Switchable volume hologram materials and devices

• US 6,699,407 B1
• Filed: 03/02/1998
• Issued: 03/02/2004
• Est. Priority Date: 07/12/1996
• Status: Expired due to Term

• Current Assignee: Leidos, Inc. (Leidos Holdings, Inc.)
• Original Assignee: Science Applications International Corporation
• Inventors: Tondiglia, Vince P., Natarajan, Lalquidi V., Bunning, Timothy J., Sutehrland, Richard L.
• Primary Examiner(s): WU, SHEAN CHIU
• Application Number:
  US09/033,512
• Time in Patent Office: 2,192 Days
• Field of Search: 252/299.01, 252/582, 430/1, 430/20, 359/15
• US Class Current: 252/582
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: G02F 1/13342 Holographic polymer dispersed liquid crystals
• CPC Class Codes: G03F 7/001 Phase modulating patterns, e.g. refractive index patterns
• CPC Class Codes: G03F 7/031 Organic compounds not covered by group G03F7/029
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 1/0248 Volume holograms
• CPC Class Codes: G03H 2001/026 Recording materials or recording processes G03H2226/11 takes precedence; corresponding details, see subgroups of G03H2260/00
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G03H 2260/33 Having dispersed compound
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between early 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.

Claims

1. A method for preparing an electrically switchable reflection hologram, comprising:

disposing a polymer-dispersed liquid crystal material between transparent plates, wherein the polymer-dispersed liquid crystal material comprising, before exposure;

(a) a polymerizable;

(b) a liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

disposing the polymer-dispersed liquid crystal material within a magnetic field wherein the orientation of at least a portion of the magnetic field is directed along an axis substantially parallel to the plane of the plates; and

exposing an interference pattern inside the polymer-dispersed liquid crystal material while the polymer-dispersed liquid crystal material is disposed within the magnetic field.

2. A method for preparing a switchable reflection hologram, comprising the steps of:

disposing a polymer-dispersed liquid crystal material between transparent plates;

exposing an interference pattern inside the polymer-dispersed liquid crystal material; and

applying a shear stress field whereby the symmetry axis of the liquid crystal is oriented substantially parallel to the transparent plates.

3. A switchable reflection hologram comprising:

a polymer-dispersed liquid crystal material wherein the reflective material is disposed adjacent to the polymer-dispersed material and wherein the hologram is made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure;

(a) a polymerizable monomer;

(b) a negative dielectric anisotropy liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye.

4. The switchable reflection hologram of claim 3, wherein the negative dielectric anisotropy liquid crystal comprises a combination of positive dielectric anisotropy liquid crystals and negative dielectric anisotropy liquid crystals whereby the liquid crystal has a negative dielectric anisotropy at the frequency of the electric field.

5. The switchable reflection hologram of claim 3, wherein the negative dielectric anisotropy liquid crystal comprises:

6. The switchable reflection hologram of claim 3, wherein the negative dielectric anisotropy liquid crystal comprises:

7. The switchable reflection hologram of claim 3, wherein the negative dielectric anisotropy liquid crystal comprises:

8. The switchable reflection hologram of claim 3, wherein the negative dielectric anisotropy liquid crystal comprises:

9. The switchable reflection hologram of claim 3, wherein the negative dielectric anisotropy liquid crystal comprises:

10. The switchable reflection hologram of claim 4, wherein the liquid crystal comprises:

11. The switchable reflection hologram of claim 4, wherein the liquid crystal comprises:

p-pentylphenyl-2-chloro-4-(p-pentylbenzoyloxy) benzoate; and

p-heptylphenyl-2-chloro-4-(p-octylbenzoyloxy) benzoate.

12. A switchable reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material in the presence of a magnetic field, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a positive dielectric anisotropy liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

wherein the hologram has opposing surfaces and a plurality of polymer regions having a first refractive index and polymer-dispersed liquid crystal regions having a second refractive index disposed substantially parallel to the opposing surfaces of the hologram;

an electrically conductive material associated with each of the opposing surfaces of the hologram and configured so that an electrical field can be applied across the hologram to modify the refractive index of the polymer-dispersed liquid crystal regions; and

wherein the symmetry axis of the positive dielectric anisotropy liquid crystal is oriented substantially parallel to the opposing surfaces of the hologram.

16. The switchable reflection hologram of claim 12, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

17. The switchable reflection hologram according to claim 12, wherein the polymer-dispersed liquid crystal material further comprises, before exposure, a surfactant.

13. A switchable reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material in the presence of a magnetic field, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a positive dielectric anisotropy liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

wherein the hologram has opposing surfaces and a plurality of alternating planes of polymer channels having a first refractive index and polymer-dispersed liquid crystal channels having a second refractive index disposed substantially parallel to the opposing surfaces of the hologram;

an electrically conductive material associated with each of the opposing surfaces of the hologram and configured so that an electrical field can be applied across the hologram to modify the refractive index of the polymer-dispersed liquid crystal channels; and

wherein the symmetry axis of the positive dielectric anisotropy liquid crystal is oriented substantially parallel to the opposing surfaces of the hologram.

18. The switchable reflection hologram of claim 13, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

19. The switchable reflection hologram according to claim 13, wherein the polymer-dispersed liquid crystal material further comprises, before exposure, a surfactant.

14. A switchable reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material and applying a shear stress field, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a positive dielectric anisotropy liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

wherein the hologram has opposing surfaces and a plurality of polymer regions having a first refractive index and polymer-dispersed liquid crystal regions having a second refractive index disposed substantially parallel to the opposing surfaces of the hologram;

an electrically conductive material associated with each of the opposing surfaces of the hologram and configured so that an electrical field can be applied across the hologram to modify the refractive index of the polymer-dispersed liquid crystal regions; and

wherein the symmetry axis of the positive dielectric anisotropy liquid crystal is oriented substantially parallel to the opposing surfaces of the hologram.

20. The switchable reflection hologram of claim 14, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

21. The switchable reflection hologram according to claim 14, wherein the polymer-dispersed liquid crystal material further comprises, before exposure, a surfactant.

15. A switchable reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material and applying a shear stress field, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a positive dielectric anisotropy liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

wherein the hologram has opposing surfaces and a plurality of alternating planes of polymer channels having a first refractive index and polymer-dispersed liquid crystal channels having a second refractive index disposed substantially parallel to the opposing surfaces of the hologram;

an electrically conductive material associated with each of the opposing surfaces of the hologram and configured so that an electrical field can be applied across the hologram to modify the refractive index of the polymer-dispersed liquid crystal channels; and

wherein the symmetry axis of the positive dielectric anisotropy liquid crystal is oriented substantially parallel to the opposing surfaces of the hologram.

22. The switchable reflection hologram of claim 15, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

23. The switchable reflection hologram according to claim 15, wherein the polymer-dispersed liquid crystal material further comprises, before exposure, a surfactant.