Polyolefin compositions having high tenacity

• US 6,743,864 B2
• Filed: 03/04/2003
• Issued: 06/01/2004
• Est. Priority Date: 03/12/2002
• Status: Expired due to Term

• Current Assignee: Basell Poliolefine Italia Srl (Lyondellbasell Industries NV)
• Original Assignee: Basell Poliolefine Italia Srl (Lyondellbasell Industries NV)
• Inventors: Butala, Robert G., Han, Choong Y., Ennis, Gerald John, Glogovsky, Todd, Goberti, Paolo
• Primary Examiner(s): Nutter, Nathan M.
• Application Number:
  US10/379,177
• Publication Number:
  US 20030181597A1
• Time in Patent Office: 455 Days
• Field of Search: 525/191, 525/216, 525/232, 525/240
• US Class Current: 525/191
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/142 at least partially crystalline copolymers of propene with other olefins
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 2308/00 Chemical blending or stepwise polymerisation process with the same catalyst
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

Abstract

A polyolefin composition suitable for preparing single ply roofing membranes, comprising:

(A) from about 15 to about 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H₂C═CHR¹, where R¹ is H or a C₂₋₈ linear or branched alkyl, containing at least about 90% by weight of propylene, having solubility in xylene at room temperature lower than about 15% by weight;

(B) from about 60 to about 85% by weight of an elastomeric fraction comprising:

(1) a copolymer of propylene with ethylene containing about 20 to about 35% by weight ethylene, and having solubility in xylene at room temperature greater than about 70% by weight, the intrinsic viscosity of the xylene soluble fraction being higher than about 3.0 dl/g up to about 6.0 dl/g; and

(2) a copolymer of ethylene with at least one alpha-olefin of formula H₂C═CHR², where R² is a C₂₋₈ linear or branched alkyl, containing about 15% to 40% by weight alpha-olefin, and having solubility in xylene at room temperature greater than about 25% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from about 0.5 to about 5.0 dl/g;

the (1)/(2) weight ratio ranging from about 1:5 to about 5:1.

The polyolefin composition of the invention, preferably prepared by sequential polymerization in at least three stages, has tensile strength at break ≧25 MPa, elongation at break ≧700 MPa and toughness ≧150 MPa.

Claims

1. A polyolefin composition comprising:

(A) from about 15 to about 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H₂C═

CHR¹, where R¹ is H or a C<sub>2−

8</sub> linear or branched alkyl, containing at least about 90% by weight of propylene, having solubility in xylene at room temperature lower than about 15% by weight;

(B) from about 60 to about 85% by weight of an elastomeric fraction comprising;

(1) a copolymer of propylene with ethylene, optionally containing about 0.5 to 5% by weight of a diene, containing from about 20 to about 35% by weight ethylene and having solubility in xylene at room temperature greater than about 70% by weight, the intrinsic viscosity of the xylene soluble fraction being higher than about 3.0 dl/g up to about 6.0 dl/g; and

(2) a copolymer of ethylene with at least one alpha-olefin of formula H₂C═

CHR², where R² is a C<sub>2−

8</sub> linear or branched alkyl, optionally containing about 0.5 to 5% by weight of a diene, containing about 15% to 40% by weight alpha-olefin, and having solubility in xylene at room temperature greater than about 25% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from about 0.5 to about 5.0 dl/g;

the (1)/(2) weight ratio ranging from about 1;

5 to about 5;

1.

2. The polyolefin composition according to claim 1, wherein the amount of the crystalline copolymer (A) ranges from about 15 to about 35% by weight.

3. The polyolefin composition according to claim 1, wherein the crystalline copolymer (A) contains at least about 95% by weight of propylene and has solubility in xylene at room temperature lower than about 10% by weight.

4. The polyolefin composition according to claim 1 wherein, in the crystalline copolymer (A), said alpha-olefin is ethylene.

5. The polyolefin composition according to claim 1, wherein the copolymer (1) of fraction (B) contains from about 25 to about 30% by weight ethylene and has solubility in xylene at room temperature greater than about 75% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from about 3.5 to about 5.0 dl/g.

6. The polyolefin composition according to claim 1, wherein the copolymer (2) of fraction (B) contains from about 20 to about 35% by weight alpha-olefin and has solubility in xylene at room temperature greater than about 30% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from about 1.0 to about 4.5 dl/g.

7. The polyolefin composition according to claim 1 wherein, in the copolymer (2) of fraction (B), said alpha-olefin is 1-butene, 1-hexene or 1-octene.

8. The polyolefin composition according to claim 1, having tensile strength at break ≧

25 MPa (ASTM D 882, on a 100 μ

m film), elongation at break ≧

700 MPa (ASTM D 882, on a 100 μ

m film), and toughness ≧

150 MPa (ASTM D 638, on a 1 mm sheet).

9. The polyolefin composition according to claim 8, having tensile strength at break ≧

28 MPa (ASTM D 882, on a 100 μ

m film), elongation at break ≧

750 MPa (ASTM D 882, on a 100 μ

m film), and toughness ≧

170 MPa (ASTM D 638, on a 1 mm sheet).

10. The polyolefin composition according to claim 1, wherein the composition is obtainable by sequential polymerization in at least three stages, carried out in the presence of a catalyst comprising a trialkylaluminum compound, optionally an electron donor, and a solid catalyst component comprising a halide or halogen-alcoholate of Ti and an electron-donor compound supported on anhydrous magnesium chloride.

11. A process for the preparation of a polyolefin composition as claimed in claim 1, comprising at least three sequential polymerization stages with each subsequent polymerization being conducted in the presence of the polymeric material formed in the immediately preceding polymerization reaction, wherein the crystalline copolymer (A) is prepared in at least one first stage, and the elastomeric polymer fraction (B) is prepared in at least two sequential stages, all polymerization stages being carried out in the presence of a catalyst comprising a trialkylaluminum compound, optionally an electron donor, and a solid catalyst component comprising a halide or halogen-alcoholate of Ti and an electron-donor compound supported on anhydrous magnesium chloride, said solid catalyst component having a surface area (measured by BET) of less than about 200 m²/g, and a porosity (measured by BET) greater than about 0.2 ml/g.

12. The process according to claim 11, wherein the sequential polymerization stages are all carried out in gas phase.

13. Sheets comprising the polyolefin composition of claim 1.

14. Single ply roofing sheet comprising the polyolefin composition of claim 1.