Ink and underprinting fluid combinations with improved inkjet print image color and stability

• US 6,740,689 B1
• Filed: 10/30/2000
• Issued: 05/25/2004
• Est. Priority Date: 10/30/2000
• Status: Expired due to Term

• Current Assignee: Hewlett-Packard Development Company, L.P. (HP Inc.)
• Original Assignee: Hewlett-Packard Development Company, L.P. (HP Inc.)
• Inventors: Kabalnov, Alexey S, Kowalski, Mark H., Schut, David M., Chatterjee, Amiya K., Byers, Gary W, Prasad, Keshava A, Lee, Shirley
• Primary Examiner(s): SHOSHO, CALLIE E
• Application Number:
  US09/702,185
• Time in Patent Office: 1,303 Days
• Field of Search: 523/160, 523/161, 106/31.27, 106/31.28, 524/548, 524/555, 524/556
• US Class Current: 523/160
• CPC Class Codes: B41J 2/2114 Ejecting specialized liquids, e.g. transparent or processing liquids B41J2/211 takes precedence
• CPC Class Codes: B41M 5/0017 Application of ink-fixing material, e.g. mordant, precipitating agent, on the substrate prior to printing, e.g. by ink-jet printing, coating or spraying
• CPC Class Codes: C09D 11/30 Inkjet printing inks
• CPC Class Codes: C09D 11/54 Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink

Abstract

Combinations of cationic underprinting fluids and anionic ink compositions that together achieve improved color quality and image stability in ink-jet printed images.

Claims

1. A dye-based ink-jet ink composition comprising:

at least one water-soluble dye and,

at least one water-soluble anionic binder,

wherein the at least one anionic binder comprises a polymer having at least one complexing group selected from the group consisting of Ethylene Diamine Tetracetic Acid, Acetyl Acetonate, Maleic Anhydride, Acrylate and combinations thereof;

and wherein, when the ink composition is printed on a medium over an underprinted fixer fluid comprising at least one cationic component, the printed ink composition and the underprinted fixer fluid together form an amorphous, viscous fluid on the medium, the mixture being an amorphous viscous fluid, having a viscosity greater than the ink;

and wherein the at least one cationic component comprises a cationic polyelectrolyte selected from the group consisting of R₁R₂R₃R₄N⁺;

R₁R₂R₃R₄P⁺and R₁R₂R₃R₄As⁺, where R can be H, alkyl or other organic substituent, and where the cationic polyelectrolyte is from 2000 up to 10,000 weight average molecular weight;

and wherein the cationic polyelectrolyte is in solution with non-polymeric cations selected from the group consisting of calcium ions, aluminum ions, barium ions, strontium ions, zinc ions, magnesium ions and titanium ions.

2. The ink-jet ink composition of claim 1, wherein the polymer comprises styrene.

3. The ink-jet ink composition of claim 1, wherein the anionic binder comprises hydrolyzed styrene maleic anhydride.

4. The ink-jet ink composition of claim 1, wherein the at least one dye comprises anionic functional groups.

5. The ink-jet ink compositions of claim 4, wherein the at least one dye having anionic functional groups is selected from the group consisting of sulfonated dyes with non-polar groups, dyes with protonatable groups, dyes with carboxylate groups and dyes with phosphonate groups.

6. The ink-jet ink composition of claim 1, wherein the ink composition further comprises low-molecular weight hydrophilic compounds.

7. The ink-jet ink composition of claim 6, wherein the low-molecular weight hydrophilic compounds are selected from the group consisting of inorganic salts and lower alcohols.

8. The ink-jet ink composition of claim 1, wherein the cationic polyelectrolyte comprises at least one branched polymer chain.

9. The ink-jet ink composition of claim 1, wherein the cationic polyelectrolye is a tetrasubstituted ammonium salt.

10. An underprinting fixer fluid comprising:

at least one cationic component,

wherein the at least one cationic component comprises a cationic polyelectrolyte selected from the group consisting of R₁R₂R₃R₄N⁺;

R₁R₂R₃R₄P⁺and R₁R₂R₃R₄As⁺, where R can be H, alkyl or other organic substituent, and where the cationic polyelectrolyte is from 2000 up to 10,000 weight average molecular weight;

and wherein the cationic polyelectrolyte is in solution with non-polymeric cations selected from the group consisting of calcium ions, aluminum ions, barium ions, strontium ions, zinc ions, magnesium ions and titanium ions;

and wherein, when an ink-jet ink composition comprising at least one water-soluble dye and at least one water-soluble anionic binder is printed on a portion of a medium underprinted with the fixer fluid, the ink composition and the fixer fluid together form an amorphous viscous fluid, the viscous fluid having a viscosity greater than the ink;

and wherein the at least one anionic binder comprises a polymer having at least one complexing group selected from the group consisting of Ethylene Diamine Tetracetic Acid, Acetyl Acetonate, Maleic Anhydride, Acrylate and combinations thereof.

11. The underprinting fixer fluid of claim 10, wherein the polyelectrolyte comprises at least one branched polymer chain.

12. The underprinting fixer fluid of claim 10, wherein the cationic polyelectrolyte is a tetrasubstituted ammonium salt.

13. The underprinting fixer fluid of claim 10, wherein the polymer comprises styrene.

14. The underprinting fixer fluid of claim 10, wherein the anionic binder comprises hydrolyzed styrene maleic anhydride.

17. The underprinting fixer fluid of claim 10, wherein the ink composition further comprises low-molecular weight hydrophilic compounds.

18. The underprinting fixer fluid of claim 17, wherein the low-molecular weight hydrophilic compounds are selected from the group consisting of inorganic salts and lower alcohols.

15. The underprinting fixer fluid of 10, wherein the at least one dye comprises anionic functional groups.

16. The underprinting fixer fluid of claim 15, wherein the at least one dye having anionic functional groups is selected from the group consisting of sulfonated dyes with non-polar groups, dyes with protonatable groups, dyes with carboxylate groups and dyes with phosphonate groups.