Base coat and its use for producing color and/or effect-producing base coatings and multi-layer coatings

• US 6,737,468 B1
• Filed: 01/11/2002
• Issued: 05/18/2004
• Est. Priority Date: 07/02/1999
• Status: Expired due to Fees

• Current Assignee: BASF Coatings AG (BASF SE)
• Original Assignee: BASF Coatings AG (BASF SE)
• Inventors: Bremser, Wolfgang
• Primary Examiner(s): REDDICK, MARIE L
• Application Number:
  US10/018,351
• Time in Patent Office: 858 Days
• Field of Search: 524/804, 524/805, 524/806, 524/812, 524/817, 524/819, 524/832, 524/833, 524/543, 524/544, 524/547, 524/551, 524/553, 524/555, 524/556, 524/558, 524/460, 524/560, 524/561, 524/563, 524/564, 524/565, 524/548, 524/567, 524/570, 524/577, 524/431
• US Class Current: 524/547
• CPC Class Codes: B05D 7/532 the two layers being cured or baked together, i.e. wet on wet
• CPC Class Codes: B05D 7/534 the first layer being let to dry at least partially before applying the second layer B05D7/538 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence
• CPC Class Codes: C09D 153/00 Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers

Abstract

The use of a copolymer (A) preparable by free-radical polymerization of

a) at least one olefinically unsaturated monomer and

b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I

R¹R²C=CR³R⁴  (I),

in which the radicals R¹, R², R³ and R⁴ each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R¹, R², R³ and R⁴ are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals, in an aqueous medium, in a basecoat material used to produce color and/or effect basecoats BL and multicoat color and/or effect coating systems ML.

Claims

1. A basecoat material comprising.

(A) a binder comprising at least one copolymer prepared by free-radical polymerization of

a) at least one olefinically unsaturated monomer and

b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and reperesented by formula I

2. The basecoat material of claim 1, wherein the copolymer

(A) is obtained by

(i) subjecting at least one monomer (a) and at least one monomer (b) to free-radical polymerization in an aqueous medium to provide a reaction product, and then

(ii) reacting the resultant reaction product with at least one further monomer (a) under free-radical conditions.

3. The basecoat material of claim 2, wherein the aryl radicals R¹, R², R³ and/or R⁴ of the compound

c) comprise phenyl or naphthyl radicals.

4. The basecoat material of claim 3, wherein the substituents in radicals R¹, R², R³ and/or R⁴ of the compound are b) electron-donating or electron-withdrawing atoms or organic radicals.

5. The basecoat material of claim 1, wherein monomers comprise at least one of

a1) (meth)acrylic esters;

a2) monomers which carry per molecule at least one hydroxyl group, amino group, alkoxymethylamino group or imino group;

a3) monomers which carry per molecule at least one acid group which can be converted to the corresponding acid anion group;

a4) vinyl esters of alpha-branched monocarboxylic acids having 5 to 18 carbon atoms in the molecule;

a5) reaction products of acrylic acid and/or methacrylic acid with the glycidyl ester of an alpha-branched monocarboxylic acid having 5 to 18 carbon atoms per molecule;

a6) cyclic and/or acyclic olefins

a7) (meth)acrylamides;

a8) monomers containing epoxide groups;

a9) vinylaromatic hydrocarbons;

a10) nitriles;

a11) vinyl compounds

a12) allyl compounds

a13) polysiloxane macromonomers having a number- average molecular weight Mn of from 1000 to 40,000 and having on average from 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; and

a14) acryloxysilane-containing vinyl monomers, prepared by reacting hydroxyl-functional silanes with epichlorohydrin and then reacting the reaction product with (meth)acrylic acid and/or hydroxyalkyl and/or hydroxycycloalkyl esters of (meth)acrylic acid.

6. The basecoat material of claim 1, herein the basecoat material further comprises at least one of:

A) at least one binder different than the copolymer (A);

C) at least one crosslinking agent,

D) at least one constituent which is crosslinkable with actinic radiation,

E) at least one photoinitiator,

F) at least one thermal crosslinking initiator,

G) at least one reactive diluent curable thermally and/or with actinic radiation,

H) at least one coatings additive, and

I) at least one organic solvent,

wherein the at least one binder different than copolymer (A) contains at least one functional group (afg) that is able to undergo thermal crosslinking reactions with complementary functional groups (cfg) in the crosslinking agent (C), and the crosslinking agent contains at least two functional groups (afg) that are able to undergo thermal crosslinking reactions with complementary functional groups (cfg) in at least one of the binder and the at least one binder different than copolymer (A).

7. The basecoat material of claim 3, wherein the aryl radicals R¹, R², R³ and/or R⁴ of the compound comprise phenyl radicals.

8. The basecoat material of claim 4, wherein the substituents in radicals R¹, R², R³ and/or R⁴ of the compound are at least one of halogen atoms, nitrile, nitro, partially or fully halogenated alkyl, cycloalkyl, alkylcycloalkyl, cycloalkyalkyl, aryl, alkylaryl, cyclalkylaryl, arylalkyl and arylcycloalkyl radicals;

aryloxy, alkyloxy and cycloalkyloxy radicals;

arylthaio, alkylthio and cycloalkylthio radicals;

hydroxyl groups and/or primary, secondary and/or tertiary amino groups.