Treatment of sugar juice

• US 6,709,527 B1
• Filed: 04/06/2001
• Issued: 03/23/2004
• Est. Priority Date: 04/07/1999
• Status: Expired due to Fees

• Current Assignee: Ufion Limited
• Original Assignee: Ufion Limited
• Inventors: Smith, Ian A., Fechter, Wolfgang L., Van De Pypekamp, Gerrit, Brewer, Peter A.
• Primary Examiner(s): Wood, Elizabeth D.
• Assistant Examiner(s): Hailey, Patricia L.
• Application Number:
  US09/700,947
• Time in Patent Office: 1,082 Days
• Field of Search: 127/46.2, 127/55, 127/58, 210/656, 210/687, 210/705
• US Class Current: 127/46.2
• CPC Class Codes: C13B 20/00 Purification of sugar juices
• CPC Class Codes: C13B 20/14 using ion-exchange materials
• CPC Class Codes: C13B 20/165 using membranes, e.g. osmosis, ultrafiltration electrodialysis C13B20/18
• CPC Class Codes: C13B 30/12 Recycling mother liquor or wash liquors

Abstract

A process for treating impure cane-derived sugar juice comprises subjecting, in a clarification stage, the juice to microfiltration/ultrafiltration to decrease the levels of suspended solids, organic non-sugar impurities and/or color therein. The resultant clarified sugar juice is sequentially passed through an ion exchange stage by bringing the juice into contact with a strong acid cation ion exchange resin in the hydrogen form, and thereafter into contact with an anion ion exchange resin in the hydroxide form. A purified sugar solution is withdrawn from the ion exchange stage, and concentrated to produce a syrup. The syrup is subjected to primary crystallization in a primary crystallization stage, to produce refined white sugar and primary mother liquor. The primary mother liquor is subjected to secondary crystallization in a secondary crystallization stage, to produce impure crystallized sugar and white strap molasses.

Claims

1. A process for treating impure cane derived sugar juice, which process comprises

subjecting, in a clarification stage, impure cane derived sugar juice to microfiltration/ultrafiltration to decrease the levels of suspended solids, organic non sugar impurities and/or colour therein;

sequentially passing the resultant clarified sugar juice through at least one ion exchange stage by bringing the clarified sugar juice into contact with a strong acid cation ion exchange resin in the hydrogen form, and thereafter into contact with an anion ion exchange resin in the hydroxide form;

withdrawing a purified sugar solution from the ion exchange stage;

concentrating the purified sugar solution, to produce a syrup;

subjecting the syrup to primary crystallization in at least one primary crystallization stage, to produce refined white sugar and primary mother liquor or molasses;

subjecting the primary mother liquor to secondary crystallization in at least one secondary crystallization stage, to produce impure crystallized sugar and secondary mother liquor or white strap molasses.

2. A process according to claim 1, wherein the Impure juice that is subjected to the microfiltration/ultrafiltration is at a temperature of at least 90°

C., with the microfiltration/ultrafiltration comprising passing the impure juice through a membrane In the size range 15000 Dalton to 300000 Dalton or 200 Angstrom to 0.2 micron, and wherein the clarified sugar juice is cooled to a temperature below 60°

C. before it enters the ion exchange stage.

3. A process according to claim 2, which includes concentrating the impure sugar juice, before it enters the clarification stage, to a sugar or sucrose concentration of at least 20% (m/m).

4. A process according to claim 2, wherein the clarified sugar juice is cooled to a temperature below 30°

C. before It enters the ion exchange stage, or while it passes through the ion exchange stage.

5. A process according to claim 1, wherein the ion exchange stage comprises a simulated moving bed arrangement or system.

6. A process according to claim 1, which includes subjecting the clarified sugar juice to a first pass through the ion exchange stage, to obtain a partially purified sugar solution, and thereafter subjecting the partially purified sugar solution to at least one further pass through the ion exchange stage, to obtain the purified sugar solution.

7. A process according to claim 6, which includes regenerating the resins from time to time by contacting the strong acid cation resin with a strong acid, with an acid stream rich in potassium salts thereby being obtained, and contacting the anion resin with a strong or weak base, with an alkaline stream with is rich in nitrogen thereby being obtained.

8. A process according to claim 6, wherein the concentration of the purified sugar solution into the syrup is effected by means of evaporation, with the resultant syrup having a sucrose or sugar concentration of about 65% (m/m).

9. A process according to claim 6, which includes subjecting the purified sugar solution from the ion exchange stage, or the partially purified sugar solution of the ion exchange stage, to further decolourizing in a decolourizing stage.

10. A process according to claim 9, wherein the decolourizing stage includes an anion resin In the chloride form, with the partially purified sugar solution, after the first pass thereof through the ion exchange stage, being brought into contact with the anion resin in the chloride form in the further ion exchange stage, and thereafter being subjected to the second pass through the ion exchange stage.

11. A process according to claim 9, wherein the decolourizing stage includes an anion resin in the hydroxide form, an absorption resin, activated carbon, or another absorption medium, with the purified sugar solution from the ion exchange stage being brought into contact with the anion resin, the absorption resin, the activated carbon or the other absorption medium.

12. A process according to claim 10, wherein the primary crystallization is effected in a plurality of sequential stages or boilings, with the secondary crystallization also being effected in a plurality of sequential stages or boilings, and with the Impure crystallized sugar from all the secondary crystallization stages or boilings being remelted or redissolved and recycled to the syrup ahead of the primary crystallization stage.

13. A process according to claim 6, which includes subjecting the syrup, prior to the primary crystallization, to decolourizing crystallization in a decolourizing crystallization stage, to produce low colour white sugar and tertiary molasses;

remelting or redissolving the low colour white sugar to produce a remelted sugar solution which is then subjected to the primary crystallization in the primary crystallization stage;

returning the primary mother liquor or molasses produced in the primary crystallization stage to the decolourizing crystallization stage;

subjecting the tertiary molasses from the decolourizing crystallization stage to mill crystallization in a mill crystallization stage to produce the white strap molasses and impure crystallized white sugar; and

returning the impure crystallized white sugar to the decolourizing crystallization stage, with the decolouring crystallization and the mill crystallization constituting the secondary crystallization.

14. A process for treating impure cane derived sugar juice, which process comprises subjecting, in a clarification stage, impure cane derived sugar juice to microfiltration/ultrafiltration to decrease the levels of suspended solids, organic non sugar impurities and/or colour therein;

sequentially passing the resultant clarified sugar juice through at least one ion exchange stage by bringing the clarified sugar juice into contact with a strong acid cation ion exchange resin in the hydrogen form, and thereafter into contact with an anion ion exchange resin in the hydroxide form;

withdrawing a purified sugar solution from the ion exchange stage;

subjecting the purified sugar solution from the ion exchange stage to further decolourizing in a decolourizing stage, to obtain a decolourized purified sugar solution;

concentrating the purified sugar solution, to produce a syrup;

subjecting the syrup to primary crystallization in at least one primary crystallization stage, to produce refined white sugar and primary mother liquor or molasses;

subjecting the primary mother liquor to secondary crystallization in at least one secondary crystallization stage, to produce impure crystallized sugar and secondary mother liquor or white strap molasses.

15. A process for treating impure cane derived sugar juice, which process comprises:

subjecting, in a clarification stage, impure cane derived sugar juice to microfiltration/ultrafiltration to decrease the levels of suspended solids, organic non sugar impurities and/or colour therein;

sequentially passing the resultant clarified sugar juice through an ion exchange stage comprising a simulated moving bed ion exchange system wherein the clarified sugar juice is brought into contact with a strong acid cation ion exchange resin in the hydrogen form, and thereafter into contact with an anion ion exchange resin in the hydroxide form;

cooling the clarified sugar juice to a temperature below 30°

C. before it enters the ion exchange stage, or while it passes through the ion exchange stage;

withdrawing a purified sugar solution from the ion exchange stage;

concentrating the purified sugar solution, to produce a syrup;

subjecting the syrup to primary crystallization in at least one primary crystallization stage, to produce refined white sugar and primary mother liquor or molasses;

subjecting the primary mother liquor to secondary crystallization in at least one secondary crystallization stage, to produce impure crystallized sugar and secondary mother liquor or white strap molasses.