Removal of sulfur compounds from wastewater

• US 6,709,592 B2
• Filed: 11/25/2002
• Issued: 03/23/2004
• Est. Priority Date: 02/25/2000
• Status: Expired due to Fees

• Current Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno, Nederlandse Organisatie Voor Toegepastnatuurwetenschappelljk Onderzoek Tno
• Original Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
• Inventors: Langerwerf, Josephus Sychbertus Adrianus, van Groenestijn, Johannes Wouterus
• Primary Examiner(s): Prince, Fred G.
• Application Number:
  US10/204,634
• Publication Number:
  US 20030141243A1
• Time in Patent Office: 484 Days
• Field of Search: 210/603, 210/612, 210/631, 951/58, 951/59, 952/35, 952/36, 423/243.01
• US Class Current: 210/603
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 3/286 including two or more steps
• CPC Class Codes: C12M 21/04 for producing gas, e.g. biogas digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10
• CPC Class Codes: C12M 47/18 Gas cleaning, e.g. scrubbers; Separation of different gases separating dispersed particles from gases or vapours B01D45/00; separation of gases or vapours B01D53/00; gas washing apparatus for laboratory uses B01L5/04
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The invention relates to a process for removal of sulfur compounds from wastewater, which process provides recovery of elemental sulfur. The process is carried out in two separate anaerobic reactors. In the first reactor organic compounds are converted to acid compounds and sulfur compounds are converted to sulfide compounds. The sulfide compounds are stripped from said first reactor with a stripping gas. Subsequently, the effluent of the first reactor is fed to a second anaerobic reactor, in which organic compounds, such as the acid compounds, are converted to produce biogas, while any unconverted sulfur compounds from the previous step are converted to sulfide compounds as well. Finally, the sulfide compounds are removed from the second reactor in a stripping system, and converted to elemental sulfur in an adsorber.

Claims

1. Process for removal of sulfur compounds from wastewater, comprising the steps of:

a) converting in a first anaerobic suspended sludge reactor organic compounds present in the wastewater to acid compounds, forming an effluent comprising the acid compounds;

b) converting the sulfur compounds to sulfide compounds in the first reactor, the remainder of the sulfur compounds being also comprised by said effluent;

c) removing sulfide compounds in said first reactor with a stripping gas, forming a gaseous effluent;

c2) concentrating said effluent, thus forming a clearer effluent and a more concentrated suspension of sludge, part of which suspension is recycled to said first reactor;

d) converting the acid compounds in said clearer effluent to biogas in a second anaerobic reactor; and

e) converting sulfur compounds in said clearer effluent to sulfide compounds in the second anaerobic reactor, forming a second liquid effluent.

2. Process according to claim 1, which further comprises a step f) of removing the sulfide compounds from said second effluent with a stripping system.

3. Process according to claim 2, wherein the removing of the sulfide in step f) comprises contacting the liquid effluent from the second reactor with a stripping gas comprising CO2, which is an off-gas from a combustion process.

4. Process according to claim 2, wherein step f) comprises stripping the liquid effluent from the second reactor without recycling the liquid.

5. Process according to claim 2, wherein step f) comprises contacting the containing biogas effluent and/or a gaseous sulfide containing effluent obtained from stripping the liquid effluent of the second reactor with a redox liquid at a pH of 7-9, which redox liquor comprises a bicarbonate buffer.

6. Process according to claim 2, wherein step f) comprises contacting the sulfide containing biogas effluent and/or a gaseous sulfide containing effluent obtained from stripping the liquid effluent of the second reactor with a redox liquor, by which sulfide is converted to sulfur, forming a sulfur comprising effluent, which is fed to a coagulation tank, a flocculation tank and a settler tank, thus forming a sulfur rich effluent.

7. Process according to claim 2, wherein the removing of the sulfide in step f) comprises contacting the liquid effluent from the second reactor with an oxygen containing gas, producing a sulfide containing gaseous effluent and feeding this gasous effluent to an absorber in which it is contacted with a redox liquor, which absorbs the sulfide.

8. Process according to claim 7, wherein the sulfide from the biogas effluent from the second reactor and the sulfide stripped from the liquid effluent from the second reactor are absorbed in separate absorbers using the same recirculating redox liquor, and wherein the sulfide from said gaseous effluent from the second reactor is contacted with said redox liquor in co-current.

9. Process according to claim 1, in which the gaseous effluent of step c) is contacted with a redox liquor or an alkaline solution, thereby removing sulfide from the gaseous effluent and producing clean stripping gas which is recirculated to the process in step c).

10. Process according to claim 1, wherein the sludge age in the first reactor is from 1-4 days.

11. Process according to claim 1, wherein an anaerobic contact process (ACP) is carried out in the first reactor.

12. Process according to claim 1, which further comprises:

g) contacting the biogas from step d) with a redox liquor, which absorbs sulfide in the redox liquor;

h) regenerating the redox liquor by contacting it with an oxygen containing gas.