Microsensor for measuring the position of liquids in capillaries

• US 6,748,804 B1
• Filed: 07/22/2002
• Issued: 06/15/2004
• Est. Priority Date: 09/15/1999
• Status: Expired due to Term

• Current Assignee: Fraunhofer Gesellschaft Zur Foerderung Der Angewandten Forsching E.V.
• Original Assignee: Fraunhofer Gesellschaft Zur Foerderung Der Angewandten Forsching E.V.
• Inventors: Lisec, Thomas, Quenzer, Hans Joachim, Wagner, Bernd
• Primary Examiner(s): Williams, Herzon
• Assistant Examiner(s): FRANK, RODNEY T
• Application Number:
  US10/088,200
• Time in Patent Office: 694 Days
• Field of Search: 733/04.R, 732/90.R
• US Class Current: 73/304.00R
• CPC Class Codes: G01F 23/242 Mounting arrangements for electrodes

Abstract

A sensor element for electrically measuring the position of liquid levels, comprising a substrate (2) and a plurality of electrodes (3) that can be contacted individually and that are mounted on the substrate, characterized in that the electrodes comprise sensor-active partial electrodes (5) that are networked with electrical connections (7), with the partial electrodes of two respective electrodes always being positioned opposite one another, separated by a distance, as partial electrode pairs (11) and with the electrode pairs (8) thus formed recurring periodically over the length of the sensor. Quasi-digital measuring methods are derived from the behavior of the impedance of the electrode pairs, whereby the liquid level is measured by detecting a conductivity boundary in a capillary filling.

Claims

1. A sensor element for electrically measuring the position of liquid levels, comprising:

a substrate; and

a plurality of electrodes adapted to be contacted individually and mounted on the substrate, wherein the electrodes comprise sensor-active partial electrodes that are networked with electrically connections, and wherein the partial electrodes of two respective electrodes are always positioned opposite one another, separated by a distance, to form partial electrode pairs, and the electrode pairs thus formed recur periodically over a length of the sensor element wherein the electrodes are essentially electrically insulated from each other.

2. The sensor element according to claim 1, wherein the electrically connections of the networked partial electrodes are coated with a passivating layer.

3. The sensor element according to claim 1, wherein the partial electrodes positioned pairwise opposite one another are always at least one of separated by the same distance, and the distances between the partial electrode pairs in the longitudinal direction of the sensor element are constant over the entire length of the sensor element, and the number of partial electrode pairs per electrode pair is constant.

4. The sensor element according to claim 1, wherein the substrate is made of one of silicon, glass, and plastic.

5. The sensor element according to claim 1, wherein the electrodes are made of one of platinum, iridium, and gold.

6. The sensor element according to claim 1, wherein the sensor chip surface has wetting properties such that the boundaries of the liquid wetting of the sensor surface correspond to the liquid level.

7. An arrangement for measuring a capillary filling, including a sensor element for electrically measuring the position of liquid levels, comprising

a substrate;

and

a plurality of electrodes adapted to be contacted individually and mounted on the substrate,

wherein the electrodes comprise sensor-active partial electrodes that are networked with electrically connections, and wherein the partial electrodes of two respective electrodes are always positioned opposite one another, separated by a distance, to form partial electrode pairs, and the electrode pairs thus formed recur periodically over a length of the sensor element, wherein the sensor element is attached to a capillary in such a way that the sensor-active partial electrodes are situated inside the capillary and the electrically connection options are situated outside the capillary, and that at least one conductivity boundary of the capillary filling is located in the region of the sensor element.

8. The arrangement according to claim 7, wherein two conductivity boundaries of operating liquids in the capillary form a bubble in the region of the sensor element, said bubble being bounded on both sides by the operating liquid.

9. The arrangement according to claim 8, wherein at least one of the bubble is filled with gas, the length of the bubble is approximately twice the length of an electrode pair in the longitudinal direction, and the same operating liquid is present on both sides of the bubble.

10. A method for measuring liquid levels using a sensor element for electrically measuring the position of liquid levels, comprising

a substrate;

and

a plurality of electrodes adopted to be contacted individually and that are mounted on the substrate, wherein the electrodes comprise sensor-active partial electrodes that are networked with electrically connections, wherein the partial electrodes of two respective electrodes are always positioned opposite one another, separated by a distance, to form partial electrode pairs,

and the electrode pairs thus formed recur periodically over a length of the sensor element comprising the steps of;

determining which electrode pairs are covered and which are not covered by an operating liquid by measuring the resistance of each individual electrode pair in an idle state of the operating liquid;

comparing the resistance values to characteristic minimum and maximum values for liquid coverage or no liquid coverage; and

detecting from this information the position of the liquid level or of a bubble on a specific electrode pair wherein the electrodes are electrically insulated from each other.

12. The method according to claim 10, wherein a path distance traveled by the bubble is determined from the detected position of the bubble or of the conductivity boundary before and after movement of the bubble.

14. The method according to claim 12, wherein a displaced liquid volume is determined from the path distance traveled.

15. The method according to claim 10, wherein the resistance measurement of the electrode pairs is performed by measuring a resulting current after an alternating current is applied to the electrodes.

16. The method according to claim 15, wherein the alternating current has a frequency in the kilohertz range and/or an amplitude in the range of 100 millivolts.

19. The method according to claim 12, wherein the resistance measurement of the electrode pairs is performed by measuring a resulting current after an alternating current is applied to the electrodes.

11. A method for measuring liquid levels using a sensor element for electrically measuring the position of liquid levels, said sensor element including a substrate;

and a plurality of electrodes adapted to be contacted individually and mounted on the substrate,

wherein the electrodes comprise sensor-active partial electrodes that are networked with electrically connections, and wherein the partial electrodes of two respective electrodes are always positioned opposite one another, separated by a distance, to form partial electrode pairs,

and the electrode pairs thus formed recur periodically over a length of the sensor element said method comprising the steps of;

comparing the intermediate value lying between the minimum and maximum resistance value of the electrode pair to a reference resistance curve of the electrode pair; and

obtaining the position of a conductivity boundary for a specific partial electrode pair from said step of comparing, wherein the electrodes are electrically insulated from each other.

18. The method according to claim 11, wherein the resistance measurement of the electrode pairs is performed by measuring a resulting current after an alternating current is applied to the electrodes.

13. A method for measuring liquid levels using a sensor element for electrically measuring the position of liquid levels, wherein the sensor element includes a substrate;

and a plurality of electrodes adapted to be contacted individually and mounted on the substrate, wherein the electrodes comprise sensor-active partial electrodes that are networked with electrically connections, and wherein the partial electrodes of two respective electrodes are always positioned opposite one another, separated by a distance, to form partial electrode pairs, and the electrode pairs thus formed recur periodically over a length of the sensor element, said method comprising the steps of;

determining jumps in the resistance values upon movement of a bubble by parallel monitoring of the resistance values of all electrode pairs; and

determining the path distance traveled by the bubble from the number of jumps.

17. The method according to claim 13, wherein a displaced liquid volume is determined from the path distance traveled.