Microwave-assisted chemical synthesis instrument with fixed tuning

• US 6,713,739 B2
• Filed: 12/13/2002
• Issued: 03/30/2004
• Est. Priority Date: 01/31/2001
• Status: Expired due to Term

• Current Assignee: CEM Global LLC
• Original Assignee: CEM Global LLC
• Inventors: Jennings, William Edward
• Primary Examiner(s): Leung, Philip H.
• Application Number:
  US10/248,052
• Publication Number:
  US 20030089706A1
• Time in Patent Office: 473 Days
• Field of Search: 219/679, 219/686, 219/704, 219/705, 219/707, 219/710, 219/711, 219/691, 219/692, 219/693, 219/745, 219/746, 219/748, 219/756, 219/699, 219/738, 219/741, 204/157.43, 422/21, 422/81.12, 422/81.13
• US Class Current: 219/679
• CPC Class Codes: B01J 19/126 Microwaves
• CPC Class Codes: B01J 2219/00058 Temperature measurement
• CPC Class Codes: B01J 2219/00063 of the reactants
• CPC Class Codes: B01J 2219/00065 Pressure measurement
• CPC Class Codes: B01J 2219/00094 Jackets
• CPC Class Codes: B01J 2219/002 inside the reactor
• CPC Class Codes: B01J 2219/0024 other than of the reactor or heat exchange system
• CPC Class Codes: B01J 2219/1209 Features relating to the reactor or vessel
• CPC Class Codes: B01J 2219/1233 Closure means, such as lids, caps, seals B01J3/03 takes precedence; pressure relief systems in the lid, e.g. rupture discs B01J2219/0027
• CPC Class Codes: B01J 2219/1269 Microwave guides
• CPC Class Codes: B01J 2219/1275 Controlling the microwave irradiation variables
• CPC Class Codes: H01P 7/06 Cavity resonators
• CPC Class Codes: H05B 6/806 for laboratory use

Abstract

An instrument is disclosed for microwave-assisted chemical processes that avoids tuning discrepancies that otherwise result based upon the materials being heated. The instrument includes a source of microwave radiation, a waveguide in communication with the source, with at least a portion of the waveguide forming a cylindrical arc, a cylindrical cavity immediately surrounded by the cylindrical arc portions of the waveguide, and at least three slotted openings in the circumference of the circular waveguide that provide microwave communication between the waveguide and the cavity.

Claims

1. An instrument for microwave-assisted chemical processes that avoids tuning discrepancies that otherwise result based upon the size and composition of the materials being heated, said instrument comprising:

a source of microwave radiation;

a waveguide in communication with said source, with at least a portion of said waveguide forming an annulus with a rectangular cross section;

a right cylindrical static cavity including a circular floor and a circular attenuator and immediately surrounded by said annular portions of said waveguide; and

at least 3 slotted openings in the circumference of said annular waveguide that provide microwave communication between said waveguide and said static cavity and optimized coupling between microwaves from said source and materials being heated.

2. An instrument according to claim 1 wherein said microwave source is selected from the group consisting of magnetrons and klystrons.

3. An instrument according to claim 1 wherein said microwave source is a solid state source.

4. An instrument according to claim 1 wherein said waveguide includes seven slots equally spaced from one another by at least 40°

.

5. An instrument according to claim 1 wherein said cylindrical cavity completes a fall 360°

.

6. An instrument according to claim 1 wherein said annular waveguide completes more than 180°

.

7. An instrument according to claim 1 wherein said annular waveguide completes between 270 and 360°

.

8. An instrument according to claim 1 wherein said slotted openings are oriented parallel to the axis of said cylindrical cavity.

9. An instrument according to claim 1 wherein said waveguide is formed of metal.

10. An instrument according to claim 1 and further comprising means for measuring the temperature of items in said cavity.

11. An instrument according to claim 10 wherein said temperature measurement means comprises an infrared photo detector positioned to receive infrared radiation from items in said cavity.

12. An instrument according to claim 10 and further comprising means for moderating the application of microwaves in response to the measured temperature.

13. An instrument according to claim 12 wherein said moderating means comprises a processor in communication with said source and said temperature measurement means for moderating the output of said source in response to the measured temperature.

14. An instrument according to claim 1 and further comprising means for measuring the pressure in said cavity.

15. An instrument according to claim 14 comprising a pressure transducer.

16. An instrument according to claim 4, and further comprising means for moderating the application of microwaves in response to the measured pressure.

17. An instrument according to claim 16 wherein said moderating means comprises a processor in communication with said source and said pressure measurement means for moderating the output of said source in response to the measured pressure.

18. An instrument according to claim 1 and further comprising means for cooling said cavity in response to elevated temperatures resulting from chemical reactions being carried out in said cavity.

19. An instrument according to claim 1 and further comprising a cylindrical dielectric insert inside said cavity and adjacent the circumference of said cavity.