Lithium metal dispersion in secondary battery anodes

• US 6,706,447 B2
• Filed: 12/19/2001
• Issued: 03/16/2004
• Est. Priority Date: 12/22/2000
• Status: Expired due to Term

• Current Assignee: Livent USA Corporation (Livent Corp.)
• Original Assignee: FMC Wyoming Corporation (Tronox Holdings Plc)
• Inventors: Burba, John L. III, Gao, Yuan
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US10/025,946
• Publication Number:
  US 20020119373A1
• Time in Patent Office: 818 Days
• Field of Search: 429/224, 429/231.4, 429/231.8, 429/232, 429/231.95
• US Class Current: 429/231.4
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H01M 2004/021 Physical characteristics, e.g. porosity, surface area
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/133 Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/387 Tin or alloys based on tin
• CPC Class Codes: H01M 4/40 Alloys based on alkali metals
• CPC Class Codes: H01M 4/405 Alloys based on lithium
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present invention is a secondary battery having a high specific capacity and good cycleability, and that can be used safely. The secondary battery is manufactured to include an anode formed from a host material capable of absorbing and desorbing lithium in an electrochemical system such as a carbonaceous material, and lithium metal dispersed in the host material. The freshly prepared anodes of the invention are combined with a positive electrode including an active material, a separator that a separates the positive electrode and the negative electrode, and an electrolyte in communication with the positive electrode and the negative electrode. The present invention also includes a method of preparing a freshly prepared anode and a method of operating a secondary battery including the anode of the invention.

Claims

1. An anode for a secondary battery comprising a host material that is capable of absorbing and desorbing lithium in an electrochemical system and lithium metal dispersed in the host material, wherein the amount of lithium metal in said anode is no more than the maximum amount sufficient to intercalate in, alloy with, or be absorbed by the host material in said anode when the anode is recharged.

2. The anode according to claim 1, wherein the lithium metal is lithium powder.

3. The anode according to claim 2, wherein the lithium powder has a mean particle size of less than about 20 microns.

4. The anode according to claim 1, being capable of reversibly lithiating and delithiating at an electrochemical potential relative to lithium metal of from greater than 0.0 V to less than or equal to 1.5 V.

5. The anode according to claim 1, wherein the host material comprises one or more materials capable of reversibly lithiating and delithiating at an electrochemical potential versus lithium of from greater than 0.0 V to less than or equal to 1.5 V.

6. The anode according to claim 1, wherein the host material comprises one or more materials selected from the group consisting of carbonaceous materials, Si, Sn, tin oxides, composite tin alloys, transition metal oxides, lithium metal nitrides and lithium metal oxides.

7. The anode according to claim 1, wherein the host material comprises a carbonaceous material.

8. The anode according to claim 7, wherein the carbonaceous material is graphite.

9. The anode according to claim 8, wherein the host material further comprises carbon black.

10. A secondary battery including the anode of claim 1.

11. A secondary battery comprising:

a positive electrode including an active material;

a negative electrode comprising a host material that is capable of absorbing and desorbing lithium in an electrochemical system and lithium metal dispersed in the host material, wherein the amount of lithium metal in said negative electrode is no more than the maximum amount sufficient to intercalate in, alloy with, or be absorbed by the host material in said anode when said battery is recharged;

a separator for separating the positive electrode and the negative electrode; and

an electrolyte in communication with the positive electrode and the negative electrode.

12. The secondary battery according to claim 11, wherein the positive electrode includes a compound that can be lithiated at an electrochemical potential of 2.0 to 5.0V versus lithium as the active material.

13. The secondary battery according to claim 12, wherein the active material in the positive electrode is selected from the group consisting of MnO₂, V₂O₅ and MoS₂, and mixtures thereof.

14. The secondary battery according to claim 12, wherein the active material in the positive electrode comprises MnO₂.

15. The secondary battery according to claim 12, wherein the active material in the positive electrode is LiMn₂O₄.

16. The secondary battery according to claim 11, wherein the lithium metal in said negative electrode is lithium powder.

17. The secondary battery according to claim 16, wherein the lithium metal in said negative electrode has a mean particle size of less than about 20 microns.

18. The secondary battery according to claim 11, wherein the negative electrode is capable of reversibly lithiating and delithiating at an electrochemical potential relative to lithium metal of from greater than 0.0 V to less than or equal to 1.5 V.

19. The secondary battery according to claim 11, wherein the host material in said negative electrode comprises one or more materials capable of reversibly lithiating and delithiating at an electrochemical potential versus lithium of from greater than 0.0 V to less than or equal to 1.5 V.

20. The secondary battery according to claim 11, wherein the host material in said negative electrode comprises one or more materials selected from the group consisting of carbonaceous materials, Si, Sn, tin oxides, composite tin alloys, transition metal oxides, lithium metal nitrides and lithium metal oxides.

21. The secondary battery according to claim 11, wherein the host material in said negative electrode comprises a carbonaceous material.

22. The secondary battery according to claim 21, wherein the carbonaceous material is graphite.

23. The secondary battery according to claim 22, wherein the host material further comprises carbon black.

24. The secondary battery according to claim 11, wherein the amount of active material in said positive electrode is sufficient to accept the removable lithium metal present in said negative electrode.

25. The secondary battery according to claim 11, being in a fully charged state.