Method for production of paper

• US 6,712,934 B2
• Filed: 05/31/2002
• Issued: 03/30/2004
• Est. Priority Date: 12/02/1999
• Status: Expired due to Term

• Current Assignee: Kemira Oyj
• Original Assignee: Kemira Chemicals Oy (Kemira Oyj)
• Inventors: Ahlgren, Jonni, Strengell, Kimmo
• Primary Examiner(s): Chin, Peter
• Assistant Examiner(s): Hug, Eric
• Application Number:
  US10/148,691
• Publication Number:
  US 20030079848A1
• Time in Patent Office: 669 Days
• Field of Search: 162/128, 162/168.1, 162/168.2, 162/168.3, 162/181.1, 162/181.6, 162/181.7, 162/181.8, 162/183-186, 162/164--16, 106/468-470, 106/482-486, 106/DIG.4, 423/331-335, 423/326, 210/716, 210/717, 210/723, 210/731, 210/732, 210/667
• US Class Current: 162/181.6
• CPC Class Codes: D21H 17/375 Poly(meth)acrylamide
• CPC Class Codes: D21H 17/44 cationic
• CPC Class Codes: D21H 17/68 siliceous, e.g. clays
• CPC Class Codes: D21H 21/10 Retention agents or drainage improvers
• CPC Class Codes: D21H 23/14 by selecting point of addition or time of contact between components

Abstract

The invention relates to a method for the production of paper or board, wherein retention aids are added to the stream of stock. Improved retention and more effective dewatering are achieved by adding to the stream of stock a cationic polymer solution and a suspension-form microparticle mixture composed of a swellable clay of the smectite group and a colloidal synthetic metal silicate in which the prevalent cation is magnesium.

Claims

1. A method for the production of paper or board comprising:

(a) adding retention aids to a stream of stock entering a paper machine headbox,

(b) directing the stream of stock to a wire,

(c) dewatering the stock a paper web to form a paper web, and

(d) drying the paper web,

wherein the retention aids are (i) a solution of a water-soluble cationic polymer, and (ii) a suspension of a microparticle mixture containing a swellable smectite clay and a colloidal synthetic metal silicate, the prevailing cation of the colloidal synthetic metal silicate being magnesium, and wherein the microparticle mixture contains the swellable smectite clay in an amount of 85-99% by weight, and the colloidal synthetic metal silicate in an amount of 1-15% by weight.

2. The method according to claim 1, wherein said swellable smectite clay is bentonite.

3. The method according to claim 1, said swellable smectite clay is hectorite.

4. The method according to claims 1 to 3, wherein said retention aids are added in steps by (i) adding a solution of the cationic polymer, (ii) shearing the solution to break up flocs, and (iii) adding the suspension of microparticle mixture.

5. The method according to claim 1, wherein said cationic polymer is selected from the group consisting of a copolymer of aczylamide and a cationic monomer, and a copolymer of mechacrylamide and a cationic monomer.

6. The method according to claim 1, wherein the molecular weight of the cationic polymer is at minimum 500,000.

7. The method according to claim 1, said cationic polymer is used in an amount of at minimum 0.02% of the dry solids weight of the stock.

8. The method according to claim 1, wherein said microparticle mixture is used in an amount of at minimum 0.05% of the dry solids weight of the stock.

9. The method according to claim 1, the suspension of microparticle mixture is prepared from a swellable smectite clay and a solid colloidal synthetic magnesium silicate.

10. The method according to claim 1, wherein the stock contains cellulose, mechanical pulp, recycled fiber, or various combinations of these, as well as fillers and additives commonly used in the production of paper.

11. The method according to claim 10, wherein the filler is ground or precipitated calcium carbonate, kaolin, calcined kaolin, talc, titanium dioxide, gypsum, or a synthetic inorganic filler.