-containing joining liquid to at least one of the joining surfaces,

bringing the joining surfaces of the plurality of glass components together to form a joint,

allowing the joint to cure for a period of time of at least 20 hours at a temperature of at least 20 degrees C., whereby a cured joint is formed between said plurality of glass components, and

dehydrating the cured joint gradually by raising the temperature slowly and maintaining an elevated temperature below the glass transition temperature of the glass ceramic for at least 20 hours.

2. A method as claimed in claim 1, wherein the step of dehydrating comprises gradually raising the temperature at a rate which allows dehydration of the joint without imparting damage to the joint from accelerated H₂O evaporation.

3. A process as claimed in claim 2, wherein the dehydrating temperature is from 60 to 600 degrees C.

4. A process as claimed in claim 3, wherein the temperature is below 120 degrees C.

5. A process as claimed in claim 1, wherein the glass ceramic components are components made of a material sold under the trademark ZERODUR®

.

6. A process as claimed in claim 1, wherein the glass ceramic components include a low expansion material prepared by partially ceramizing a lithium alumino silicate glass.

7. A process as claimed in claim 1, wherein the glass ceramic components include a material selected from the group consisting of ULE, NEXCERA CLEARCERAM VO2, ASTROSITALL and SITALL.

8. A process as claimed in claim 1, wherein the silicate containing liquid is a lithium silicate containing liquid or a sodium silicate containing liquid.

9. A process as claimed in claim 1, wherein the silicate containing liquid is an alkali silicate, mixed alkaline earth silicate, or mixed alkali/alkaline earth silicate liquid.

10. A process as claimed in claim 2, wherein the step of gradually raising the temperature comprises increasing the temperature at a rate less than or equal to 3 degrees K/hour.

11. A process as claimed in claim 10, wherein the temperature is periodically stabilized and held.

12. A process as claimed in claim 11, wherein the temperature is stabilized at intervals of from 5 to 20 degrees C. and held for at least 10 hours.

13. A process as claimed in claim 12, wherein the temperature is stabilized at intervals of about 10 degrees C. and held for about 20 hours.

14. A process as claimed in claim 1, wherein the components include at least one component with a hollowed out light-weighted portion.

15. A process as claimed in claim 1, wherein the components comprise segments of a light-weighted core.

16. A process as claimed in claim 1, wherein the components include a mirror blank.

17. A process as claimed in claim 1, wherein the period of time is at least one day.

18. A process as claimed in claim 1, wherein the period of time is at least one week.

19. A process as claimed in claim 1, wherein the step of providing the silicate containing liquid comprises applying the silicate containing liquid in an amount of at least 0.01 microliter/cm².

20. A process according to claim 1, wherein the glass ceramic components have a CTE of less than 75 ppb/K from 0-500°

C.