Encapsulated lithium alloy electrodes having barrier layers

• US 6,737,197 B2
• Filed: 10/30/2001
• Issued: 05/18/2004
• Est. Priority Date: 11/01/1999
• Status: Expired due to Term

• Current Assignee: PolyPlus Battery Company
• Original Assignee: PolyPlus Battery Company
• Inventors: Chu, May-Ying, Visco, Steven J., DeJonghe, Lutgard C.
• Primary Examiner(s): Ruthkosky, Mark
• Application Number:
  US09/999,673
• Publication Number:
  US 20020034688A1
• Time in Patent Office: 931 Days
• Field of Search: 429/231.95, 429/232, 429/218.1
• US Class Current: 429/231.95
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0402 Methods of deposition of the material
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0407 by coating on an electrolyte layer
• CPC Class Codes: H01M 4/0411 by extrusion
• CPC Class Codes: H01M 4/0421 involving vapour deposition
• CPC Class Codes: H01M 4/0426 Sputtering
• CPC Class Codes: H01M 4/043 involving compressing or compaction
• CPC Class Codes: H01M 4/0495 Chemical alloying
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/66 Selection of materials
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/10 Battery-grid making
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

A method employing a bonding layer is used to form active metal electrodes having barrier layers. Active metals such as lithium are highly reactive in ambient conditions. The method involves fabricating a lithium electrode or other active metal electrode without depositing the barrier layer on a layer of metal. Rather a smooth barrier layer is formed on a smooth substrate such as a web carrier or polymeric electrolyte. A bonding or alloying layer is formed on top of the barrier layer. Lithium or other active material is then attached to the bonding layer to form the active metal electrode. A current collector may also be attached to the lithium or active metal during the process.

Claims

1. A barrier layer laminate for use in fabricating an active metal electrode, the barrier layer laminate comprising:

(i) a substantially smooth and flat substrate;

(ii) a barrier layer disposed on the substrate, the barrier layer forming a substantially impervious layer which is conductive to ions of an active metal, and

(iii) a bonding layer disposed on the barrier layer, the bonding layer material being capable of forming a bond with the active metal,

wherein the barrier layer laminate does not comprise an attached active metal.

2. The barrier layer laminate of claim 1, wherein the substrate on which the barrier layer is disposed is a releasable web carrier.

3. The barrier layer laminate of claim 2, wherein the releasable web carrier includes a layer of copper, tin, zinc, aluminum, iron, a polymeric material, or combination thereof on which the barrier layer is disposed.

4. The barrier layer laminate of claim 1, wherein the substrate on which the barrier layer is disposed is a solid-state or gel-state electrolyte separator.

5. The barrier layer laminate of claim 1, wherein the substrate on which the barrier layer is disposed is a polymeric electrolyte separator.

6. The barrier layer laminate of claim 5, wherein the polymeric electrolyte separator comprises a material selected from the group consisting of polyethers, polyimines, polythioethers polyphosphazenes, and polymer blends, mixtures, and copolymers thereof.

7. The barrier layer laminate of claim 5, wherein the polymeric electrolyte separator comprises a polyalkylene oxide.

8. The barrier layer laminate of claim 1, wherein the barrier layer includes at least one of a lithium silicate, a lithium borate, a lithium aluminate, a lithium phosphate, a lithium phosphorus oxynitride, a lithium silicosulfide, a lithium borosulfide, a lithium aluminosulfide, and a lithium phosphosulfide.

9. The barrier layer laminate of claim 1, wherein the barrier layer comprises an organic polymeric material.

10. The barrier layer laminate of claim 9, wherein the organic polymeric material includes at least one of nitrogen and phosphorus.

11. The barrier layer laminate of claim 1, wherein the barrier layer is a glass layer having a thickness of between about 50 angstroms and 5 micrometers.

12. The barrier layer laminate of claim 1, wherein the barrier layer is a glass and has a thickness of between about 500 angstroms and 2000 angstroms.

13. The barrier layer laminate of claim 1, wherein the barrier layer has an ionic conductivity of between about 10⁻

8 and about 10<sup>−

2</sup> (ohm-cm)<sup>−

1</sup>.

14. The barrier layer laminate of claim 1, wherein the bonding layer is not substantially reactive with moisture and air.

15. The barrier layer laminate of claim 1, wherein the bonding layer is comprised of at least one of aluminum, an aluminum alloy, silicon, zinc, manganese, silver, antimony, magnesium, lead, tin, iron, titanium and also alloys of such metals, carbon, spinel Mn₂O₄, NiO₂, CoO₂, vanadium oxides, pyrite, FeS₂, MoO₂, tin oxide, titanium oxide, polyethylene oxide, polyethylene glycol, polyaniline, polyacetylene, and polypyrrole.

16. The barrier layer laminate of claim 1, wherein the bonding layer is comprised of aluminum or an aluminum alloy.

17. The barrier layer laminate of claim 1, wherein the bonding layer is an aluminum or aluminum alloy layer having a thickness between about 100 angstroms and 10 micrometers.

18. The barrier layer laminate of claim 1, wherein the active metal is lithium or an alloy of lithium.

19. An active metal electrode comprising an active metal layer bonded to the bonding layer of the barrier layer laminate of claim 1.

20. A battery comprising the active metal electrode of claim 19.

21. The battery of claim 20, wherein the battery is a lithium-sulfur battery.