Multi component controlled delivery system for fabric care products
First Claim
1. A multi component moisture activated composition comprising:
- a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said solid nanoparticles are positively charged, wherein said nano-particles further comprise a cationic fabric conditioning agent.
1 Assignment
0 Petitions
Accused Products
Abstract
The present invention relates to an improved controlled delivery system that can be incorporated in dry granular, or powder, fabric care products, such as laundry detergents, tumble dryer sheets, rinse added products, and other fabric care products, to enhance fragrance performance. The controlled delivery system of the present invention comprises substantially free-flowing, powder formed of solid hydrophobic, positively charged, nano-spheres of encapsulated active ingredients, such as a fragrance, that are encapsulated in a moisture sensitive micro-spheres, solid spheres. The high cationic charge density of the nano-sphere improves fragrance deposition onto the laundered fabric. The high cationic charge density on the nano-sphere surface is created by incorporating a cationic fabric conditioning agent into the solid hydrophobic matrix of the nano-spheres, by incorporating a cationic charge “booster” in the water sensitive micro-sphere matrix, or by using a cationic fabric conditioning agent in the nano-sphere matrix in conjunction with a cationic charge “booster” in the micro-sphere matrix. The fragrance carrier system also provides controlled release or prolonged fragrance release from the dry laundered fabric over an extended period of time, or yields a high impact fragrance “burst” upon ironing the fabric. The invention also pertains to fabric care products comprising the controlled release system of the present invention.
107 Citations
42 Claims
-
1. A multi component moisture activated composition comprising:
-
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said solid nanoparticles are positively charged, wherein said nano-particles further comprise a cationic fabric conditioning agent. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18)
(i) incorporating the first active agent and said cationic fabric conditioning agent into said nano-spheres;
(ii) forming an aqueous mixture comprising said nano-spheres, said second active agent, and said cationic charge booster and said moisture sensitive material; and
(iii) spray drying said mixture to form a dry powder composition.
-
-
14. A method for producing the composition of claim 9 comprising the steps of:
-
(i) heating a hydrophobic material for forming said nano-spheres to a temperature above a melting point of said hydrophobic material to form a melt;
(ii) dissolving or dispersing the cationic fabric conditioning agent into said melt;
(iii) dissolving or dispersing a fragrance and said first active agent into said melt;
(iv) dispersing said second active agent, said cationic charge booster, and said moisture sensitive matrix material in the aqueous phase;
(v) heating the dispersion to above the melting temperature of said hydrophobic material to form a hot melt;
(vi) mixing said hot melt with the aqueous phase to form a dispersion;
(vii) homogenizing the dispersion at a temperature above the melting temperature until a homogeneous fine dispersion is obtained having a particle size of from about 1 micron to about 2 microns;
(viii) cooling the homogenized dispersion to ambient temperature to form a suspension; and
(ix) spray drying the emulsified mixed suspension to form a dry powder composition.
-
-
15. The composition of claim 1 wherein said moisture sensitive matrix material is selected from the group consisting of a water soluble synthetic polymer, water dispersible synthetic polymers, a starch derivative, natural gum, polyvinyl alcohol, polysaccharide, protein, hydrocolloid, and mixtures thereof.
-
16. The composition of claim 15 wherein said hydrocolloid is selected from the group consisting of xanthan, maltodextrin, galactomanan, and tragacanth.
-
17. The composition of claim 15 wherein said starch derivative is present in an amount by weight of about 1% to about 70% by weight of said micro-sphere.
-
18. A fabric care product comprising said composition of claim 1.
-
19. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said micro-spheres further comprise a cationic charge booster selected from the group consisting of a quaternary ammonium compound, polyvinyl amine, polyalkyleneimine, and a poly-quaternary ammonium compound, wherein said solid nanoparticles are positively charged. - View Dependent Claims (20, 21, 22)
-
23. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said first active agent is selected from one or more of the agents of the group consisting of a fragrance, ironing aid, silicones, anti-shrinkage agent, anti -wrinkle agent, fabric crisping agent, bleaching agent, spotting agent, germicide, fungicide, stabilizer, preservative, bactericide, flow agent, and mixtures thereof, wherein said solid nanoparticles are positively charged. - View Dependent Claims (24, 25)
-
26. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, a second active agent encapsulated in said moisture sensitive matrix wherein said matrix releases said second active agent upon contact with said moisture and continuously thereafter for an extended period of time, wherein said solid nanoparticles are positively charged. - View Dependent Claims (27, 28, 29)
-
30. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material of gum arabic, wherein said solid nanoparticles are positively charged.
-
31. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material is polyvinyl alcohol, said polyvinyl alcohol is present in an amount by weight of about 1% to about 70% by weight of said particle, wherein said solid nanoparticles are positively charged.
-
32. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, wherein said moisture sensitive matrix material is polyvinyl alcohol, said polyvinyl alcohol is present in an amount by weight of about 70% to about 80% of said particle, wherein said solid nanoparticles are positively charged.
-
33. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, wherein said moisture sensitive matrix material is said polyvinyl alcohol, said polyvinyl alcohol has a degree of hydrolysis from about 75% to about 99%, wherein said solid nanoparticles are positively charged.
-
34. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, wherein said moisture sensitive matrix material is a starch derivative is present in an amount by weight of about 30% to about 40% of said sphere and said polyvinyl alcohol is present in an amount by weight of about 30% to about 40% of said sphere, wherein said nanoparticles are positively charged.
-
35. A multi component moisture activated composition comprising:
-
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said hydrophobic material is selected from the group consisting of natural waxes and synthetic waxes, natural wax and silicon copolymers, synthetic wax and silicon copolymer, fatty acid esters, fatty alcohols, solid hydrogenated plant oils, natural polymers and synthetic polymers, wherein said solid nanoparticles are positively charged.
-
-
36. A multi component moisture activated composition comprising:
-
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said hydrophobic material comprises candelilla wax, wherein said solid nanoparticles are positively charged.
-
-
37. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said hydrophobic material comprises candelilla wax and silicon copolymer, wherein said nanoparticles are positively charged.
-
38. A multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said first active agent comprises about 1% to about 50% by weight of a fragrance, wherein said solid nanoparticles are positively charged. - View Dependent Claims (39)
-
40. A method for providing fragrance control release over an extended period of time in a fabric care product comprising the step of providing a moisture activated composition, comprising a fragrance incorporated into a hydrophobic positively charged nano-particle and encapsulated in a moisture sensitive matrix material.
-
41. A method for providing fragrance control release over an extended period of time in a fabric care product comprising the step of providing a moisture activated composition, said composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, wherein said solid nanoparticles are positively charged.
-
42. A fabric care product comprising a multi component moisture activated composition comprising:
a plurality of solid nanoparticles, each of said solid nanoparticles comprising an effective amount of a first active agent, said solid nanoparticles are formed of a hydrophobic material, said plurality of nanoparticles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, said solid nanoparticles are positively charged wherein said fabric care product is selected from the group consisting of;
a fabric softener;
tumble dryer sheets, powder laundry detergent;
rinse added product;
drier-added fabric softener product; and
ironing added product.
Specification