Electrochromic display device

• US 6,744,549 B2
• Filed: 03/19/2002
• Issued: 06/01/2004
• Est. Priority Date: 03/19/2002
• Status: Expired due to Fees

• Current Assignee: Aveso, Inc. (Thales DIS France SA)
• Original Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Inventors: Flick, Derrick W., Vincent, John B.
• Primary Examiner(s): Epps, Georgia
• Assistant Examiner(s): Spector, David N.
• Application Number:
  US10/102,535
• Publication Number:
  US 20030179432A1
• Time in Patent Office: 805 Days
• Field of Search: 359/266, 359/268, 359/269, 359/270, 359/273, 359/274
• US Class Current: 359/269
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 2001/1557 Side by side arrangements of working and counter electrodes

Abstract

The invention is a display device comprising a solid top transparent, charge conducting material, positioned below the transparent solid material is an active layer comprising an electrochromic material and an electrolyte, and positioned below the active layer is a working electrode and a counter-electrode arranged to be isolated from one another, wherein the distance between the working and the counter electrode is greater than two times the thickness of the active layer between the electrode and the conductive material.

Claims

1. A display device comprising a solid transparent charge conducting material, positioned below the transparent material an active layer comprising an electrochromic material and an electrolyte;

and positioned below the active layer a working electrode and a counter-electrode arranged to be isolated from one another wherein the distance between the working electrode and the counter-electrode is greater than two times the thickness of the active layer between the electrode and the transparent conductive material.

2. The device of claim 1 wherein the working electrode and the counter electrode are arranged side-by-side in the same plane.

3. The device of claim 1 wherein the total resistance of the active layer is greater than 1,000 Ohms per centimeter.

4. The device of claim 1 wherein the total resistance of the active layer is greater than 10,000 Ohms per centimeter.

5. The device of claim 1 wherein the total resistance of the active layer is greater than 25,000 Ohms per centimeter.

6. The device of claim 1 wherein the resistance of the active layer is greater than twenty times the resistance of the top transparent material.

7. The device of claim 1 wherein the resistance of the active layer is greater than fifty times the resistance of the top transparent material.

8. The device of claim 1 wherein the resistance of the active layer is greater than one hundred times the resistance of the top transparent substrate.

9. The device of claim 1 wherein the active layer is continuously present across the working electrode and the counter electrode.

10. The device of claim 1 wherein an insulator is present between the working electrode and the counter electrode.

11. A display device comprising a transparent charge conducting material, positioned below the top transparent material, an active layer comprising (a) a non-aqueous compound that undergoes an electron transfer reaction with a subsequent change in its protic state resulting in a pH gradient in the device, (b) at least one indicator dye, and (c) a charge transport material;

and positioned below the active layer a working electrode and a counter electrode arranged to be isolated from one another wherein the distance between the working electrode and the counter electrode is two times the thickness of the active layer between the electrode and the transparent conductive material.

12. The device of claim 11 wherein the working electrode and the counter electrode are arranged side-by-side in the same plane.

13. The device of claim 12 wherein an insulator is present between the working electrode and the counter electrode.

14. A display device comprising a top transparent layer charge conducting material, positioned below the top transparent material an active layer comprising

(a) a compound that undergoes an electron transfer reaction with subsequent change in its protic state

(b) at least one indicator dye which changes color when a change in pH occurs, and

(c) an ionically conductive material

and optionally component (d), a matrix material, wherein components (a), (b), (c), and (d) are different from one another and component (a) preferentially undergoes the electron transfer reaction when a charge is applied to the composition and positioned below the active layer a working electrode and a counter-electrode arranged to be isolated from one another wherein the distance between the working electrode and the counter electrode is greater than two times the thickness of the active layer between the electrode and the transparent conductive material.

15. The device of claim 14 characterized in that the active layer further comprises component (a) is present in an amount from 0.01 to 15 weight percent, component (b) is present in an amount from 0.01 to 15 weight percent, component (c) is present in an amount from 5 to 99.98 weight percent, component (d) is present in an amount from 0 to 90 weight percent, an opacifier component (e) is present in an amount from 0 to 75 weight percent based on total weight of the composition and component (f) a secondary redox couple present in an amount of 0 to 15 weight percent.

16. The device of claim 14 wherein component (a) is selected from the group consisting of iodates, bromates, sulfates, metal hydroxides, phosphates, ketones, aldehydes, quinones, quinolines, sulfur compounds, hydroxybenzenes, carboxylic acids, and amines.

17. The device of claim 14 wherein component (b) comprises one or more indicator dyes selected from but not limited to the group consisting of phenylthalein, bromocrescol purple, phenol red, ethyl red, quinaldine red, thymolthalein, thymol blue, malachite green, crystal violet, methyl violet 2B, xylenol blue, cresol red, phyloxine B, congo red, methyl orange, bromochlorophenol blue, alizarin red, chlorophenol red, 4-nitrophenol, nile blue A, aniline blue, indigo carmine, and bromothymol blue.

18. The composition of claim 14 wherein the matrix (d) comprises a polymer or other viscosity modifier and the matrix is blended with the other components of the composition.

19. The composition of claim 14 wherein component (e) one opacifier is selected from the group consisting of titanium dioxide, latexes, and barium titanate.

20. The device of claim 14 wherein the top transparent charge conducting material is selected from the group consisting of indium tin oxide, tin oxide, antimony tin oxide, gold, chrome, platinum, poly(3,4-ethylenedioxythiophene), polyaniline, polythiophene, polypyrrole, and polyphenylenevinylene.

21. The device of claim 14 wherein the working electrode and the counter electrode are arranged side-by-side in the same plane.

22. The device of claim 14 wherein an insulator is present between the working electrode and the counter electrode.