Nanocomposite materials with engineered properties

• US 6,710,366 B1
• Filed: 08/02/2002
• Issued: 03/23/2004
• Est. Priority Date: 08/02/2001
• Status: Expired due to Term

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: UltraDots, Inc. (Omnipv Incorporated)
• Inventors: Keshavarz, Majid, Lee, Howard Wing Hoon
• Primary Examiner(s): CRANE, SARA W
• Application Number:
  US10/212,005
• Time in Patent Office: 599 Days
• Field of Search: 257/14, 257/15, 257/19, 257/13, 257/21, 257/40, 257/103, 359/248, 359/328, 359/329
• US Class Current: 257/14
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: G02B 2006/12097 Ridge, rib or the like
• CPC Class Codes: G02B 2006/12145 Switch
• CPC Class Codes: G02B 2006/12147 Coupler
• CPC Class Codes: G02B 2006/12159 Interferometer
• CPC Class Codes: G02B 2006/12195 Tapering
• CPC Class Codes: G02B 6/122 Basic optical elements, e.g. light-guiding paths
• CPC Class Codes: G02B 6/1225 comprising photonic band-gap structures or photonic lattices
• CPC Class Codes: G02F 1/01791 Quantum boxes or quantum dots
• CPC Class Codes: G02F 1/217 Multimode interference type
• CPC Class Codes: G02F 1/3515 All-optical modulation, gating, switching, e.g. control of a light beam by another light beam G02F1/353, G02F1/37, G02F1/39 take precedence
• CPC Class Codes: G02F 1/3517 using an interferometer
• CPC Class Codes: G02F 1/3521 using a directional coupler
• CPC Class Codes: G02F 1/3556 Semiconductor materials, e.g. quantum wells
• CPC Class Codes: G02F 1/365 in an optical waveguide structure G02F1/377, G02F1/395 take precedence
• CPC Class Codes: G02F 2/006 All-optical wavelength conversion
• CPC Class Codes: G02F 2202/32 Photonic crystals
• CPC Class Codes: G02F 2202/36 Micro- or nanomaterials
• CPC Class Codes: H01L 29/127 Quantum box structures

Abstract

The invention relates to a nanocomposite material. The nanocomposite material comprises a matrix material and a plurality of quantum dots dispersed in the matrix material. The nanocomposite material has a nonlinear index of refraction γ that is at least 10⁻⁹ cm²/W when irradiated with light having a wavelength λ between approximately 3×10⁻⁵ cm and 2×10⁻⁴ cm.

Claims

1. A nanocomposite material comprising:

a) a matrix material; and

b) a plurality of quantum dots dispersed in said matrix material,

said nanocomposite material having a nonlinear index of refraction γ

that is at least 10<sup>−

9</sup> cm²/W when irradiated with light having a wavelength λ

between approximately 3×

10 <sup>−

5</sup> cm and 2×

10<sup>−

4</sup> cm.

2. The nanocomposite material of claim 1, where in said matrix material is selected from the group consisting of polymers and glasses.

3. The nanocomposite material of claim 1, wherein said nanocomposite material comprises more than 10 percent by weight of said plurality of quantum dots.

4. The nanocomposite material of claim 1, wherein said nanocomposite material comprises at least 40 percent by weight of said plurality of quantum dots.

5. The nanocomposite material of claim 1, wherein said plurality of quantum dots has a peak size between approximately 1 nm and 100 nm.

6. The nanocomposite material of claim 1, wherein at least one quantum dot of said plurality of quantum dots exhibits photoluminescence with a quantum efficiency that is greater than 10 percent.

7. The nanocomposite material of claim 1, wherein a quantum dot of said plurality of quantum dots includes:

a core including a semiconductor material Y selected from the group consisting of Si and Ge; and

a shell surrounding said core, said s hell being substantially defect free.

8. The nanocomposite material of claim 7, wherein said shell includes an oxide YO_n with n being between approximately 0 and 2.

9. The nanocomposite material of claim 1, wherein a quantum dot of said plurality of quantum dots includes:

a core including a semiconductor material selected from the group consisting of Si and Ge; and

a ligand layer surrounding said core, said ligand layer including a plurality of surface ligands.

10. The nanocomposite material of claim 9, wherein a surface ligand of said plurality of surface ligands includes a first portion and a second portion, said first portion being coupled to said core, said second portion being chemically compatible with said matrix material to facilitate dispersing said quantum dot in said matrix material.

11. The nanocomposite material of claim 1, wherein a quantum dot of said plurality of quantum dots includes:

a core including a semiconductor material; and

a ligand layer surrounding said core, said ligand layer including a plurality of surface ligands, a surface ligand of said plurality of surface ligands including a portion that is chemically compatible with said matrix material to facilitate dispersing said quantum dot in said matrix material.

12. The nanocomposite material of claim 11, wherein said semiconductor material is selected from the group consisting of Group IV semiconductor materials, Group II-VI semiconductor materials, Group III-V semiconductor materials, Group IV-VI semiconductor materials, mixtures thereof, and alloys thereof.

13. The nanocomposite material of claim 11, wherein said semiconductor material is a first semiconductor material, said quantum dot further includes a shell positioned between said core and said ligand layer and surrounding said core, said shell including a second semiconductor material, said first semiconductor material and said second semiconductor material being independently selected from the group consisting of Group IV semiconductor materials, Group II-VI semiconductor materials, Group III-V semiconductor materials, Group IV-VI semiconductor materials, mixtures thereof, and alloys thereof.

14. The nanocomposite material of claim 11, wherein said plurality of surface ligands are coupled to said core to provide a surface coverage between approximately 50 percent and 100 percent.

15. The nanocomposite material of claim 11, wherein said plurality of surface ligands are coupled to said core to provide a surface coverage between approximately 80 percent and 100 percent.

16. The nanocomposite material of claim 1, further comprising a molecule coupling a first quantum dot and a second quantum dot of said plurality of quantum dots.

17. The nanocomposite material of claim 16, wherein said molecule provides charge transport between said first quantum dot and said second quantum dot.

18. The nanocomposite material of claim 1, further comprising a plurality of molecules coupling at least three quantum dots of said plurality of quantum dots to form one of a linear array, a two-dimensional array, and a three-dimensional array.

19. The nanocomposite material of claim 1, wherein said plurality of quantum dots has a substantially monodisperse size distribution.

20. The nanocomposite material of claim 1, wherein said plurality of quantum dots has a substantially monodisperse shape distribution.

21. The nanocomposite material of claim 1, wherein γ

is at least 10<sup>−

8</sup> cm²/W.

22. The nanocomposite material of claim 1, wherein γ

is at least 10<sup>−

8</sup> cm²/W when λ

is between approximately 1.25×

10<sup>−

4</sup> cm and 1.35×

10<sup>−

4</sup> cm.

23. The nanocomposite material of claim 1, wherein γ

is at least 10<sup>−

8</sup> cm²/W when λ

is between approximately 1.5×

10<sup>−

4</sup> cm and 1.6×

10<sup>−

4</sup> cm.

24. The nanocomposite material of claim 1, wherein each quantum dot of said plurality of quantum dots includes a core, a shell surrounding said core, and a ligand layer surrounding said shell, and γ

is established by selecting at least one of a chemical composition of said core, a chemical composition of said shell, a peak size of said plurality of quantum dots, a thickness of said shell, a chemical composition of said ligand layer, a chemical composition of said matrix material, and a concentration of said plurality of quantum dots in said matrix material.

25. The nanocomposite material of claim 1, wherein said nanocomposite material has a linear index of refraction between approximately 1.3 and 5.0.

26. The nanocomposite material of claim 25, wherein each quantum dot of said plurality of quantum dots includes a core, a shell surrounding said core, and a ligand layer surrounding said shell, and said linear index of refraction is established by selecting at least one of a chemical composition of said core, a chemical composition of said shell, a peak size of said plurality of quantum dots, a thickness of said shell, a chemical composition of said ligand layer, a chemical composition of said matrix material, and a concentration of said plurality of quantum dots in said matrix material.

27. The nanocomposite material of claim 1, wherein said nanocomposite material has a figure-of-merit that is at least 1, said figure-of-merit being defined as 2γ

/β

λ

, where β

is a two-photon absorption coefficient of said nanocomposite material expressed in cm/W.

28. The nanocomposite material of claim 27, wherein said figure-of-merit is at least 1.8.

29. The nanocomposite material of claim 1, wherein each quantum dot of said plurality of quantum dots includes a core and a shell surrounding said core, and said nanocomposite material has single-photon and multi-photon absorption characteristics that are established by selecting at least one of a chemical composition of said core, a chemical composition of said shell, a peak size of said plurality of quantum dots, and a thickness of said shell.

30. The nanocomposite material of claim 1, wherein each quantum dot of said plurality of quantum dots includes a core and a ligand layer surrounding said core, and said nanocomposite material has chemical characteristics that are established by selecting at least one of a chemical composition of said ligand layer and a chemical composition of said matrix material.

31. The nanocomposite material of claim 1, wherein each quantum dot of said plurality of quantum dots includes a core and a ligand layer surrounding said core, and said nanocomposite material has mechanical characteristics that are established by selecting at least one of a chemical composition of said ligand layer and a chemical composition of said matrix material.

32. The nanocomposite material of claim 1, wherein said nanocomposite material has at least two different characteristics that are independently established, said at least two different characteristics being selected from the group consisting of γ

, linear index of refraction, single-photon absorption characteristics, multi-photon absorption characteristics, chemical characteristics, and mechanical characteristics.

33. A nanocomposite material comprising:

a plurality of quantum dots, said plurality of quantum dots being arranged in one of a two-dimensional array and a three-dimensional array, said plurality of quantum dots including a semiconductor material Y selected from the group consisting of Si and Ge, at least one quantum dot of said plurality of quantum dots exhibiting photoluminescence with a quantum efficiency that is greater than 10 percent.

34. The nanocomposite material of claim 33, wherein said plurality of quantum dots has a peak size between approximately 1 nm and 50 nm.

35. The nanocomposite material of claim 33, wherein a packing density of said plurality of quantum dots in said nanocomposite material is between approximately 0.005 percent and 75 percent by volume of said nanocomposite material.

36. The nanocomposite material of claim 33, wherein a packing density of said plurality of quantum dots in said nanocomposite material is between approximately 50 percent and 75 percent by volume of said nanocomposite material.

37. The nanocomposite material of claim 33, wherein said plurality of quantum dots is substantially arranged in a cubic close-packed array.

38. The nanocomposite material of claim 33, wherein a quantum dot of said plurality of quantum dots includes:

a core including Y; and

a shell surrounding said core, said shell including an oxide YO_n with n being between approximately 0 and 2.

39. The nanocomposite material of claim 33, wherein a quantum dot of said plurality of quantum dots includes:

a core including Y; and

a ligand layer surrounding said core, said ligand layer including a plurality of surface ligands.

40. The nanocomposite material of claim 33, wherein at least one quantum dot of said plurality of quantum dots exhibits photoluminescence with a quantum efficiency that is at least 50 percent.

41. The nanocomposite material of claim 33, wherein said nanocomposite material has a nonlinear index of refraction γ

that is at least 10<sup>−

9</sup> cm²/W when irradiated with light having a wavelength λ

between approximately 3×

10<sup>−

5</sup> cm and 2×

10 <sup>−

4</sup> cm.

42. The nanocomposite material of claim 41, wherein said nanocomposite material has a figure-of-merit that is at least 1, said figure-of-merit being defined as 2γ

/β

λ

, where β

is a two-photon absorption coefficient of said nanocomposite material expressed in cm/W.