Method for producing a cellulose fibre from hydrocellulose

• US 6,720,057 B1
• Filed: 05/17/2000
• Issued: 04/13/2004
• Est. Priority Date: 08/07/1997
• Status: Expired due to Fees

• Current Assignee: Fuji Electric Company Limited (Fuji Electric Systems Company Limited)
• Original Assignee: Achim Neumayr, Herbert Hasl
• Inventors: Hasl, Herbert, Neumayr, Achim
• Primary Examiner(s): JUSKA, CHERYL ANN
• Application Number:
  US09/485,277
• Time in Patent Office: 1,427 Days
• Field of Search: 428/92, 428/97, 428/95, 428/397, 428/400, 264/188, 264/195, 264/196, 264/186, 264/187
• US Class Current: 428/92
• CPC Class Codes: A61K 8/0208 Tissues; Wipes; Patches
• CPC Class Codes: A61K 8/027 Fibers; Fibrils
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: C08B 16/00 Regeneration of cellulose
• CPC Class Codes: D01D 5/18 by means of rotating spinnerets
• CPC Class Codes: D01D 5/253 with a non-circular cross section; Spinnerette packs therefor D01D5/38 takes precedence
• CPC Class Codes: D01F 2/06 from viscose
• CPC Class Codes: D01F 2/08 Composition of the spinning solution or the bath
• CPC Class Codes: D03D 27/00 Woven pile fabrics
• CPC Class Codes: Y10T 428/23957 Particular shape or structure of pile
• CPC Class Codes: Y10T 428/23993 Composition of pile or adhesive

Abstract

The invention described here concerns a process to permit the manufacture of a cellulose fibre from hydrate cellulose with an extremely large surface area which may be used for the preparation of a fabric characterized by a high absorptive power, good liquid-retention properties, high grease-solvent properties as well as particle-absorbing properties, which is suitable for making products that are themselves easy to clean, which can be used for cleaning and decontamination as well as to reduce the surface tension of water and which can be disposed of without damage to the environment.

Claims

1. A process to manufacture a cellulose fibre having fibre-parallel lamellae with spacing between 1 nm and 5 μ

m from hydrate cellulose, the method comprising the following steps;

a) selecting shoots no older than 1 year of deciduous trees or conifers;

b) deriving wood pulp from the shoots;

c) treating the wood pulp derived from shoots no older than 1 year of deciduous tees or conifers with an alkali metal hydroxide solution to obtain an alkali cellulose;

d) pressing out superfluous alkali metal hydroxide solution from the alkali cellulose;

e) shredding the alkali cellulose into alkali cellulose crumbs;

f) ripening the alkali cellulose crumbs to a maturity of between 5° and

30°

Hottenroth to form ripened crumbs;

g) treating the ripened crumbs with a wet sulphide process to form sulphadised cellulose;

h) rinsing and diluting of the sulphadised cellulose with water to obtain a spinning solution;

i) ripening of the spinning solution to a maturity of between 5° and

30°

Hottenroth;

j) filtering and downstream deaerating the spinning solution;

k) injecting the spinning solution into a regenerating bath under application of spinnerets;

l) stripping the coagulating fibres off of the spinnerets with simultaneous twisting in order to obtain twisted fibres;

m) dehydrating the twisted fibres;

n) desulphurising the twisted fibres;

o) washing the twisted fibres with water;

p) predehydrating the twisted fibres; and

q) drying the twisted fibres, whereby the fibres have fibre-parallel lamellae with spacing between 1 nm and 5 μ

m.

2. Process in accordance with claim 1, characterised in that the wood pulp derives from shoots no older than 1 year of false acacia trees, teak trees, bongassi trees or bamboo.

3. Process in accordance with claim 1, characterised in that the lignin content of the less-than-one-year-old shoots used does not exceed 7%.

4. Process in accordance with claim 1, characterized in that the alkali metal hydroxide solution used to treat the wood pulp in Step c) is a sodium hydroxide solution which contains between 150 and 350 g/l of sodium hydroxide.

5. Process in accordance with claim 4, characterised in that the sodium hydroxide solution contains approx. 300 g/l of sodium hydroxide.

6. Process in accordance with claim 1, characterized in that treatment of the wood pulp in Step c) is carried out at a temperature ranging between 15°

C. and 25°

C.

7. Process in accordance with claim 1, characterized in that the shredding process of the alkali cellulose in Step e) comprises a course comminution step and a fine comminution step.

8. Process in accordance with claim 1, characterized in that the alkali cellulose crumbs in Step f) are ripened at a temperature ranging between 60°

C. and 75°

C.

9. Process in accordance with claim 8, characterised in that the alkali cellulose crumbs are ripened at a temperature of between 65°

C. and 75°

C.

10. Process in accordance with claim 9, characterised in that the alkali cellulose crumbs are ripened at a temperature of approx. 72°

C.

11. Process in accordance with claim 1, characterized in that the alkali cellulose crumbs in Step f) are ripened to maturity of between 8°

and 12°

Hottenroth.

12. Process in accordance with claim 11, characterised in that the alkali cellulose crumbs are ripened to a maturity of about 10°

Hottenroth.

13. Process in accordance with claim 1, characterized in that the wet sulphide process in Step (g) is carried out in a solution containing between 150 and 250 g/l carbon disulphide and between 250 and 350 g/l sodium hydroxide.

14. Process in accordance with claim 1, characterized in that the wet sulphide process in Step (g) is carried out in solution containing between 180 and 210 g/l carbon disulphide and between 280 and 320 g/l sodium hydroxide.

15. Process in accordance with claim 1, characterized in that subsequent ripening of the cellulose in Step i) is carried out to a maturity of between 8°

and 12°

Hottenroth.

16. Process in accordance with claim 1, characterized in that the spinning solution downstream of the subsequent ripening of the cellulose and upstream of the filtration of the spinning solution is mixed with at least one other spinning solution produced using a process which comprises Steps a) to i) as described in claim 1.

17. Process in accordance with claim 1, characterized in that the temperature of the regenerating bath in Step k) is between 35°

C. and 45°

C.

18. Process in accordance with claim 17, characterised in that the temperature of the regenerating bath is approximately 40°

C.

19. Process in accordance with claim 1, characterized in that the regenerating bath in Step k) contains between 70 and 160 g/l of sulphuric acid.

20. Process in accordance with claim 1, characterized in that the regenerating bath in Step k) contains between 0.3 and 4 g/l of zinc sulphate.

21. Process in accordance with claim 1, characterized in that the spinnerets in Step k) are heated to keep them at a temperature of between 55°

C. and 75°

C.

22. Process in accordance with claim 21, characterized in that the spinnerets are kept at a temperature of between 65°

C. and 70°

C.

23. Process in accordance with claim 21, characterized in that the spinnerets are kept at a temperature of approximately 67°

C.

24. Process in accordance with claim 1, characterized in that the spinnerets in Step k) are oval to long-slit-shaped.

25. Process in accordance with claim 1, characterized in that dehydrating of the fibres in Step m) is carried out with a sulphuric acid solution which contains up to 15 g/l of sulphuric acid.

26. Process in accordance with claim 25, characterised in that the sulphuric acid solution used to dehydrate the fibres contains up to 10 g/l of sulphuric acid.

27. Process in accordance with claim 1, characterized in that desulphurisation of the fibres in Step n) is carried out with a sodium sulphate solution which contains between 2 and 5 g/l of sodium sulphate.

28. Process in accordance with claim 27, characterised in that the sodium sulphate solution used to desulphurise the fibres contains approximately 3 g/l of sodium sulphate.

29. Process in accordance with claim 1, characterised in that the twisted fibres are treated with titanium dioxide after being washed with water and before being dehydrated.

30. Process in accordance with claim 1, characterized in that the prehydrating of the fibres in Step p) is carried out with compressed air.

31. Process in accordance with claim 1, characterized in that the drying of the fibres in Step q) is carried out under application of tunnel dryers.

32. Process in accordance with claim 1, characterized in that the lignin content of the less-than-one-year-old shoots used does not exceed 5%.

33. Process in accordance with claim 1, characterized in that the lignin content of the less-than-one-year-old shoots used does not exceed 2%.

34. Process in accordance with claim 1, characterized in that the regenerating bath in Step k) contains between 90 and 140 g/l of sulphuric acid.

35. Process in accordance with claim 1, characterized in that the regenerating bath in Step k) contains approximately 120 g/l of sulphuric acid.

36. Process in accordance with claim 1, characterized in that the regenerating bath in Step k) contains between 0.5 and 2 g/l of zinc sulphate.

37. Process in accordance with claim 1, characterized in that the regenerating bath in Step k) contains approximately 1 g/l of zinc sulphate.

38. Cellulose fibre, produced by a process in accordance with claim 1.

39. Cellulose fibre in accordance with claim 38, characterised by a microstructure which displays fibre-parallel lamellae.

40. Cellulose fibre in accordance with claim 39, characterised in that the spacing between the fibre-parallel lamellae ranges between 1 nm and 5 μ

m.

41. Cellulose fibre in accordance with claim 40, characterised in that the spacing between the fibre-parallel lamellae ranges between 200 nm and 1 μ

m.

42. Fabric comprising:

a) a backing fabric; and

b) a pile comprising fibers in accordance with claim 38;

wherein the pile is woven into the backing fabric.

43. Fabric in accordance with claim 42, characterized in that the backing fabric has a lattice structure.

44. Fabric in accordance with claim 42, characterised in that the pile forms a fibre bed of approx. 0.5 cm in height above the backing fabric.

45. Fabric in accordance with claim 42, characterised in that the backing fabric contains viscose staple fibres.

46. Fabric in accordance with claim 45, characterised in that the backing fabric consists exclusively of viscose staple fibres.

47. Fabric in accordance with claim 42, characterised in that the pile contains oval and tape fibres.

48. A cleaning and decontamination fabric made in accordance with claim 42.

49. A water surface tension reducer comprising a fabric in accordance with claim 42.

50. A textile comprising a fabric in accordance with claim 42.

51. A clothing textile comprising a fabric in accordance with claim 42.

52. A personal hygiene article comprising a fabric in accordance with claim 42.

53. A particle filter comprising a fabric in accordance with claim 42.

54. A condensation catalyst comprising a fabric in accordance with claim 42.

55. A floor covering comprising a fabric in accordance with claim 42.

56. A covering material comprising a fabric in accordance with claim 42.

57. Fabric comprising a backing fabric and a pile woven into the backing fabric, wherein the pile is comprised of cellulose fibers formed by:

a) treating wood pulp derived from shoots no older than 1 year of deciduous trees or conifers with an alkali metal hydroxide solution in order to obtain an alkali cellulose;

b) pressing out the superfluous alkali metal hydroxide solution from the obtained alkali cellulose;

c) shredding the alkali cellulose into crumbs;

d) ripening the alkali cellulose crumbs to a maturity of between 5° and

30°

Hottenroth;

e) employing a wet sulfide process to treat the ripened crumbs in order to sulfadize the cellulose;

f) rinsing and diluting the sulfadized cellulose with water in order to obtain a spinning solution;

g) subsequenty ripening the rinsed and diluted cellulose to a maturity of between 5° and

30°

Hottenroth;

h) filtering and deaerating the spinning solution;

i) injecting the spinning solution into a regenerating bath under application of spinnerets;

j) stripping off the coagulating fibers with simultaneous twisting in order to obtain twisted fibers;

k) dehydrating the twisted fibers;

l) desulfurizing the twisted fibers;

m) washing the twisted fibers with water;

n) predehydrating the twisted fibers; and

o) drying the twisted fibers;

the fabric characterised in that the pile consists of 50% oval fibers and 50% tape fibers.

58. Fabric comprising a backing fabric and a pile woven into the backing fabric, wherein the pile is comprised of cellulose fibers formed by:

a) treating wood pulp derived from shoots no older than 1 year of deciduous trees or conifers with an alkali metal hydroxide solution in order to obtain an alkali cellulose;

b) pressing out the superfluous alkali metal hydroxide solution from the obtained alkali cellulose;

c) shredding the alkali cellulose into crumbs;

d) ripening the alkali cellulose crumbs to a maturity of between 5° and

30°

Hottenroth;

e) employing a wet sulfide process to treat the ripened crumbs in order to sulfadize the cellulose;

f) rinsing and diluting the sulfadized cellulose with water in order to obtain a spinning solution;

g) subsequently ripening the rinsed and diluted cellulose to a maturity of between 5° and

30°

Hottenroth;

h) filtering and deaerating the spinning solution;

i) injecting the spinning solution into a regenerating bath under application of spinnerets;

j) stripping off the coagulating fibers with simultaneous twisting in order to obtain twisted fibers;

k) dehydrating the twisted fibers;

l) desulfurizing the twisted fibers;

m) washing the twisted fibers with water;

n) predehydrating the twisted fibers; and

o) drying the twisted fibers;

the fabric characterized in that the pile consists of 50% of oval fibers with a count of 330 dtex F60 and 50% of tape fibers with a count of 300 dtex F80.