Method and apparatus for in-process liquid analysis by laser induced plasma spectroscopy

• US 6,741,345 B2
• Filed: 02/08/2001
• Issued: 05/25/2004
• Est. Priority Date: 02/08/2001
• Status: Expired due to Term

• Current Assignee: Noranda, Inc. (Glencore Plc), National Research Council Canada
• Original Assignee: National Research Council Canada
• Inventors: Lucas, John M., Sabsabi, Mohamad, Héon, René
• Primary Examiner(s): Nguyen, Thong
• Assistant Examiner(s): Lavarias, Arnel C.
• Application Number:
  US09/778,723
• Publication Number:
  US 20020149768A1
• Time in Patent Office: 1,202 Days
• Field of Search: 356/318, 356/311, 356/313, 356/317, 356/51, 356/36, 250/428, 250/430, 250/432.R, 250/435, 250/438, 250/573, 250/576
• US Class Current: 356/318
• CPC Class Codes: G01N 21/15 Preventing contamination of the components of the optical system or obstruction of the light path
• CPC Class Codes: G01N 21/718 Laser microanalysis, i.e. with formation of sample plasma
• CPC Class Codes: G01N 21/85 Investigating moving fluids or granular solids

Abstract

A method and apparatus for spectrochemical analysis of liquids, including molten metals, using laser-induced plasma spectroscopy. The apparatus preferably comprises a high power pulsed laser focused on the surface of a liquid stream flowing in a measurement cell, and an optical spectrometer-detector assembly, which receives, detects and analyzes the radiation emitted by the high temperature plasma thereby excited. The measurement cell, and optional pump, establish laminar flow of the liquid flow, thereby permitting the laser to repeatedly sample a fresh un-perturbed surface, while also ensuring that bubbles formed in the liquid are removed from the focal volume Preferably, a blower prevents aerosols and matter ejected from the sample responsive to the incident energy from interacting with subsequent laser pulses, and from accumulating on the optic.

Claims

1. A laser-induced plasma spectroscopic apparatus for analysing a liquid comprising:

an optical structure to direct a beam of laser pulses to a surface of the liquid to generate a plasma that emits elemental radiation that corresponds to at least one compositional element of the liquid;

a detector structure for detecting said emitted elemental radiation; and

a cell assembly which establishes a substantially laminar flow of the liquid past the detector structure, said laminar flow sufficient to prevent said beam of laser pulses from perturbing a region on said surface within a focal volume of said detector structure, said cell assembly including a controller to control a liquid surface level.

2. An apparatus according to claim 1, wherein the controller controls a liquid speed of flow.

7. The laser-induced plasma spectroscopic apparatus of claim 1 wherein said laminar flow is sufficient to prevent waves being induced within said region on said surface by said beam of laser pulses.

8. The laser-induced plasma spectroscopic apparatus of claim 1 wherein said laminar flow is sufficient to prevent bubbles induced in the liquid by said beam of laser pulses from reaching said surface within said region.

3. A method of laser-induced plasma spectroscopic analysis of a liquid, comprising the steps of:

establishing a substantially laminar flow of the liquid;

directing a beam of laser pulses to a surface of the liquid to generate a plasma that emits elemental radiation that corresponds to at least one compositional element of the liquid; and

detecting the emitted elemental radiation using a detector;

wherein said laminar flow is sufficient to prevent said beam of laser pulses from perturbing a region on said surface within a focal volume of said detector.

4. A method according to claim 3, wherein said establishing step includes controlling a liquid speed of flow.

5. A method according to claim 3, wherein said detecting step uses an optical window and said establishing step includes establishing a substantially laminar flow of the liquid past said optical window and controlling a liquid surface level.

6. A method according to claim 5 further comprising generating an air flow between said optical window and the liquid, said air flow substantially preventing liquid drops, which are ejected from the liquid in response to said beam of lacer pulses, from accumulating on said optical window.

9. The method of claim 3, wherein said laminar flow is sufficient to prevent waves being induced within said region on said surface by said beam of laser pulses.

10. The method of claim 3 wherein said laminar flow is sufficient to prevent bubbles induced in the liquid by said beam of laser pulses from reaching said surface within said region.