Filler-containing polymer dispersion, method for its production and its use

• US 6,727,305 B1
• Filed: 06/28/2001
• Issued: 04/27/2004
• Est. Priority Date: 12/30/1998
• Status: Expired due to Term

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA), Henkel China Company Limited
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Pavez Aranguiz, Roberto
• Primary Examiner(s): CHEUNG, WILLIAM K
• Application Number:
  US09/869,467
• Time in Patent Office: 1,034 Days
• Field of Search: 524/500, 524/425, 524/423, 524/431, 524/503, 524/487
• US Class Current: 524/423
• CPC Class Codes: C08F 2/44 Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
• CPC Class Codes: C08F 263/04 on to polymers of vinyl acetate
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence
• CPC Class Codes: C09J 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09J151/04, C09J151/06 take precedence

Abstract

A filler-containing an organic polymer dispersion is provided. The organic polymer of the dispersion is polymerized in the presence of particles of at least one filler. The ratio of the particle size of the filler particles to the particle size of the polymer particles is in the range of from 1.1:1 to 20:1.

Claims

1. A filler-containing polymer dispersion comprising water, particles of at least one filler selected from the group consisting of organic fillers, inorganic fillers and mixtures thereof, at least one nonionic surfactant with an HLB value of from 13 to 20 and particles of at least one synthetic organic polymer, polymerized in the presence of at least one type of the filler particles, wherein the ratio of the particle size of the filler particles to the particle size of the polymer particles is in the range from 1.1:

1 to 20;

1.

2. The filler-containing polymer dispersion as claimed in claim 1, wherein the polymer particles have a diameter (d50) of 0.03 to 0.5 μ

m.

3. A filler-containing polymer dispersion as claimed in claim 1, wherein the inorganic filler comprises a member selected from the group consisting of chalk (CaCO₃), gypsum (CaSO₄) as anhydrite, hemlhydrate or dihydrate, silica flour, silica gel, titanium dioxide, talcum, a layer silicate, barium sulfate, barite and mixtures thereof and wherein the organic filler comprises a member selected from the group consisting of polyvinyl acetate, vinyl acetate copolymers, polystyrene, polyethylene, polypropylene, waxes, polybutylene, polybutadiene, copolymers of butadiene and styrene, polyacrylonitrile, resins, polyacrylate esters, polymethacrylate esters polymers containing silyl groups and mixtures thereof.

4. The filler-containing polymer dispersion as claimed in claim 1, wherein the dispersion comprises at least one ionic surfactant with an HLB value of 1 to 10.

5. The filler-containing polymer dispersion as claimed in claim 1 comprising:

a) 10 to 70% by weight of a water-insoluble organic polymer;

b) 5 to 55% by weight of filler particles;

c) 0.05 to 0.5% by weight of a nonionic surfactant with an HLB value of 13 to 20;

d) 0.01 to 0.1% by weight of an ionic surfactant with an HLB value of 1 to 10;

e) 0.05 to 10% by weight of a water-soluble organic polymer with a molecular weight of more than 600 and an HLB value of more than 15;

f) 24.89 to 84.89% by weight of water and

g) 0 to 30% by weight of additives.

14. An adhesive or surface coating composition, comprising at least one filler-containing polymer dispersion according to claim 1.

16. The filler containing polymer of claim 2, wherein the inorganic filler comprises a member selected from the group consisting of chalk (CaCO₃), gypsum (CaSO₄) as anhydrite, hemihydrate or dihydrate, silica flour, silica gel, titanium dioxide, talcum, a layer silicate, barium sulfate, barite and mixtures thereof and wherein the organic filler comprises a member selected from the group consisting of polyvinyl acetate vinyl acetate copolymers, polystyrene, polyethylene, polypropylene, waxes, polybutylene, polybutadiene, copolymers of butadiene and styrene, polyacrylonitrile, resins, polyacrylate esters, polymethacrylate esters polymers containing silyl groups and mixtures thereof.

17. The filler-containing polymer dispersion as claimed in claim 2, wherein the dispersion comprises at least one ionic surfactant with an HLB value of 1 to 10.

6. The process for the production of a filler-containing polymer dispersion, in least two successive stages comprising:

a) a first stage comprising prepare a dispersion containing;

1) at least one ionic surfactant with an HLB value of 1 to 10 or a nonionic surfactant with an HLB value of 13 to 20 or a mixture of two or more thereof,

2) at least one inorganic filler with a particle size (d50) of 0.01 to 0.5 μ

m,

3) at least one polymerizable initiator;

4) at least one water-soluble organic polymer with a molecular weight of more than 600 and an HLB value of more than 15; and

5) heating the dispersion to a temperature of 70 to 90°

C.; and

b) a second stage comprising;

6) adding and polymerizing at least one radical-polymerizable monomer.

7. The process as claimed in claim 6, wherein the aqueous phase contains an ionic surfactant.

8. The process as claimed in claim 6, wherein the aqueous phase contains a nonionic surfactant.

9. The process as claimed in claim 6, wherein the polymerization initiator is water-soluble.

10. The process as claimed in claim 6, wherein the inorganic filler particles are added before the polymerization initiator.

11. The process as claimed in claim 6, wherein the filler particles dispersed in the aqueous phase are pre-emulsified with one or more monomers.

12. The process as claimed in claim 11, wherein the polymerization initiators are added in portions to the dispersion.

13. The filler-containing polymer dispersion, produced by the process claimed in claim 6.

15. The adhesive or surface coating composition produced by the process of claim 6.