Method for removing H2S and CO2 from above ground hydrocarbon streams

• US 6,740,141 B2
• Filed: 08/26/2002
• Issued: 05/25/2004
• Est. Priority Date: 02/23/2001
• Status: Expired due to Term

• Current Assignee: Intevep, S.A. (PDVSA Gas SA), Timilon Corporation
• Original Assignee: Nanoscale Materials, Inc., Intevep, S.A. (PDVSA Gas SA)
• Inventors: Klabunde, Kenneth, Winecki, Slawomir, Decker, Shawn, Araujo, Mariela, Ranson, Aaron, Espin, Douglas
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US10/228,123
• Publication Number:
  US 20030033934A1
• Time in Patent Office: 638 Days
• Field of Search: 95/90, 951/35, 951/36, 951/39, 210/667, 210/747, 502/325, 502/328, 502/340, 166/265, 166/266, 166/267, 166/276, 166/279, 585/820
• US Class Current: 95/136
• CPC Class Codes: C10G 25/00 Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
• CPC Class Codes: C10G 25/003 Specific sorbent material, not covered by C10G25/02 or C10G25/03

Abstract

A method for removing at least one contaminant selected from the group consisting of H₂S and CO₂ from contaminating streams, including the steps of providing an above ground stream comprising hydrocarbon containing the at least one contaminant, and positioning metal-containing nanoparticles having a particle size of less than or equal to about 100 nm in the stream, the metal-containing nanoparticles being selected from the group consisting of metal oxides, metal hydroxides and combinations thereof, whereby the nanoparticles adsorb the contaminants from the stream.

Claims

1. A method for removing at least one contaminant selected from the group consisting of H₂S and CO₂ from above ground hydrocarbon streams, comprising the steps of:

providing an above ground stream of hydrocarbon containing said at least one contaminant; and

positioning metal-containing nanoparticles having a particle size of less than or equal to about 100 nm in said above ground stream, said metal-containing nanoparticles being selected from the group consisting of metal oxides, metal hydroxides and combinations thereof, whereby said nanoparticles adsorb said at least one contaminant from said above ground stream.

2. The method of claim 1, wherein said nanoparticles have a particle size of less than or equal to about 30 nm.

3. The method of claim 1, wherein said nanoparticles have a particle size of between about 1 nm and about 20 nm.

4. The method of claim 1, wherein said nanoparticles have a particle size of between about 1 nm and about 10 nm.

5. The method of claim 1, wherein said nanoparticles have a surface area of at least about 80 m²/g.

6. The method of claim 1, wherein said hydrocarbon stream is selected from the group consisting of hydrocarbon gas, crude and mixtures thereof.

7. The method of claim 1, wherein said nanoparticles contain a metal selected from the group consisting of calcium, magnesium, zinc, iron, and metals from groups 8, 9 and 10 of the period table of elements, and combinations thereof.

8. The method of claim 1, wherein said nanoparticles are calcium oxide having a surface area of greater than or equal to about 80 m²/g.

9. The method of claim 1, wherein said hydrocarbon stream contains H₂S and CO₂, and said nanoparticles are iron oxide-coated calcium oxide particles.

10. The method of claim 1, wherein said above ground stream being derived from a below ground source.