Zinc-diffused alloy coating for corrosion/heat protection

• US 6,756,134 B2
• Filed: 09/23/2002
• Issued: 06/29/2004
• Est. Priority Date: 09/23/2002
• Status: Expired due to Term

• Current Assignee: Raytheon Technologies Corporation d/b/a RTX (Rtx Corporation)
• Original Assignee: United Technologies Corporation (Rtx Corporation)
• Inventors: Hodgens, Henry M., Hanlon, Thomas R., Bhatia, Promila
• Primary Examiner(s): Jones, Deborah
• Application Number:
  US10/252,867
• Publication Number:
  US 20040058189A1
• Time in Patent Office: 645 Days
• Field of Search: 428/658, 428/659, 428/941, 428/679, 148/537, 148/533
• US Class Current: 428/658
• CPC Class Codes: C23C 10/60 After-treatment
• CPC Class Codes: C23C 22/34 containing fluorides or complex fluorides
• CPC Class Codes: C23C 2222/10 Use of solutions containing trivalent chromium but free of hexavalent chromium
• CPC Class Codes: C23C 28/021 including at least one metal alloy layer
• CPC Class Codes: C23C 28/023 only coatings of metal elements only
• CPC Class Codes: C23C 28/025 with at least one zinc-based layer
• CPC Class Codes: C23C 28/028 Including graded layers in composition or in physical properties, e.g. density, porosity, grain size
• CPC Class Codes: Y10S 428/941 Solid state alloying, e.g. diffusion, to disappearance of an original layer
• CPC Class Codes: Y10T 428/12458 having composition, density, or hardness gradient
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/12799 Next to Fe-base component [e.g., galvanized]
• CPC Class Codes: Y10T 428/12937 Co- or Ni-base component next to Fe-base component

Abstract

The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.

Claims

1. A method for forming a corrosion and heat protective coating on a substrate comprising the steps of:

forming a nickel base coating layer on said substrate;

applying a layer of zinc over said nickel base coating layer;

diffusing the zinc into said nickel base coating layer; and

said diffusing step comprising carrying out a thermal diffusion cycle in at least one of an atmospheric and an inert gas oven at a temperature in the range of 600 to 800°

F. for a time of at least 100 minutes.

2. A method according to claim 1, wherein said nickel base coating layer forming step comprises electrodepositing a layer of nickel or nickel alloy onto a surface of said substrate.

3. A method according to claim 1, wherein said nickel base coating layer forming step comprises forming a layer of nickel or nickel alloy having a thickness in the range of 2.0 to 20 μ

m.

4. A method according to claim 1, wherein said nickel base coating layer forming step comprises forming a layer of nickel or nickel alloy having a thickness in the range of from 2.0 to 14.0 μ

m.

5. A method according to claim 1, wherein said nickel base coating layer forming step comprises forming a layer of nickel or nickel alloy having a thickness in the range of from 8.0 to 11 μ

m.

6. A method according to claim 1, wherein said nickel base coating layer forming step comprises forming a layer of nickel or nickel alloy on a steel substrate.

7. A method according to claim 1, wherein said nickel base coating layer forming step comprises forming a layer of nickel alloy on a component used in a gas turbine engine.

8. A method according to claim 1, wherein said nickel base coating layer step comprises forming a layer of a nickel alloy selected from the group consisting of a nickel cobalt alloy, a nickel iron alloy, a nickel manganese alloy, a nickel molybdenum alloy, and a nickel tin alloy.

9. A method according to claim 1, wherein said zinc layer applying step comprises forming an electroplating solution containing a zinc metal concentration of between 8.0 and 45.0 g/l and electroplating said layer of zinc onto said nickel alloy layer.

10. A method according to claim 1, wherein said zinc layer applying step comprises forming a layer of zinc having a thickness in the range of 0.8 to 14 μ

m.

11. A method according to claim 1, wherein said zinc layer applying step comprises forming a layer of zinc having a thickness in the range of 2.0 to 14 μ

m.

12. A method according to claim 1, wherein said zinc layer applying step comprises forming a layer of zinc having a thickness in the range of 4.0 to 7.0 μ

m.

13. A method according to claim 1, wherein said thermal diffusion cycle comprises heating said nickel base coated substrate with said layer of zinc to a first temperature in the aforesaid range for a time period in the range of 80 to 100 minutes and then to a second temperature higher than the first temperature for a time period in the range of 20 to 60 minutes.

14. A method according to claim 1, further comprising immersing said substrate in a phosphate trivalent chromium conversion solution.

15. A method according to claim 14, wherein said immersing step is performed after said zinc layer applying step and before said diffusion step.

16. A method according to claim 14, wherein said immersing step comprises immersing said substrate into a solution comprising a water soluble trivalent chromium compound, a water soluble fluoride compound and a corrosion resistance improving additive.

17. A method for forming a corrosion and heat protective coating on a substrate comprising the steps of:

forming a nickel base coating layer on said substrate;

applying a layer of zinc over said nickel base coating layer;

diffusing the zinc into said nickel base coating layer;

immersing said substrate in a phosphate trivalent chromium conversion solution; and

said immersing step being performed after said zinc layer applying step and before said diffusion step.

18. A substrate having at least one surface and a zinc diffused nickel alloy coating on said at least one surface, said coating having a nickel or nickel alloy layer into which zinc atoms have diffused and a zinc layer into which nickel atoms have diffused, and said nickel alloy being formed from a nickel cobalt alloy having a cobalt content in the range of 7.0 to 40 wt %.

19. A substrate according to claim 18, wherein said substrate is formed from steel.

20. A method for forming a corrosion and heat protective coating on a substrate comprising the steps of:

forming a nickel base coating on said substrate;

applying a layer of zinc over said nickel base coating layer;

diffusing the zinc into said nickel base coating layer; and

atmospheric and an inert gas oven at a temperature of at least 600°

F. for a time sufficient to diffuse said zinc into said nickel base coating.

21. A method according to claim 20, further comprising forming said substrate from a low carbon steel material.