Peelable foam coating composition
First Claim
1. A peelable foam coating composition, comprising a blend of:
- an aqueous polyurethane dispersion resin in an effective amount having at least 40 percent by weight solids contents;
an effective amount of a release agent in an amount of from between 0.1 and 5 percent of the total weight percent of the composition, said release agent being selected from the group consisting of propylene glycol, soy lecithin, organosilicone fluids, nonylphenoxypoly-(ethyleneoxy) ethanol, oleic acid polyethylene glycol monostearate, petrolatum, sodium alkyl benzene, sulfonates, siloxanes, polyglycols, silicone surfactants, polyvinyl alcohol resins, paraffin and polymeric waxes, and synthetic waxes including low molecular weight polyethylene waxes, and combinations thereof;
an effective amount of a propellant up to 25 percent by weight;
a surfactant or profoamer in an effective amount of up to 5 percent by weight selected from the group consisting of alkanolamides, silicone glycols, alkyl benzene sulfonates, alcohol ethoxylated, phosphate esters, oleates, betaines, alkylphenol ether sulfates, alkylaryl sulfonates, fatty acids, soy lecithin, anionic, cationic, amphoteric, or nonionic surfactants, and combinations thereof;
wherein upon curing said peelable foam coating composition forms a smooth sealed exterior skin enclosing a porous interior providing structural integrity thereto.
9 Assignments
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Accused Products
Abstract
This invention relates generally to water resistant peelable protective and decorative clear or pigmented foam coating compositions and, more specifically, to aqueous and solvent based, polymeric coating compositions which form a protective and/or decorative coating and is removably adheres to a variety of substrates, including automotive paints, metals, glass, vinyl, plastics, concrete, natural and synthetic elastomers, and ceramics. The coatings present a three-dimensional expandable foamy coating, and can be readily peeled off from the substrate as a whole piece. The coatings may be formulated for temporary or long-term protection depending upon the application. The peelable coatings can be applied as a paint, paste, film, or expandable foam cord whereby the expansion of the foam can be controlled by the formulation and applicator.
71 Citations
49 Claims
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1. A peelable foam coating composition, comprising a blend of:
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an aqueous polyurethane dispersion resin in an effective amount having at least 40 percent by weight solids contents;
an effective amount of a release agent in an amount of from between 0.1 and 5 percent of the total weight percent of the composition, said release agent being selected from the group consisting of propylene glycol, soy lecithin, organosilicone fluids, nonylphenoxypoly-(ethyleneoxy) ethanol, oleic acid polyethylene glycol monostearate, petrolatum, sodium alkyl benzene, sulfonates, siloxanes, polyglycols, silicone surfactants, polyvinyl alcohol resins, paraffin and polymeric waxes, and synthetic waxes including low molecular weight polyethylene waxes, and combinations thereof;
an effective amount of a propellant up to 25 percent by weight;
a surfactant or profoamer in an effective amount of up to 5 percent by weight selected from the group consisting of alkanolamides, silicone glycols, alkyl benzene sulfonates, alcohol ethoxylated, phosphate esters, oleates, betaines, alkylphenol ether sulfates, alkylaryl sulfonates, fatty acids, soy lecithin, anionic, cationic, amphoteric, or nonionic surfactants, and combinations thereof;
wherein upon curing said peelable foam coating composition forms a smooth sealed exterior skin enclosing a porous interior providing structural integrity thereto. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8)
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9. A foamy peelable coating composition, comprising a blend of:
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an aqueous polyurethane dispersion resin in an effective amount of at least 40 percent by weight solids of the total weight percent of the composition;
an effective amount of a release agent in an amount of from between 0.1 and 5 percent of the total weight percent of the composition, said release agent being selected from the group consisting of soy lecithin, organosilicone fluids, nonylphenoxypoly-(ethyleneoxy)ethanol, oleic acid polyethylene glycol monostearate, petrolatum, sodium alkyl benzene, sulfonates, siloxanes, polyglycols, silicone surfactants, polyvinyl alcohol resins, paraffin and polymeric waxes, and synthetic waxes including low molecular weight polyethylene waxes, and combinations thereof;
at least 0.1 percent by weight of a plasticizer selected from the group consisting essentially of polyvinyl alcohol, a cellulose, a polyglycol, a phthalate, an adipate, a sebacate ester, a glyceryl tri(acetoxystearate), an epoxidized soybean oil, an epoxidized linseed oil, an n-butyl benzene sulfonamide, an aliphatic polyurethane, a polyester glutarate, a triethylene glycol, a caprate/caprylate, a long chain alkyl ether, a dialkyl diester, a glutarate, an epoxy plasticizer, a polyester based on adipic acid, a hydrogenated dimer acid, a distilled dimer acid, a polymerized fatty acid trimer, an ethyl ester of hydrolyzed collagen, an isostearic acid, a sorbian oleate, a cocoyl hydrolyzed keratin, a lanolin oil, a dialkyl adipate, an alkylaryl phosphate, an alkyl diaryl phosphate, a modified triaryl phosphate, a triaryl phosphate, a butyl benzyl phthalate, an octyl benzyl phthalate, an alkyl benzyl phthalate, a dibutoxy ethoxy ethyl adipate, a 2-ethylhexyldiphenyl phosphate, a dibutoxy ethoxy ethyl formyl, a diisopropyl adipate, a diisopropyl sebacate, an isodecyl oleate, a neopentyl glycol dicaprate, a neopenty glycol diotanoate, an isohexyl neopentanoate, an ethoxylated lanolin, a polyoxyethylene cholesterol, a propoxylated (2 moles) lanolin alcohols, a propoxylated lanoline alcohol, an acetylated polyoxyethylene derivative of lanoline, a dimethylpolysiloxane, a glycerine, a polyethylene glycol, a dibutyl phthalate, a 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, and a diisononyl phthalate;
a propellant in an amount of up to 20.0 percent of the total weight percent of the composition;
wherein upon curing said peelable foam coating composition forms a smooth sealed exterior skin enclosing a porous interior providing structural integrity thereto. - View Dependent Claims (10, 11, 12, 13, 14)
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15. A blended peelable foam coating composition comprising:
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an aqueous polyurethane dispersion resin in an effective amount of at least 40 percent by weight solids of the total weight percent off the composition;
a pigment in an amount of up to 10 percent by weight;
a release agent in an amount of from between 0.1 and 5 percent of the total weight percent of the composition, said release agent being selected from the group consisting of soy lecithin, organosilicone fluids, nonylphenoxypoly-(ethyleneoxy)ethanol, oleic acid polyethylene glycol monostearate, petrolatum, sodium alkyl benzene, sulfonates, siloxanes, polyglycols, silicone surfactants, polyvinyl alcohol resins, paraffin and polymeric waxes, and synthetic waxes including low molecular weight polyethylene waxes, and combinations thereof;
a propellant in an effective amount of up to 25 percent selected from the group consisting of air, a carbon dioxide, nitrogen, and a hydrocarbon propellant;
a plasticizer in an amount of up to 20 percent by weight selected from the group consisting essentially of a polyvinyl alcohol, a cellulose, a polyglycol, a phthalate, an adipate, a sebacate ester, a glyceryl tri(acetoxystearate), an epoxidized soybean oil, an epoxidized linseed oil, an n-butyl benzene sulfonamide, an aliphatic polyurethane, a polyester glutarate, a triethylene glycol, a caprate/caprylate, a long chain alkyl ether, a dialkyl diester, a glutarate, an epoxy plasticizer, a polyester based on adipic acid, a hydrogenated dimer acid, a distilled dimer acid, a polymerized fatty acid trimer, an ethyl ester of hydrolyzed collagen, an isostearic acid, a sorbian oleate, a cocoyl hydrolyzed keratin, a lanolin oil, a dialkyl adipate, an alkylaryl phosphate, an alkyl diaryl phosphate, a modified triaryl phosphate, a triaryl phosphate, a butyl benzyl phthalate, an octyl benzyl phthalate, an alkyl benzyl phthalate, a dibutoxy ethoxy ethyl adipate, a 2-ethylhexyldiphenyl phosphate, a dibutoxy ethoxy ethyl formyl, a diisopropyl adipate, a diisopropyl sebacate, an isodecyl oleate, a neopentyl glycol dicaprate, a neopenty glycol diotanoate, an isohexyl neopentanoate, an ethoxylated lanolin, a polyoxyethylene cholesterol, a propoxylated (2 moles) lanolin alcohols, a propoxylated lanoline alcohol, an acetylated polyoxyethylene derivative of lanoline, a dimethylpolysiloxane, a glycerine, a polyethylene glycol, a dibutyl phthalate, a 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, and a diisononyl phthalate;
wherein upon curing said peelable foam coating composition forms a smooth sealed exterior skin enclosing a porous interior providing structural integrity thereto. - View Dependent Claims (16, 17, 18, 19, 20, 21, 22, 23, 24, 45, 46, 48)
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25. A foamy peelable coating composition blend, comprising:
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an aqueous polyurethane dispersion resin in an effective amount of from 40 to 98 percent by weight solids of the total weight percent of the composition; and
a release agent in an amount of from between 0.1 and 5 percent of the total weight percent of the composition, said release agent being selected from the group consisting of soy lecithin, organosilicone fluids, nonylphenoxypoly-(ethyleneoxy) ethanol, oleic acid polyethylene glycol monostearate, petrolatum, sodium alkyl benzene, sulfonates, siloxanes, polyglycols, silicone surfactants, polyvinyl alcohol resins, paraffin and polymeric waxes, and synthetic waxes including low molecular weight polyethylene waxes, and combinations thereof;
a propellant in an amount of up to 25.0 percent of the total weight percent of the composition;
wherein upon curing said peelable foam coating composition forms a smooth sealed exterior skin enclosing a porous interior providing structural integrity thereto. - View Dependent Claims (26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 47, 49)
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Specification