Ammonia separator and neutralizer

• US 6,755,029 B2
• Filed: 01/08/2003
• Issued: 06/29/2004
• Est. Priority Date: 01/08/2002
• Status: Expired due to Fees

• Current Assignee: James A. Masterson, Marvin Ralph Jr. Bertrand
• Original Assignee: James A. Masterson, Marvin Ralph Jr. Bertrand
• Inventors: Masterson, James A., Bertrand, Marvin Ralph Jr.
• Primary Examiner(s): Jiang, Chen Wen
• Application Number:
  US10/338,504
• Publication Number:
  US 20030126868A1
• Time in Patent Office: 538 Days
• Field of Search: 62/84, 624/75, 621/95, 621/92, 621/93, 624/68, 624/70, 624/71
• US Class Current: 62/84
• CPC Class Codes: B01D 19/0068 General arrangements, e.g. flowsheets B01D19/0063 takes precedence

Abstract

The present invention is a method and apparatus to provide for the safe and effective removal and neutralization of ammonia from a stream of waste oil or other liquid. The apparatus consists of a receiving tank, a treatment tank, transfer piping, associated controls, pumping and monitoring mechanisms. The primary utility for the invention is with commercial and industrial refrigeration units. The mixture of waste oil and entrained ammonia is removed from the drain port of the refrigeration system and placed into the receiving tank. The receiving tank includes aeration piping and nozzles and is in fluid communication with the treatment tank. The system provides for the introduction of an acid such as carbon dioxide as a neutralizing agent to be mixed with liberated ammonia as it is pumped into the treatment tank for recirculation.

Claims

1. An apparatus for separating and neutralizing entrained ammonia from an oil stream being removed from a refrigeration system comprised of:

a closed receiving tank for receiving an ammonia-entrained oil supply from said refrigeration system;

a transfer pipeline having a first end and second end with said first end of said transfer pipeline being oriented in the top of said receiving tank and in fluid communication therewith;

a treatment tank for holding an aqueous media with said second end of said transfer pipeline being oriented inside said treatment tank and terminating at a level at or above the top surface of said aqueous media;

means for controllably introducing an acid into said treatment tank or into said transfer pipeline such as to introduce the acid into said treatment tank;

means for pumping said mixture of said aqueous media, acid and released ammonia from said treatment tank and circulating said mixture through a closed system of recirculation piping consisting of a first end and a second end, both of which terminate in said treatment tank.

2. The apparatus of claim 1 wherein said first end of said recirculation piping terminates in the bottom of said treatment tank and wherein said second end of said recirculation piping terminates in one or more spray arms comprising one or more spray nozzles in the top of said treatment tank oriented to spray the recirculated mixture inside the top of said treatment tank at a level above said aqueous media.

3. The apparatus of claim 1 wherein said receiving tank further includes a means for heating the contents of said receiving tank.

4. The apparatus of claim 1 wherein said apparatus is constructed as a portable apparatus disposed upon a wheeled frame.

5. The apparatus of claim 4 wherein said receiving tank and treatment tank are oriented in a stacked configuration on said wheeled frame.

6. The apparatus of claim 1 wherein said acid is carbon dioxide.

7. The apparatus of claim 1 wherein said acid is muriatic acid.

8. The apparatus of claim 1 wherein said aqueous media is comprised of water.

9. A method of separating and neutralizing entrained ammonia from an oil stream being removed from a refrigeration system, comprising the steps of:

a) removing the ammonia-entrained oil supply from said refrigeration system and placing said ammonia-entrained oil supply into a receiving tank;

b) heating said receiving tank to above a temperature required to evaporate the entrained ammonia from said oil supply, whereupon said released gaseous ammonia rises and enters a first end of a transfer pipeline extending from the top of said receiving tank and travels through said transfer pipeline into a treatment tank;

c) mixing said released gaseous ammonia with an aqueous media in said treatment tank by orienting the second end of said transfer pipeline at or above the level of said aqueous media in said treatment tank;

d) placing an acid into said aqueous media; and

e) pumping the mixture of said aqueous media, acid and released ammonia from said treatment tank, circulating said mixture through a closed system of piping for return to said treatment tank.

10. The method of claim 9 wherein said first end of said recirculation piping terminates in the bottom of said treatment tank and wherein said second end of said recirculation piping terminates in one or more spray arms comprising one or more spray nozzles in the top of said treatment tank oriented to spray the recirculated mixture inside the top of said treatment tank at a level above said aqueous media.

11. The method of claim 9 wherein said receiving tank further includes a means for heating the contents of said receiving tank.

12. The method of claim 9 wherein said receiving tank, treatment tank, transfer piping, recirculating piping and all associated equipment are disposed upon a wheeled frame.

13. The method of claim 12 wherein said receiving tank and treatment tank are oriented in a stacked configuration on said wheeled frame.

14. The method of claim 9 wherein said acid is carbon dioxide.

15. The method of claim 9 wherein said acid is muriatic acid.

16. The method of claim 9 wherein said aqueous media is comprised of water.