Direct dye inks and a method of making direct dye inks

• US 6,715,868 B2
• Filed: 01/25/2002
• Issued: 04/06/2004
• Est. Priority Date: 02/16/2001
• Status: Active Grant

• Current Assignee: Hewlett-Packard Development Company, L.P. (HP Inc.)
• Original Assignee: MacDermid ColorSpan, Inc. (HP Inc.)
• Inventors: Thai, Uyen Q., Schmidt, Peter D.
• Primary Examiner(s): Meier, Stephen D.
• Assistant Examiner(s): Do, An H.
• Application Number:
  US10/057,569
• Publication Number:
  US 20020155224A1
• Time in Patent Office: 802 Days
• Field of Search: 347/95, 347/100, 347/102, 347/101, 106/31.58, 106/31.49, 106/31.27, 106/31.13, 427/337
• US Class Current: 347/100
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing
• CPC Class Codes: D06P 1/60 using compositions containing polyethers
• CPC Class Codes: D06P 1/613 Polyethers without nitrogen
• CPC Class Codes: D06P 1/65118 Compounds containing hydroxyl groups
• CPC Class Codes: D06P 5/30 Ink jet printing

Abstract

A dye-based, thermal ink jet printer ink is formulated by combining a water miscible organic solvent, water, and a dye, and blending the water miscible organic solvent, the water, and the dye together. The ink has the ability to form printed images on a variety of textile media and can be used to achieve acceptable results on both coated silk and coated cotton substrates. Also included is a method of making the ink jet ink and a method of applying the ink to a recording medium.

Claims

1. A method of applying a series of dye-based ink jet inks in different colors to a recording medium, comprising the steps of:

a) formulating each of the dye-based ink jet inks by combining water, water-miscible organic solvent, and dye

b) printing said dye-based ink jet ink as a series of ink dots on said recording medium as a first layer of said ink dots;

c) fixing the printed dye-based ink dots to said recording medium; and

d) rinsing said printed recording medium to remove any excess dye;

wherein said recording medium is selected from the group consisting of coated cloth, coated textiles, and coated fabric and said coating enhances one or more functional attributes of the recording medium.

2. The method of claim 1, wherein said printing of said dye-based ink jet ink is accomplished using an ink jet printer or an on-head camera system.

3. The method of claim 2, wherein said ink jet printer is selected from the group consisting of a thermal ink jet printer, a piezo ink jet printer, and a plunger ink jet printer.

4. The method of claim 1, wherein said coating supports absorption of the dye-based ink jet ink into the recording medium or supports adhesion of the dye-based ink jet ink to the recording medium.

5. The method of claim 1, wherein said recording medium includes a temporary or permanent backing material on a side of the recording medium that is not being printed with said dye-based ink jet ink.

6. The method of claim 5, wherein said temporary backing material is removed following printing of said dye-based ink jet ink on said recording medium.

7. The method of claim 1, wherein said recording medium comprises woven or knitted yarn, thread or fibers derived from animals, derived from plants, and combinations thereof.

8. The method of claim 1, wherein said ink dots are circular dots that are substantially free of ragged edges.

9. The method of claim 1, wherein said different colors comprise primary color inks.

10. The method of claim 9, wherein said primary color inks are selected from the group consisting of cyan, magenta, yellow and black.

11. The method of claim 9, wherein said ink set includes inks that are prepared by mixing different proportions of said primary color inks.

12. The method of claim 1, wherein said series of inks in different colors are formulated by changing a concentration of the dye in said dye-based ink jet ink.

13. The method of claim 12, wherein as a concentration of the dye in said dye-based ink jet ink is changed, a concentration of water is changed by the same weight percent in an opposite direction to that of the dye concentration change while a concentration of the water miscible solvent remains the same or approximately the same.

14. The method of claim 12, wherein said ink sets includes a combination of different colored inks and inks with different concentrations of the same dye.

15. The method of claim 14, wherein surface tension and viscosity are balanced in each of the different inks of the ink set to give the printed dots of each of the different inks of the ink set about the same diameter.

16. The method of claim 15, wherein the diameter of the ink dots is from about 4 mils to about 5 mils.

17. The method of claim 1, wherein said printed dye based ink jet inks dots are printed onto the recording medium in a predetermined fashion.

18. The method of claim 17, wherein the dots have about the same diameter for each ink of the ink set.

19. The method of claim 17, wherein one or more secondary layers of ink dots are printed onto the first layer of ink dots.

20. The method of claim 19, wherein said one or more secondary layers of ink dots are the same color as the first layer of ink dots, a different color from the first layer of ink dots, or any combination thereof.

21. The method of claim 1, wherein the dye-based ink dots, except for black dye-based ink dots, are overlapped with each other in any order and said order does not change the visually observed color.

22. The method of claim 1, wherein the water-miscible organic solvent is selected from the group consisting of ethers, oxyethylene or oxypropylene addition dimers, trimers or polymers, alkylene glycols having an alkylene group of 2 to 6 carbons, thiodiglycol, glycerin, lower alkyl ethers of a polyhydric alcohol, lower dialkyl ethers of a polyhydric alcohol, sulfolane, 1,3-dimethyl-2-imidazolidinone, and combinations thereof.

23. The method of claim 1, wherein the water-miscible organic solvent includes a high-boiling, water miscible organic solvent selected from the group consisting of oxyethylene or oxypropylene addition dimers, trimers, or polymers, lower alkyl ethers of a polyhydric alcohol, or any combination thereof.

24. The method of claim 1, wherein the concentration of the water-miscible organic solvent in the ink ranges from about 2% to about 30%, by weight, based on the total weight of the ink.

25. The method of claim 24, wherein the concentration of the water-miscible organic solvent in the ink ranges from about 5% to about 20%, by weight, based on the total weight of the ink.

26. The method of claim 25, wherein the concentration of the water-miscible organic solvent in the ink ranges from about 10% to about 15%, by weight, based on the total weight of the ink.

27. The method of claim 1, wherein the concentration of the water in the ink ranges from about 5% to about 95%, by weight, based on the total weight of the ink.

28. The method of claim 27, wherein the concentration of the water in the ink ranges from about 35% to about 90%, by weight, based on the total weight of the ink.

29. The method of claim 28, wherein the concentration of the water in the ink ranges from about 70% to about 90%, by weight, based on the total weight of the ink.

30. The method of claim 1, wherein the concentration of the dye in the ink ranges from about 0.1% to about 55%, by weight, based on the total weight of the ink.

31. The method of claim 1 wherein said printed dye-based ink dots are fixed to the recording medium by applying steam or steam and air.

32. The method of claim 1, wherein each of the formulated dye-based ink jet inks is subsequently vacuumed and filtered.