Electrochemical device such as an electrically controlled system with variable optical and/or energy properties

• US 6,747,779 B1
• Filed: 01/10/2001
• Issued: 06/08/2004
• Est. Priority Date: 03/19/1999
• Status: Expired due to Term

• Current Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Inventors: Giron, Jean-Christophe, Beteille, Fabien, Morin, Claude
• Primary Examiner(s): Thompson, Tim
• Application Number:
  US09/700,684
• Time in Patent Office: 1,245 Days
• Field of Search: 359/265, 359/237, 359/275, 359/254, 359/251, 359/252, 359/269, 359/270, 359/271, 359/273, 359/274, 204/450, 204/600, 204/606, 204/485, 315/106, 315/107, 315/108, 315/111, 315/109
• US Class Current: 359/265
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10376 Laminated safety glass or glazing containing metal wires
• CPC Class Codes: B32B 17/10495 optoelectronic, i.e. optical valve
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/1077 containing polyurethane
• CPC Class Codes: B32B 17/10788 containing ethylene vinylacetate
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: G02F 1/13439 characterised by their electrical, optical, physical properties; materials therefor; method of making
• CPC Class Codes: G02F 1/155 Electrodes

Abstract

An electrochemical device including at least one carrier substrate, and a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, the higher-conductivity material having a surface resistance which is lower than a surface resistance of the electrically conducting layer.

Claims

1. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said higher-conductivity material is incorporated in said electrically conducting layer.

2. The device of claim 1, wherein said higher-conductivity material is incorporated in said electrically conducting layer, in the form of fibers or particles.

3. The device of claim 1, wherein said at least one electrically conducting layer comprises at least one doped metal oxide selected from the group consisting of doped tin oxide, doped zinc oxide and doped indium oxide.

4. The device of claim 3, wherein the doped tin oxide is fluorine doped or antimony doped.

5. The device of claim 3, wherein the doped zinc oxide is aluminum doped, tin doped or fluorine doped.

6. The device of claim 3, wherein the doped indium oxide is tin doped.

7. The device of claim 1, wherein said higher-conductivity material is essentially metallic.

8. The device of claim 7, wherein said higher-conductivity material comprises a metal selected from the group consisting of Ag, Au, Cu, Al, and alloys of thereof.

9. The device or claim 1, wherein said multicomponent electrode is essentially transparent in the visible region.

14. The device of claim 1, wherein said network comprises a fabric, a net or a metallic nonwoven material.

15. The device of claim 14, wherein said network comprises metallic wires having a diameter of from 10 to 100 μ

m.

22. The device of claim 1, wherein said multicomponent electrode is provided with current leads.

23. The device of claim 22, wherein said current leads are in the form of metal braids or shims.

28. A glazing, comprising:

the device of claim 1;

wherein said device uses as carrier substrate a) at least one rigid constituent substrate of a glazing or b) at least one flexible substrate combined by lamination with one rigid constituent substrate of said glazing or c) a combination of a) and b).

29. A method of making a glazing, comprising:

lamination the device of claim 1 with at least one rigid constituent substrate.

32. The device of claim 1, which is an electrically controllable system having variable optical properties or variable energy properties or both.

10. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said network comprises a plurality of conducting strips obtained by screen printing using a paste-like suspension of a silver-type metal and a low-melting-point frit in an organic binder.

11. The device of claim 10, wherein said plurality of conducting strips are essentially parallel each to the other.

12. An electrochemical device having at least one carrier substrate, and a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s) and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer, the device obtained by a process comprising:

screen-printing said network onto a glass-type carrier substrate to obtain a screen-printed network;

covering said screen-printed network with said at least one electrically conducting layer in order to form said multicomponent electrode;

or

laying down said network on said electrically conducting layer covering said carrier substrate.

13. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said network comprises a plurality of conducting wires in the form of essentially metallic wires surface-laid on a sheet comprising a thermoplastic polymer.

16. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said network comprises a fabric, a net or a metallic nonwoven material and is a network surface-laid on a sheet comprising a thermoplastic polymer.

17. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and n multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said network is obtained by etching or perforating a metallic layer or a metallic sheet.

18. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said multicomponent electrode comprises said at least one electrically conducting layer and at least one layer comprising said higher-conductivity material in electrical contact;

wherein at least one of said at least one electrically conducting layer and said at least one layer comprising said higher-conductivity material are optionally in contact with at least one layer comprising a dielectric material.

19. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, as least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said at least one layer comprising a dielectric material has an optical a function of anchoring said at least on layer comprising said higher-conductivity material to said carrier substrate or a function as a barrier to a migration of alkaline species coming from said carrier substrate which is glass.

20. The device of claim 19, wherein said at least one layer comprising a dielectric material comprising a member selected from the group consisting of metal oxide, silicon oxide, metal oxycarbide, silicon oxycarbide, metal oxynitride, silicon oxycarbide and silicon nitride.

21. An electrochemical device comprising:

at least one carrier substrate; and

a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemical active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer,

wherein said multicomponent electrode comprises a sequence ITO/Ag/ITO or Ag/ITO with optional interposition of at least one thin layer of partially oxidized metal at an Ag/ITO interface.

24. An electrochromic system, with at least one carrier substrate and a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer, comprising at least, in succession.

a first electrically conducting layer,

an electrochemically active layer liable to reversible insertion of ions of anodic-coloring or, respectively, cathodic-coloring electrochromic material type,

a layer of electrolyte,

a second electrochemically active layer to reversible insertion of ions of anodic-coloring or, respectively, anodic-coloring electrochromic material type, and

a second electrically conducting layer,

wherein at least one of said first and said second electrically conducting layer comprises said electrically conducting layer comprising metal oxide(s);

and

wherein at least one of said first and said second electrically conducting layer is part of said multicomponent electrode.

25. The device of claim 24, wherein said electrochromic system is an all-solid or all-polymer electrochromic system.

26. The device of claim 24, wherein said ions are H⁺, Li⁺ or OH⁻

.

27. A viologenic system comprising at least one carrier substrate and a stack of functional layers comprising at least one electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer, comprising at least, in succession,

a first electrically conducting layers,

a film having viologenic properties in the form of a polymer, of a gel or of a suspension in a liquid medium, and

a second electrically conducting layer;

wherein at least one of said first and second electrically conducting layer comprises said electrically conducting layer comprising metal oxide(s); and

wherein at least one of said first and said second electrically conducting layer is part of said multicomponent electrode.

30. An electrochemical energy storage device, comprising an electrochemical device including at least one carrier substrate and a stack of functional layers comprising at least on electrically conducting layer comprising metal oxide(s), and a multicomponent electrode including at least one electrochemically active layer, at least one higher-conductivity material and at least one network of one of conducting wires and conducting strips, said higher-conductivity material having a surface resistance which is lower than a surface resistance of said electrically conducting layer.

31. The electrochemical energy storage device of claim 30 which is a battery or a fuel cell.