Infrared analysis instrument with offset probe for particulate sample

• US 6,737,649 B2
• Filed: 04/16/2002
• Issued: 05/18/2004
• Est. Priority Date: 04/16/2002
• Status: Active Grant

• Current Assignee: Foss Nirsystems, Inc. (Metrohm Stiftung)
• Original Assignee: Foss Nirsystems, Inc. (Metrohm Stiftung)
• Inventors: Webster, Donald R.
• Primary Examiner(s): Hannaher, Constantine
• Assistant Examiner(s): Gabor, Otilia
• Application Number:
  US10/122,373
• Publication Number:
  US 20030193028A1
• Time in Patent Office: 763 Days
• Field of Search: 250/339.07, 250/339.01, 250/339.02, 250/339.09, 250/339.11, 250/339.12, 250/341.8, 356/301
• US Class Current: 250/339.07
• CPC Class Codes: G01N 21/35 using infrared light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/3563 for analysing solids; Preparation of samples therefor
• CPC Class Codes: G01N 21/474 Details of optical heads therefor, e.g. using optical fibres

Abstract

In an infrared analysis instrument, a fiber optic probe, designed to be inserted into a particulate sample, is formed from distal ends of transmitting and receiving optic fibers. The distal ends of the transmitting fibers are located centrally in the probe and the distal ends of the receiving fibers are formed in a ring around the distal ends of the transmitting fibers. The distal ends of the receiving fibers are set back from the distal ends of the transmitting fibers. The receiving fibers carrying diffusely scattered light reflected from and transmitted through the particulate sample to a spectrophotometer housing containing fixed grating and an array of silicon photodetectors arranged to detect the spectrum dispersed by the grating in the range of 500 to 1100 nm.

Claims

1. An infrared analysis instrument comprising first and second sets of optical fibers, the distal ends of said first and second sets of optical fibers being formed into a probe for inserting into a particulate sample, an infrared light source arranged to introduce a near infrared light into the proximal ends of said first set of optical fibers to introduce said near infrared light into a particulate sample through the distal ends of said first set of optic fibers, the distal ends of said first and second set of optical fibers being offset from one another so that light introduced into said sample through said first set of optical fibers is diffusely transmitted through said sample to be received by the distal ends of said second set of optic fibers, a spectrophotometer positioned to receive the diffusely reflected light transmitted through said second set of optic fibers and detect the intensity of narrow band components of the spectrum of the near infrared light transmitted from the distal ends of said second set of optic fibers through said second set of optic fibers to said spectrophotometer.

2. An infrared analysis instrument as recited in claim 1 wherein the distal ends of one of said first and second sets of fiber optic fibers is centrally located in said probe and the distal ends of the other one of said first and second sets of optic fibers is arranged in a ring around the distal ends of said first set of optic fibers.

3. An infrared analysis instrument as recited in claim 2 wherein the distal ends of said second set of fibers are set back from the distal ends of said first set of fibers.

4. An infrared analysis instrument as recited in claim 1 wherein the distal ends of said second set of fibers are set back from the distal ends of said first set of fibers.

5. An infrared analysis instrument as recited in claim 1 wherein said spectrophotometer comprises a fixed grating positioned to be irradiated by light transmitted through said second set of fibers and an array of photodetectors positioned to detect narrow band width components of the spectrum dispersed by said grating.

6. An infrared analysis instrument as recited in claim 5 wherein said array of photodetectors are arranged to detect the spectrum of said near infrared light transmitted to said spectrophotometer in the range of 500 to 1100 nm, said photodetectors comprising silicon photodetectors.

7. An infrared analysis instrument as recited in claim 1 wherein said spectrophotometer comprises an array of photodetectors each arranged to detect a narrow band component of a dispersed spectrum, said spectrophotometer further comprising an optical dispersing element to disperse the near infrared light received through said second set of optic fibers into a spectrum dispersed over said array of photodetectors.

8. A infrared analysis instrument as recited in claim 7 wherein said array of photodetectors is arranged to detect the spectrum in the range of 500 to 1100 nm and wherein said photodetectors comprise silicon photodetectors.

9. A probe for an instrument measuring infrared absorbance of a particulate sample comprising a first set of optic fibers designed to transmit near infrared in the range of 500 to 1100 nm, a second set of optic fibers designed to transmit infrared light in the range of 500 to 1100 nm, the distal ends of said second set of optic fibers forming a ring around the distal ends of said first set of optic fibers to form said probe, the distal ends of said second set of optic fibers being set back from the distal ends of said first set of optic fibers, a sheath enclosing said second set of optic fibers said sheath having a distal end terminating at the distal ends of said second set of optic fibers.

10. A method of measuring the absorbance of a particulate material comprising inserting a fiber optic probe into said particulate material, said probe comprising a first set of optic fibers and a second set of optic fibers, the distal ends of said second set of optic fibers being offset from the distal ends of said first set of optic fibers, introducing near infrared light into said sample through said first set of optic fibers, receiving infrared light diffusely reflected by said sample into the distal ends of said second set of optic fibers, and measuring the intensity of the light transmitted through said second set of optic fibers.

11. A method as recited in claim 10 wherein the distal ends of said second set of optic fibers is set back from said first set of optic fibers so that light introduced into said sample through the distal ends of said first set of optic fibers is backward scattered from said sample and then forward scattered through said sample into the distal ends of said second set of optic fibers.

12. A method as recited in claim 10 further comprising dispersing the light received into the distal ends of said second optic fibers into a spectrum, and detecting narrow band components of said spectrum.

13. A method as recited in claim 12 wherein said narrow band components of said spectrum are detected by an array of silicon photodetectors positioned to detect said spectrum in the range from 500 nm to 1100 nm.