Method for producing metallic microparticles

• US 6,755,886 B2
• Filed: 04/18/2002
• Issued: 06/29/2004
• Est. Priority Date: 04/18/2002
• Status: Expired due to Term

• Current Assignee: UNM Rainforest Innovations (f/k/a STC.UNM) (The University of New Mexico), TRIAD National Security, LLC
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Kroenke, William J., Phillips, Jonathan, Perry, William L.
• Primary Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US10/126,039
• Publication Number:
  US 20030196513A1
• Time in Patent Office: 803 Days
• Field of Search: 753/46, 753/67, 753/36, 75/101.9, 75/102.1, 419/52, 419/66
• US Class Current: 75/346
• CPC Class Codes: B22F 1/148 Agglomerating
• CPC Class Codes: B22F 2202/13 Use of plasma
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 9/04 starting from solid material, e.g. by crushing, grinding or milling C22C1/1084 takes precedence; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C

Abstract

Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

Claims

1. A method for converting metallic nanoparticles into larger, spherical metallic particles, comprising the steps of:

(a) generating an aerosol of solid metallic precursor nanoparticles entrained in plasma gas, the nanoparticles consisting essentially of metal or oxide coated metal;

(b) generating a non-oxidizing plasma from plasma gas, the plasma comprising a portion sufficiently hot to melt the solid metallic precursor nanoparticles;

(c) directing the aerosol into the plasma and allowing the solid precursor metallic nanoparticles to melt, collide, join, and spheroidize to form larger molten, spherical, metallic particles; and

(d) directing the molten, spherical, metallic microparticles away from the plasma so that they solidify and form larger, metallic, spherical, product particles.

2. The method of claim 1, wherein the metal is selected from the group consisting of Be, Mg, Ca, Sr, Ba, Ra, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Pt, Au, Al, Ga, In, Sb, Pb, Te, Bi, larithanide metals, actinide metals, and alloys thereof.

3. The method of claim 1, wherein the non-oxidizing plasma comprises argon plasma, helium plasma, xenon plasma, nitrogen plasma, neon plasma, hydrogen plasma, or mixtures thereof.

4. The method of claim 1, wherein the plasma comprises oxygen plasma or halogen plasma.

5. The method of claim 1, where the plasma is generated from plasma gas at a gas pressure of about 0.001-100 atmospheres.

6. The method of claim 5, wherein the plasma is generated from plasma gas at a pressure of about 1 atmosphere.

7. The method of claim 1, wherein the plasma is generated by supplying at least 50 Watts of power to the plasma gas.

8. The method of claim 7, wherein the plasma is generated by a DC discharge.

9. The method of claim 7, wherein the plasma is generated using radiofrequency energy.

10. The method of claim 9, wherein the plasma is generated using microwave energy.

11. The method of claim 10, wherein the plasma is generated using about 200-300 watts of power.

12. The method of claim 1, wherein the product particles have a diameter of about 0.5-1000 microns.

13. A method for converting aluminum nanoparticles into larger, spherical aluminum particles, comprising the steps of:

(a) generating an aerosol comprising solid aluminum precursor nanoparticles entrained in plasma gas;

(b) generating a non-oxidizing plasma from plasma gas, the plasma comprising a portion sufficiently hot to melt the solid metallic precursor nanoparticles;

(c) directing the aerosol into the plasma and allowing the solid precursor aluminum nanoparticles to melt, collide, join, and spheroidize to form larger molten, soherical, aluminum particles; and

(d) directing the molten, soherical, metallic microparticles away from the plasma so that they solidify and form larger, spherical, aluminum product particles comprising a diameter of about 0.5-3 microns.