Flexible organic electronic device with improved resistance to oxygen and moisture degradation

• US 6,720,203 B2
• Filed: 02/26/2003
• Issued: 04/13/2004
• Est. Priority Date: 04/28/1999
• Status: Expired due to Term

• Current Assignee: LG Chem Limited (LG Corporation)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: McLean, Robert Scott, Carcia, Peter Francis
• Primary Examiner(s): CRANE, SARA W
• Application Number:
  US10/374,611
• Publication Number:
  US 20030164497A1
• Time in Patent Office: 412 Days
• Field of Search: 257/40, 438/99, 438/25, 438/26, 438/116, 438/118, 438/126, 438/127, 313/504, 313/511
• US Class Current: 438/99
• CPC Class Codes: H10K 10/00 Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers integrated devices or assemblies of multiple devices H10K19/00
• CPC Class Codes: H10K 2102/311 Flexible OLED
• CPC Class Codes: H10K 30/00 Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation integrated devices or assemblies of multiple devices H10K39/00, H10K65/00; electrolytic light-sensitive devices H01G9/20
• CPC Class Codes: H10K 30/88 Passivation; Containers; Encapsulations
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 71/00 Manufacture or treatment specially adapted for the organic devices covered by this subclass
• CPC Class Codes: H10K 77/111 Flexible substrates
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y10S 428/917 Electroluminescent
• CPC Class Codes: Y10T 428/259 Silicic material

Abstract

Flexible composite barrier structures are used to improve the resistance, to oxygen and moisture degradation, of an organic electronic device including at least one active layer comprising an organic material.

Claims

1. A method for improving resistance to oxygen and moisture degradation of a flexible organic electronic device comprising at least one first electrical contact layer having a first electrical contact layer outer surface and an opposite first electrical contact layer inner surface, at least one active layer adjacent to the first electrical contact layer inner surface, the active layer comprising an organic active material, said active layer having a set of dimensions, and at least one second electrical contact layer having a second electrical contact layer outer surface and an opposite second electrical contact layer inner surface, wherein the second electrical contact layer inner surface is adjacent to the active layer, the method comprising the steps of:

placing a first flexible composite barrier structure adjacent to the at least one first electrical contact layer outer surface, the first flexible composite barrier structure comprising at least one layer of a first polymeric film and at least one layer of a first barrier material, the first barrier structure having a first inner surface;

placing a second flexible composite barrier structure adjacent to the at least one second electrical contact layer outer surface, the second flexible composite barrier structure comprising at least one layer of a second polymeric film and at least one layer of second barrier material, the second barrier structure having a second inner surface;

wherein at least one of the first and second composite barrier structures is light-transmitting,

sealing the first inner surface and the second inner surface together outside the dimensions of the active layer to envelop the active layer.

2. The method of claim 1 wherein a portion of the first electrical contact layer and a portion of the second electrical contact layer extend beyond the dimensions of the active layer, wherein the first and second composite barrier structures are also sealed to the extended portions of the first and second electrical contact layers.

3. The method of claim 1 wherein the second electrical contact layer comprises a material having a lower work function than the first electrical contact layer.

4. The method of claim 1 wherein the first electrical contact layer is a cathode and the second electrical contact layer is an anode.

5. The method of claim 1 wherein the first and second polymeric films of the first and second composite barrier structures are selected from polyolefins, polyesters, polyimides, polyamides, polyacrylonitrile and polymethacrylonitrile;

perfluorinated and partially fluorinated polymers, polycarbonates, polyvinyl chloride, polurethanes, polyacrylic resins, epoxy resins, and novolac resins.

6. The method of claim 1 wherein the first and second barrier materials are selected from metals, metal alloys, inorganic oxides, inorganic nitrides, inorganic carbides, inorganic fluorides, and combinations thereof.

7. The method of claim 1 wherein the first flexible composite barrier structure and the first electrical contact layer are light-transmitting.

8. The method of claim 1 wherein the first and second polymeric films in the first composite barrier material is selected from polyethylene terephthalate, polyethylene naphthalate, polyimide, and combinations thereof.

9. The method of claim 1 wherein the barrier material is selected from aluminum, nickel, chromium, copper, tin, stainless steel, and alloys thereof.

10. The method of claim 1 wherein the barrier material selected from inorganic oxides, inorganic nitrides, inorganic fluorides, inorganic carbides, and combinations thereof.

11. The method of claim 1 wherein the layer of first and second barrier materials has a thickness in the range of 2-500 nm.

12. The method of claim 1 wherein the first flexible composite barrier structure comprises two layers of polymeric film with a layer of the first barrier material therebetween.

13. The method of claim 1 wherein the second flexible composite barrier structure comprises two layer of polymeric film with a layer of the first barrier material therebetween.

14. The method of claim 1 wherein the first flexible composite barrier structure further comprises a layer of adhesive on the first inner surface.

15. The method of claim 1 wherein the second flexible composite barrier structure further comprises a layer of adhesive on the second inner surface.

16. The method of claim 1 wherein at least one of the first inner surface and the second inner surface contains an adhesive component.

17. The method of claim 14 or 15 wherein the adhesive is selected from polymer adhesive resins, amorphous polyesters, copolyesters, polyester blends, nylon, polyurethanes, polyolefins, vinyl alcohol, ethylene vinylacetate copolymer, copolymers of ionomers and acids, and combinations thereof.

18. The method of claim 16 wherein the adhesive component is selected from polymer adhesive resins, amorphous polyesters, copolyesters, polyester blends, nylon, polyurethanes, polyolefins, vinyl alcohol, ethylene vinylacetate copolymer, copolymers of ionomers and acids, and combinations thereof.

19. The method of claim 1, wherein the active layer includes electroluminescent material.

20. The method of claim 1, wherein the active layer includes a conjugated polymer.