Particulate compositions and their manufacture

• US 6,716,526 B2
• Filed: 07/17/2002
• Issued: 04/06/2004
• Est. Priority Date: 01/27/2000
• Status: Expired due to Term

• Current Assignee: CIBA Specialty Chemicals Water Treatments Limited (BASF SE)
• Original Assignee: CIBA Specialty Chemicals Water Treatments Limited (BASF SE)
• Inventors: Dungworth, Howard Roger, Weston, Rachel Clare
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): TRAN, THAO T
• Application Number:
  US10/181,335
• Publication Number:
  US 20030018102A1
• Time in Patent Office: 629 Days
• Field of Search: 427/2.14, 427/162, 427/164, 427/212, 427/213.3, 428/402.2, 428/34.2
• US Class Current: 428/402.2
• CPC Class Codes: B01J 13/14 Polymerisation; cross-linking
• CPC Class Codes: C08F 2/22 Emulsion polymerisation
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: D01F 1/10 Other agents for modifying properties
• CPC Class Codes: D06M 23/12 Processes in which the treating agent is incorporated in microcapsules making microcapsules B01J13/02
• CPC Class Codes: D21H 21/54 being spherical, e.g. microcapsules, beads
• CPC Class Codes: Y10T 428/2984 Microcapsule with fluid core [includes liposome]

Abstract

A composition comprising particles which comprise a core material within a polymeric shell, wherein the core material comprises a hydrophobic substance, characterized in that the polymeric shell comprises a copolymer formed from a monomer blend which comprises, A) 30 to 90% by weight methacrylic acid B) 10 to 70% by weight alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 60° C. and C) 0 to 40% by weight other ethylenically unsaturated monomer. The core material can comprise an active ingredient selected from the group consisting of UV absorbers, UV reflectors, pigments, dyes, colorants, scale inhibitors, corrosion inhibitors, antioxidants, pour point depressants, wax deposition inhibitors, dispersants, flame retardants, biocides, active dye tracer materials and phase change materials. The composition has the advantage that the polymeric shell is highly impermeable to the core material even at elevated temperatures.

Claims

1. A composition comprising particles which comprise a core material within a polymeric shell, wherein the core material comprises a hydrophobic substance, characterized in that the polymeric shell comprises a copolymer formed from a monomer blend which comprises,

A) 30 to 90% by weight methacrylic acid

B) 10 to 70% by weight alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 60°

C. and

C) 0 to 40% by weight other ethylenically unsaturated monomer.

2. A composition according to claim 1 in which component B is an alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 80°

C.

3. A composition according to claim 1 in which component B of the monomer blend is selected from the group consisting of methyl methacrylate, acrylonitrile, tertiary butyl methacrylate, phenyl methacrylate, cyclohexyl methacrylate and isobornyl methacrylate.

4. A composition according to claim 1 in which component C is selected from the group consisting of an ethylenically unsaturated carboxylic acid and salts thereof, amino alkyl esters of ethylenically unsaturated carboxylic acid and salts thereof, C_1-30 esters of ethylenically unsaturated carboxylic acid, styrene, vinyl acetate and cross-linking monomer.

5. A composition according to claim 1 in which the copolymer is formed from a monomer blend which comprises 40 to 90% of component A and 10 to 60% of component B.

6. A composition according to claim 1 in which the copolymer is formed from a monomer blend which comprises 45 to 90% by weight component A and 10 to 55% of component B.

7. A composition according to claim 1 in which the polymeric shell comprises a copolymer consisting essentially of, 45 to 90% by weight component A and 10 to 55% by weight of component B.

8. A composition according to claim 1 in which the core consists essentially of at least 90% by weight of the of the hydrophobic substance.

9. A composition according to claim 1 in which the hydrophobic substance is a non-polymeric material.

10. A composition according to claim 1 in which the hydrophobic substance which is an oil or wax which has a melting point at a temperature between −

30°

C. and 150°

C.

11. A composition according to claim 1 in which the core material comprises an active ingredient selected from the group consisting of UV absorbers, UV reflectors, flame retardants, active dye tracer materials, pigments, dyes, colorants, scale inhibitors, corrosion inhibitors, antioxidants, pour point depressants, wax deposition inhibitors, dispersants, biocides, enzymes, detergent builders, fragrances, phase change materials and silicone oils.

12. A process of manufacturing a composition comprising particles, which comprise core material within a polymeric shell, wherein the core material comprises a hydrophobic substance, comprising the steps,forming a solution of monomer in a hydrophobic liquid, homogenizing the monomer solution into an aqueous phase to form an emulsion, subjecting the emulsion to polymerization conditions, and forming a dispersion of polymeric particles in the aqueous phase characterized in that the polymeric shell comprises a copolymer formed from a monomer blend which comprises,

A) 30 to 90% by weight methacrylic acid

B) 10 to 70% by weight alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 60°

C. and

C) 0 to 40% by weight other ethylenically unsaturated monomer.

13. A process according to claim 12 in which the copolymer is formed from a monomer blend which comprises, 40 to 90% by weight of component A and 10 to 60% by weight of component B.

14. A process according to claim 12 in which component B is an alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 80°

C.

15. A process according to claim 12 in which component B is selected from the group consisting of methyl methacrylate, acrylonitrile, tertiary butyl methacrylate, phenyl methacrylate, cyclohexyl methacrylate and isobornyl methacrylate.

16. A process according to claim 12 in which component C is selected from the group consisting of an ethylenically unsaturated carboxylic acid and salts thereof, amino alkyl esters of ethylenically unsaturated carboxylic acid and salts thereof, C_1-30 esters of ethylenically unsaturated carboxylic acid, styrene vinyl acetate and cross-linking monomer.

17. A process according to claim 12 in which the shell comprises a copolymer consisting essentially of 45 to 90% by weight of component A and 10 to 55% by weight of component B.

18. A process accordipg to claim 12 in which the core consists essentially of at least 90% by weight of the hydrophobic substance.

19. A process according to claim 12 in which the hydrophobic substance is a non-polymeric material.

20. A process according to claim 12 in which the hydrophobic substance which is an oil or wax which has a melting point at a temperature between −

30°

C. and 150°

C.

21. A process according to claim 12 in which the core material comprises an active ingredient selected from the group consisting of UV absorbers, UV reflectors, pigments, dyes, colorants, scale inhibitors, corrosion inhibitors, biocides, enzymes, detergent builders, fragrances, antioxidants, pour point depressants, wax deposition inhibitors, dispersants, flame retardants, active dye tracer materials, phase change materials and silicone oils.

22. An article comprising a particulate composition comprising a polymeric shell, in which the core material comprises a hydrophobic substance, characterized in that the polymeric shell comprises a copolymer formed from a monomer blend which comprises,

A) 30 to 90% by weight methacrylic acid

B) 10 to 70% by weight alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 60°

C. and

C) 0 to 40% by weight other ethylenically unsaturated monomer.

23. An article according to claim 22 which is a textile product or a paper or board packaging material.

24. A fiber which comprises a particulate composition comprising a polymeric shell, in which the core material comprises a hydrophobic substance, characterized in that the polymeric shell comprises a copolymer formed from a monomer blend which comprises,

A) 30 to 90% by weight methacrylic acid

B) 10 to 70% by weight alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 60°

C. and

C) 0 to 40% by weight other ethylenically unsaturated monomer.

25. A process of forming a fiber containing particles comprising a core material within a polymeric shell in which the core material comprises a hydrophobic substance comprising the steps of,combining said particles with a liquid spinning dope, extruding the spinning dope, passing extruded dope through an atmosphere at a temperature of at least 150°

C. and

4) collecting formed fibers,

characterized and wherein the polymeric shell that has been formed from a copolymer derived from a monomer blend which comprises,

A) 30 to 90% by weight methacrylic acid

B) 10 to 70% by weight alkyl ester of (meth)acrylic acid which is capable of forming a homopolymer of glass transition temperature in excess of 60°

C. and 0 to 40% by weight other ethylenically unsaturated monomer.