Scratch and mar resistant propylene polymer composition

• US 6,734,253 B2
• Filed: 07/19/2002
• Issued: 05/11/2004
• Est. Priority Date: 07/19/2002
• Status: Expired due to Fees

• Current Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Original Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Inventors: Krabbenborg, Franciscus J. T., Hovestad, Neldes J.
• Primary Examiner(s): Nutter, Nathan M.
• Application Number:
  US10/199,531
• Publication Number:
  US 20040014891A1
• Time in Patent Office: 662 Days
• Field of Search: 525/191, 525/240, 524/451
• US Class Current: 525/191
• CPC Class Codes: C08F 10/06 Propene
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 8/34 Introducing sulfur atoms or sulfur-containing groups
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08L 2023/44 Coupling; Molecular weight increase
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 2314/06 Metallocene or single site catalysts
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

Abstract

Disclosed are injection molded automotive articles comprising a coupled propylene polymer composition and optionally a thermoplastic elastomer, a thermoplastic polymer and a filler.

Claims

1. A process for preparing an injection molding automotive article from a coupled propylene polymer composition comprising the steps of:

i preparing a coupled propylene polymer composition comprising;

(a) a propylene polymer formed by a reaction of from about 0.01 to 1.0 weight percent of a poly(sulfonyl azide) with a propylene polymer, wherein weight percent is based on the weight of the propylene polymer, and optionally one or more of

(b) a polyolefin elastomer,

(c) a thermoplastic polymer

(d) a filler or

(e) a slip agent, and

ii injection molding an automotive article.

2. The process of claim 1 wherein the propylene polymer is an impact propylene copolymer.

3. The process of claim 1 wherein the poly(sulfonyl)azide is 4,4′

-diphenyl ether bis(sulfonyl azide).

4. The process of claim 1 wherein the poly(sulfonyl)azide is added as a dry mixture of 4,4′

-diphenyl ether bis(sulfonyl azide) and tetrakis methane optionally blended with a linear propylene homopolymer polymer powder.

5. The process of claim 1 wherein the poly(sulfonyl)azide is added as a melt blended mixture of 4,4′

-diphenyl ether bis(sulfonyl azide) and tetrakis methane with a linear propylene homopolymer.

6. The process of claim 1 wherein the coupled propylene polymer composition comprises from about 1 to about 70 weight percent of a polyolefin elastomer, wherein weight percent is based on the weight of the propylene polymer composition.

7. The process of claim 6 wherein the polyolefin elastomer is a substantially linear ethylene polymer or a linear ethylene polymer.

8. The process of claim 1 wherein the coupled propylene polymer composition comprises from about 1 to about 70 weight percent of a thermoplastic polymer, wherein weight percent is based on the weight of the propylene polymer composition.

9. The process of claim 8 wherein the thermoplastic polymer is linear low density polyethylene, low density polyethylene or high density polyethylene.

10. The process of claim 1 wherein the coupled propylene polymer composition comprises from about 1 to about 60 weight percent of a filler, wherein weight percent is based on the weight of the propylene polymer composition.

11. The process of claim 10 wherein the filler is a calcined talc, an uncalcined talc or mixture thereof.

12. The process of claim 1 wherein the coupled propylene polymer composition comprises up to about 1 weight percent of a slip agent, wherein weight percent is based on the weight of the propylene polymer composition.

13. The process of claim 12 wherein the slip agent is erucamide.

15. The process of claim 1 wherein the propylene polymer coupling reaction takes place in the same injection molding machine that produces the injection molded automotive article.

16. The process of claim 1 wherein the article is a seat back, a head rest, a knee bolster, glove box door, an instrument panel, a bumper facia, a bumper beam, a center console, an intake manifold, a spoiler, a side molding, a pillar, a door trim, an airbag cover, a HVAC duct, a spare tire cover, a fluid reservoir, a rear window shelf, a resonator, a trunk board, airbag covers, mats, weather stripping, window seals, shift lever knobs, interior skins, and soft tough over-moldings or an arm rest.

14. A process for preparing an injection molding automotive article from a coupled propylene polymer composition comprising the steps of:

i preparing a coupled propylene polymer composition comprising;

(a) from about 30 to about 80 weight percent of a propylene polymer formed by a reaction of from about 0.1 to about 0.6 weight percent based on the weight of the propylene polymer of 4,4′

-diphenyl ether bis(sulfonyl azide) with a propylene polymer,

(b) from about 5 to about 20 weight percent of a substantially linear ethylene polymer or linear ethylene polymer,

(c) from about 5 to about 20 weight percent of linear low density polyethylene or high density polyethylene

(d) from about 10 to about 30 weight percent of calcined talc, uncalcined talc or mixture thereof and

(e) from 0 to about 1 weight percent of erucamide, wherein weight percents for (b), (c), (d) and (e) are based on the weight of the coupled propylene polymer composition and

ii injection molding an automotive article.